| Project/Area Number |
13450025
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Applied optics/Quantum optical engineering
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| Research Institution | Tohoku University |
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Principal Investigator |
KAINO Toshikuni TOHOKU UNIVERSITY, Institute of Multidisciplinary Research for Advanced Materials, Professor, 多元物質科学研究所, 教授 (00281709)
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| Co-Investigator(Kenkyū-buntansha) |
OKAMOTO Etsuya TOHOKU UNIVERSITY, Institute of Multidisciplinary Research for Advanced Materials, Research Associate, 多元物質科学研究所, 助手 (50312682)
KOMATSU Kyoji TOHOKU UNIVERSITY, Institute of Multidisciplinary Research for Advanced Materials, Research Associate, 多元物質科学研究所, 助手 (90261502)
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| Project Period (FY) |
2001 – 2003
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| Project Status |
Completed (Fiscal Year 2003)
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| Budget Amount *help |
¥15,100,000 (Direct Cost: ¥15,100,000)
Fiscal Year 2003: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2002: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2001: ¥9,000,000 (Direct Cost: ¥9,000,000)
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| Keywords | Serially Grafted Structure / Photobleaching / Reactive Ion Etching / Optical Waveguide / Refractive Index / Optical Loss / フォトプロセス / 有機イオン性色素 / ビーム伝搬法 / 有機結晶成長 / ポリアリールエーテル / リフトオフプロセス / 紫外線硬化エポキシ樹脂 / 異性化 / アゾベンゼン色素 |
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| Research Abstract |
Organic crystal optical waveguides are promising device for practical photonic applications though because of their large optical loss, they should be serially grafted with transparent polymer waveguides. Among a variety of organic crystals we investigated an organic salt, 4-N, N-dimethylamino-4'-N-methyl-stilbazorium tosylate, DAST, an a promising functional crystal. It is of particular interest because its largest NLO coefficient d_<11> is 〜540V and electro-optic (EO) coefficient r_<11> is 〜55pm/V (λ=1.54μm). DAST crystal is relatively hard to fabricate optical waveguide because it is very easy to dissolve into organic solvents as well as in water. This is very critical because the selection of the waveguide fabrication methods will be limited.
So we had used special lift off method to fabricate a serially grafted optical waveguide of DAST and transparent polymer. Based on the photolithography and reactive ion etching technology, we had succeeded to fabricate a serially grafted struct
… More
ure of the waveguide, for the first time as far as the combined waveguide of crystal and polymer. As far as NLO organic crystal waveguide concerns, only two molecular crystals that are usually insoluble in water were reported, though their loss was large, larger than 20dB/cm. In the case of the DAST, loss was around 10dB/cm and 〜6dB/cm with serially grafted structure of 5 mm long DAST. DAST serially grafted waveguide was also fabricated using photobleaching. We had already reported that the DAST crystal is photo-bleachable based on photo-isomerization and photodecomposition. So as a polymer waveguide, we had selected azobenzene-dye containing transparent polymer to photobleach. After synthesizing novel polyarylether with azo-dye, we have fabricated a serially grafted waveguide of DAST and the polyarylether. We had succeeded to fabricate it using this simple photobleaching technology.
In conclusion, a serially grafted organic functional crystal and transparent polymer was successfully fabricated for the time as far as we know. The waveguide of the DAST crystal and polymer is expected to apply for functional optical circ in optical telecommunication system. Less
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