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Submillimeter-wae Investigations of Reaction Intermediates Relevant to Interstellar and Atmospheric Chemistry

Research Project

Project/Area Number 13440172
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionIbaraki University

Principal Investigator

AMANO Takayoshi  IBARAKI UNIV., COLLEGE OF SCIENCE, PROFESSOR, 理学部, 教授 (60037249)

Co-Investigator(Kenkyū-buntansha) 笠井 康子  独立行政法人通信総合研究所, 主任研究員 (60281630)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 2003: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2002: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2001: ¥2,900,000 (Direct Cost: ¥2,900,000)
KeywordsSubmillimeter-wave spectroscopy / Interstellar molecules / Deuterated species / Earth's atmosphere / Molecular ions / Free radicals / サブミリ波 / 大気化学 / クラスター
Research Abstract

During the past several years, out effort was focused on submillimeter-wave spectroscopic studies of free radicals and molecular ions, in particular, of astrophysical and atmospheric chemical interests. Very high-sensitivity, high-precision, and high efficiency of data acquisition of a spectrometer system are the most crucial factors for successful search of free radicals and ions. To achieve this goal, we employed Russian-made backward-wave oscillators as radiation sources. The oscillation frequencies have been stabilized by using a double phase-lock loop. Below major results are summarized and full report already published on these results will attached as Appendices. The collaboration with the JEM/SMILES group has been measured. These projects are also pursued in collaboration with the JPL group.
Major achievements obtained during this project term are mainly in the following areas: (1)Spectroscopy of unstable species (2)Identification of reaction intermediates in discharge plasma used for plasma CVD processes. (3Precise pressure broadening measurements of molecules relevant to the Earth's atmospheric chemistry.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge"J.Mol.Spectrosc. 211. 273-278 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.M.Yamada, M.Kobayashi, H.Habara, T.Amano, B.J.Drouin: "Submillimeter-wave Measurements of the Pressure Broadening of BrO"J.Quant.Spectrosc.Radiation Transfer. 82. 391-399 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Z.Zelinger, T.Amano, B.Ahrens, S.Bruenken, F.Lewen, H.S.P.Mueller, G.Winnewisser: "Submillimeter-wave spectroscopy of HCN in excited vibrational states"J.Mol.Spectrosc. 220. 223-233 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical."J.Mol.Spectrosc. 221. 31-37 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D_2H^+ : A New Probe into Multiple Deuteration?"Astrophys.J.Letters. 597. L85-L87 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge."J.Mol.Spectrosc.. 211. 273-278 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Habara, S.Yamamoto, T.Amano: "Submillimeter-wave spectra of HCS and DCS."J.Chem.Phys.. 116. 9232-9238 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Tanabashi, T.Amano: "New Identification of the Visible Bands of the C_2 Swan System."J.Mol.Spectrosc.. 215. 285-294 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.M.Yamada, M.Kobayashi, H.Habara, T.Amano, B.J.Drouin: "Submillimeter-wave Measurements of the Pressure Broadening of BrO."J.Quant.Spectrosc.Radiation Transfer.. 82. 391-399 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Z.Zelinger, T.Amano, B.Ahrens, S.Bruenken, F.Lewen, H.S.P.Mueller, G.Winnewisser: "Submillimeter-wave spectroscopy of HCN in excited vibrational states."J.Mol.Spectrosc.. 220. 223-233 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical."J.Mol.Spectrosc.. 221. 31-37 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D_2H^+ : A New Probe into Multiple Deuteration?"Astrophys.J.Letters. 597. L85-L87 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hirao, T.Amano: "Precise Laboratory Rest Frequency of a Submillimeter-Wave Line of D_2H^+."The Interstellar Medium in Galaxies(91 Springer Proceedings in Physics). 103-106 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Amano, M.M.Yamada: "Pressure Broadening Measurements at Ibaraki; BrO and O_3."Proceedings of International Workshop on Critical Evaluation of mm/sub-mm-wave Spectroscopic Data for Atmospheric Observations. 28-31 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.M.Yamada, M.Kobayashi, et al.: "Submillimeter-wave Measurements of the Pressure Broadening of BrO"Journal of Quantitative Spectroscopy and Radiation Transfer. 82. 391-399 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Z.Zelinger, T.Amano, et al.: "Submillimeter-wave spectroscopy of HCN in excited vibrational states"Journal of Moleculular Spectroscopy. 220. 223-233 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical"Journal of Molecular Spectroscopy. 221. 31-37 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D2H+ : A New Probe into Multiple Deuteration?"Astrophysical Journal. 597. L85-L87 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC--"Journal of Molecular Spectroscopy. 211. 273-278 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Habara, S.Yamamoto, T.Amano: "Submillimeter-wave Spectra of HCS and DCS"Journal of Chemical Physics. 116. 9232-9238 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Tanabashi, T.Amano: "New Identification of the Visible Bands of C_2---"Journal of Molecular Spectroscopy. 215. 285-294 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 羽原秀太, 天埜堯義: "マイクロ波分光・サブミリ波分光の最近の進展"ぶんせき. 2002. 373-379 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Yamada, M.Kobayashi 他3名: "Submillimeter-wave measurements of thu ---"J. Quant. Spectrosc. Radiation Transfer. (accepled). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Maeda, T.Hirao, P.F.Bernach, T.Amano: "Submillimeter-Wave Spectroscopy of TiCL in the・・・"Journal of Molocular Spectrescopy. 210. 250-258 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Amano, Z.Zelinger: "Submillimeter-Wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge"Journal of Molocular Spectrescopy. 211. 1-6 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] R.S.Ram, T.Hirao, P.F.Bernach: "The X^3Σ^- ground state of WO"Chemical Physics Letters. 343. 437-445 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] P.F.Bernach, S.McLeod: "DiRef, A Database of Reference・・・"Journal of Moleculer Spectrescopy. 207. 287 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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