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Control of material properties with photo-induced charge transfer using negative electron affinity surface

Research Project

Project/Area Number 13440101
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionSaga University

Principal Investigator

KAMADA Masao  Saga University, Synchrotron Light Application Center, Professor, シンクロトロン光応用研究センター, 教授 (60112538)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Kazutoshi  Saga University, Synchrotron Light Application Center, Lecturer, シンクロトロン光応用研究センター, 講師 (30332183)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥15,700,000 (Direct Cost: ¥15,700,000)
Fiscal Year 2003: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 2002: ¥5,700,000 (Direct Cost: ¥5,700,000)
Fiscal Year 2001: ¥7,600,000 (Direct Cost: ¥7,600,000)
Keywordsphoto-induced phenomena / negative electron affinity / core-level spectroscopy / Laser and SR / Surface photo voltage / Time-resolved photoelectron / electron spin / GaAs
Research Abstract

We have been investigating the new way to control the charge transfer from semiconductor surfaces to the adsorbed films, which is based on our recent achievement of the new core-level photoelectron spectroscopy using, synchrotron radiation and laser light and also of the formation for, the negative-electron affinity surfaces. This is closely related the important problems such as transient change in the surface potential, dynamics of the photo-induced charge transfer, spin-polarized electrons, photo-induced phase transitions.
The purpose of the present study is to apply the techniques mentioned above for the interface between the semiconductors and intelligent materials and control the material properties and spin,characters. Moreover, the important basic subjects related to the interfacial dynamics such as interfacial potential, non-equilibrium dynamics, photo-induced charge transfer, and production of new properties.
(1)In this year, we have summarized the negative electron amity surfaces on GaAs. Also we have conducted the time-resolved measurements of surface photo-voltage effect and constructed the dynamical model for surface photo-voltage effects on GaAs and GaAsP-GaAs superlattices. The results have been published in the journals.
(2)Based on the above results, we have developed our studies to the photo-induced phenomena on surfaces nad interfaces. The appreciable change was observed on p-GaAs(100)/Cr system in spite of the expectation for the suppression. Although the large photo-effect is expected on p-GaN, the photon-flux dependence of the surface photovoltage effect is not simple and shows the anomalous behavior. The analyses are under progress.
(3)In order to investigate the fast dynamics of the surfaces, we have also been testing the new system consisted of an intense femt-second laser and a rare-gaseous chamber. The new microscopy system is under construction.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] S.More, S.Tanaka, S.Tanaka, Y.Fujii, M.Kamada: "Interaction of Cs and O with GaAs(100) at the overlayer-substrate interface during negative electron affinity type activations"Surface Science. 527. 41-50 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Tanaka, S.D.More, K.Takahashi, M.Kamada: "Dynamics of Surface Photovoltage Effects on Clean and Negative Electron Surfaces of p-GaAs(100)"J.Phys.Soc.Jpn. 72. 657-663 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Yuhara, S.Yussa, O Yoshimoto, D.Nakamura, K.Soda, M.Kamada: "Electronic structure of Si(111)√7x√3-(pb, Sn) surface"Nucl.Instr.Methods B. 199. 422-426 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Soda.J.Yuhara.T.Takada.O.Yoshimoto, M.Kato, S.Yagi, K.Morita, M.Kamada: "Core-level photoelectron study of Si(111)√7x√3-(pb, S)surface"Nucl.Instr.Methods B. 199. 419-421 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Tanaka.T.Nishitani.T.Nakanishi, S.D.More, J.Azuma, K.Takahashi, O.Watanabe, M.Kamada: "Surface photovoltage effect and its time dependence in GaAs-GaAsP superlattice studied with combination of synchrotron and laser radiati on"J.Appl.Physics. 91. 551-556 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 鎌田雅夫, 田中仙君, 高橋和敏, 東 純平, 辻林 徹, 有本 収, 渡辺雅之, 中西俊介, 伊藤 寛, 伊藤 稔: "X線分析の進歩34(放射光とレーザーの組み合わせによろ新しい分光法)"日本分析化学会・X線分析研究懇談会. 1-13 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.More, S.Tanaka, S.Tanaka, Y.Fujii, M.Kamada: "Interaction of Cs and O with GaAs(100) at the overlayer-substrate interface during negative electron affinity type activations"Surface Science. 