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Direct Observation of Orbital Ordering in Light Transition Metal Oxides by Soft-X Ray Core Absorption Spectroscopy with Linearly Polarized Light

Research Project

Project/Area Number 13440113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionHIROSHIMA UNIVERSITY

Principal Investigator

KIMURA Akio  Hiroshima Univ., Graduate School of Science, Associate Professor, 大学院・理学研究科, 助教授 (00272534)

Co-Investigator(Kenkyū-buntansha) SHIMADA Kenya  Hiroshima University, Hiroshima Synchrotron Radiation Center, Associate Professor, 放射光科学研究センター, 助教授 (10284225)
NAMATAME Hirofumi  Hiroshima University, Hiroshima Snchrotron Radiation Center, Professor, 放射光科学研究センター, 教授 (10218050)
TANIGUCHI Masaki  Hiroshima Univ., Graduate School of Science, Professor, 大学院・理学研究科, 教授 (10126120)
IGA Fumitoshi  Hiroshima University, Graduate School of Science, Associate Professor, 大学院・先端物質科学研究科, 助教授 (60192473)
SATO Hitoshi  Hiroshima Univ., Graduate School of Science, Research Associate, 大学院・理学研究科, 助手 (90243550)
Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥12,300,000 (Direct Cost: ¥12,300,000)
Fiscal Year 2002: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2001: ¥10,600,000 (Direct Cost: ¥10,600,000)
KeywordsLinear Dichroism in Core Absorption / Soft X-ray Synchrotron Radiation / Linearly Polarized Light / Transition Metal Oxides / Orbital Ordering / 直線偏光 / 放射光ビームライン / ペロブスカイト構造 / 四楕円イメージ炉
Research Abstract

We have developed the experimental system to observe a linear dichroism in core absorption spectra using soft X-ray synchrotron radiation at Hiroshima Synchrotron Radiation Center (HSRC) of Hiroshima University. Using this system, we study orbital ordering, which possibly exists in several 3d transition metal oxides involving Ti and V atoms. These transition metal oxides are fabricated in our group. Our research goal is to find if the orbital ordering exists in these transition metal oxides and also to relate the spin ordering with the orbital ordering.
During the first fiscal year (H13), we have developed the observation system, which was attached to the beam-line of HiSOR, the strage ring at HSRC. We also attached the cryostat with the heater to the sample manipulator, which enabled us to change the sample temperature from 10K to 300K. In the first fiscal year, we newly bought a low energy electron diffraction (LEED) system for the check of the sample surface cleanliness. We finished the adjustment of the beamline at HiSOR by the end of the year (H13). As a result, we could use the light beam in the photon energy range of 400-1000eV with the photn flux of 10^8-10^9 photons/sec. At the second fiscal year, we actually performed the experiment on single crystalline VTiO3, which has been fabricated in our research group. We could observe the difference between the absorption coefficients with the light polarization vector parallel to a and b axes. We are now analyzing data and going to clarify the relationship between the orbital ordering and the physical properties.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] M.Taniguchi, H.Namatame: "Electron Spectroscopies of d, felectron systems at Hiroshima Synchrotron Radiation Center"J. Electron Spectrosc. Relat. Phenom.. 124. 107-125 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Shimada et al.: "Direct Observation of the Ce 4f States in the Kondo Semiconductor CeRhAs and Related Compounds, A High-Resolution Resonant Photoemission Study"Phys. Rev. B. 66. 155202-155205 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Sato et al.: "X-dependent Electronic Structure of YbXCu_4 (X=In, Cd, Mg) Investigated by High-resolution Photoemission Spectroscopy"J. Phys. Condens. Matter.. 14. 4445-4459 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.Kimura et al.: "Soft X-ray Magnetic Circular Dichroism of c(2x2) CuMn Ordered Surface Alloy"Jpn. J. Appl. Phys.. 42(掲載予定). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Xie, A.Kimura et al.: "Magnetic Properties of Mn Ultrathin Film on Ni(110)"Jpn. J. Appl. Phys.. 42(掲載予定). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M. Taniguchi and H. Namatame: "Electron Spectroscopies of d, f electron systems at Hiroshima Synchrotron Radiation Center"J. Electron Spectrosc. Relat. Phenom.. 124. 107-125 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Shimada et al.: "Direct Observation of the Ce 4f States in the Kondo Semiconductor CeRhAs and Related Compounds. A High-Resolution Resonant Photoemission Study"Phys. Rev. B. 66. 155202-155205 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Sato et al.: "X-dependent Electronic Structure of YbXCu_4 (X=In, Cd, Mg) Investigated by High-resolution Photoemission Spectroscopy"J. Phys. Condens. Matter.. 14. 4445-4459 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A. Kimura et al.: "Soft X-ray Magnetic Circular Dichroism of c(2x2) CuMn Ordered Surface Alloy"Jpn. J. Appl. Phys. in press. 42 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Xie, A. Kimura et al.: "Magnetic Properties of Mn Ultrathin Film on Ni(110)"Jpn. J. Appl. Phys.. in press. 42 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M.Taniguchi, H.Namatame: "Electron spectroscopies of d, f electron systems at Hiroshima Synchrotron Radiation Center"J. Electron Spectrosc. Relat. Phenom.. 124. 107-125 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Shimada et al.: "Direct observation of the Ce 4f states in the Kondo semiconductor CeRhAs and related compounds"Phys. Rev. B. 66. 155202-155205 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Sato et al.: "X-dependent electronic structure of YbXCu_4(X=In, Cd, Mg) investigated by high-resolution photoemission spectroscopy"J. Phys., Condens. Matter.. 14. 4445-4459 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Kimura et al.: "Soft X-ray Magnetic Circular Dichroism of c(2x2) CuMn Ordered Surface Alloy"Jpn. J. Appl. Phys.. 42(掲載予定). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Xie, A.Kimura et al.: "Magnetic Properties of Mn Ultrathin Film on Ni(110)"Jpn. J. Appl. Phys.. 42(掲載予定). (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2001-04-01   Modified: 2020-05-15  

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