| Project/Area Number |
13440199
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
MATSUZAKA Hiroyuki Osaka Prefecture University, Faculty of Arts and Sciences, Professor, 総合科学部, 教授 (50221586)
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| Co-Investigator(Kenkyū-buntansha) |
TAKEMOTO Shin Osaka Prefecture University, Faculty of Arts and Sciences, Assistant Professor, 総合科学部, 助手 (20347511)
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| Project Period (FY) |
2001 – 2003
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| Project Status |
Completed (Fiscal Year 2003)
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| Budget Amount *help |
¥15,200,000 (Direct Cost: ¥15,200,000)
Fiscal Year 2003: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2001: ¥13,800,000 (Direct Cost: ¥13,800,000)
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| Keywords | Heteronuclear Metal-Metal Bond / Mixed-Metal Cluster / Ruthenium / Cobalt / Rhodium / Iridium / Nanowire / Nanowheel / 金属クラスター / 金属-金属結合 / X線構造解析 / ベンゼンジチオラート / カテコラート / アミド |
|---|
| Research Abstract |
Reaction of Cp^*Ru(CO)_2Cl (1, Cp^* = η^5-C_5Me_5) with NaCo(CO)_4 (2) exclusively gave the Ru-Co heterobimetallic complex (3), whereas similar treatment of 1 with [PPN] [Rh(CO)_4] (4, PPN^+ = (Ph_3P)_2N) selectively yielded the Ru_2Rh trinuclear culuster (5). Complex 3 has been found to be an excellent precursor to a series of Ru/Rh mixed-metal clusters with Ru_2Rh (10), Ru_2Rh_2 (8), Ru_3Rh_2 (6), Ru_4Rh_2 (98), and Ru_4Rh_4 (7) cores, Particularly interesting are the Ru_3Rh_2 pentanuclear nanowire (6) and the Ru_4Rh_4 octanuclear nanowheel (7), in both of which the selective expansion of heteronuclear metal-metal bond results in the formation of nanoscale metal framework with the alternate arrangement of Ru and Rh atoms. Novel mixed-metal clusters (3), (5) 〜 (10) have been determined by X-ray crystallography.
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