527. 41-50 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Tanaka, S.D.More, K.Takahashi, M.Kamada: "Dynamics of Surface Photovoltage Effects on Clean and Negative Electron Affinity. Surfaces of p-GaAs(100)"J.Phys.Soc.Jpn.. 72. 657-663 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Yuhara, S.Yussa, O.Yoshimoto, D.Nakamura, K.Soda, M.Kamada: "Electronic Structure of Si(111) √7×√3-(pb, Sn) surface"Nucl.Irstr.Methods B. 199. 422-426 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Soda, J.Yuhara, T.Takada, O.Yoshimoto, M.Kato, S.Yagi, K.Morita, M.Kamada: "Core-level photoelectron study of Si(111) √7×√3-(pb, Sn) surface"Nucl.Instr.Methods. 199. 416-421 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Tanaka, T.Nishitani, T.Nakanishi, S.D.More, J.Azuma, K.Takahashi, O.Watanabe, M.Kamada: "Surface photovoltage effect and its time dependence in GaAs-GaAsP superlattice studied with combination of synchrotron and laser radiation"J.Appl.Physics. 95. 551-556 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.More: "Interaction of Cs and O with GaAs(100) at the overlayer-substrate interface during negative electron affinity type activations"surface Science. 527. 41-50 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Tanaka: "Dynamics of Surface Photovoltage Effects on Clean and Negative Electron Affinity Surfaces of p-GaAs(100)"J.Phys.Soc.Jpn. 72. 657-663 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Yuhara: "Electronic structure of Si(111) √<7>x√<3>-(pb,Sn) surface"Nucl.Instr.Methods B. 199. 422-426 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Soda: "Core-level photoelectron study of Si(111) √<7>x√<3>-(pb,Sn) surface"Nucl.Instr.Methods B. 199. 419-421 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Tanaka: "Surface photovoltage effect and its time dependence in GaAs-GaAsP superlattice studied with combination of synchrotron and laser radiation"J.Appl.Physics. 91. 551-556 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 鎌田雅夫: "X線分析の進歩34(放射光とレーザーの組み合わせによる新しい分光法)"日本分析化学会・X線分析研究懇談会. 1-13 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Kamada, M.Itoh.: "Nonradiative decay of core excitons in the Auger-free luminescence materials CsCl and BaF2"Phys. Rev. B. 65. 245104-1-245104-6 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Tsujibayashi, K.Toyoda, S.Sakuragi, M.Kamada, M.Itoh: "Spectral profile of the two-photon absorption coefficients in CaF2"Appl. Phys. Lett.. 80. 2883-2885 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.Azuma, K.Tanaka, M.Kamada, K.Kan'no: "Valence-Band Structures of Quasi-One-Dimensional Crystals C5H10NH2PbX3[X=I, Br]"J. Phys. Soc. Jpn.. 71. 2730-2735 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Kamada, K.Takahashi, Y.Doi, K.Fukui, T.Tayagaki, K.Tanaka: "Photoelectron Spectroscopic Study on Photo-induced Phase Transition of Spin-crossover Complex"Phase Transition. 75. 847-853 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Tanaka, S.D.More, K.Takahashi, M.Kamada, T.Nishitani, T.Nakanishi: "Surface-photovoltage effect in GaAs-GaAsP super-Lattice studied with combi synchrotron radiation and the laser"Surface Review and Letters. 9. 1297-1301 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Tanaka, K.Takahashi, J.Azuma, K.Hayakawa, M.Itoh, M.Kamada: "New spectroscopy using synchrotron radiation and laser light"Phase Transitions. 75. 911-918 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 鎌田 雅夫: "極限状態を見る放射光アナリシス"日本分光学会、測定法シリーズ40. 49-58 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Kamada et al.: "Beam-line systems for pump-probe photoelectron spectroscopy using SR and laser"Nuclear Instruments and Methods. A467/468. 1441-1443 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Asaka et al.: "Optical detection system using time structure of UVSOR for combined laser-SR experiments"Nuclear Instruments and Methods. A467/468. 1455-1457 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Asaka et al.: "Ultraviolet light amplification within a nanometer-sized layer"Phys.Rev.B. 63. 81104-81106 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Tanaka et al.: "Surface photovoltage effects on p-GaAs(100) from core-level photoelectron spectroscopy using synchrotron radiation and a laser"Phys.Rev.B. 64. 1553081-1553086 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2020-05-15  

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