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Study on fabrication of heterostructures based on InN, GaN and alloys and applications for HFET

Research Project

Project/Area Number 13450131
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionRitsumeikan University

Principal Investigator

NANISHI Yasushi  RITSUMEIKAN UNIVERSITY, COLLEGE OF SCIENCE & ENGINEERING, PROFESSOR, 理工学部, 教授 (40268157)

Co-Investigator(Kenkyū-buntansha) TAKAKURA Hideyuki  RITSUMEIKAN UNIVERSITY, COLLEGE OF SCIENCE & ENGINEERING, PROFESSOR, 理工学部, 教授 (30112022)
IMAI Shigeru  RITSUMEIKAN UNIVERSITY, COLLEGE OF SCIENCE & ENGINEERING, PROFESSOR, 理工学部, 教授 (40223309)
ARAKI Tsutomu  RITSUMEIKAN UNIVERSITY, COLLEGE OF SCIENCE & ENGINEERING, ASSISTANT PROFESSOR, 理工学部, 講師 (20312126)
SUZUKI Akira  RITSUMEIKAN UNIVERSITY, RESEARCH ORGANIZATION OF SCIENCE & ENGINEERING, PROFESSOR, 総合理工学研究機構, 教授 (10111931)
HARIMA Hiroshi  KYOTO INSTITUTE OF TECHNOLOGY, DEPARTMENT OF ELECTRONICS AND INFORMATION, PROFESSOR, 電子情報工学科, 教授 (00107351)
寺口 信明  シャープ(株), 技術本部基盤技術研究所, 係長
鈴木 章  シャープ(株), 技術本部基盤技術研究所, 技師長
Project Period (FY) 2001 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥12,800,000 (Direct Cost: ¥12,800,000)
Fiscal Year 2004: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2003: ¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2002: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 2001: ¥3,300,000 (Direct Cost: ¥3,300,000)
KeywordsInN / RF-MBE / InGaN / HFET / bandqap / heterostructure / quantum well / crystal growth / InN / InGaN / 臨界膜厚 / InAlN / 量子井戸構造 / 貫通転位 / バンドギャツプ / 極性 / Si基板 / AlNバッファ / ヘテロ接合 / モンテカルロシミュレーション / 最大ドリフト速度 / 窒化 / 低温中間層 / AlGaN / GaN / 二次元電子ガス / Full Band Monte Carlo Simulation
Research Abstract

In this research project, our aim is to develop fundamental technologies for fabrication of HFET based on InN, GaN and their alloys. We have studied the crystal growth of high quality InN and InGaN using plasma-excited molecular beam epitaxy and the fabrication of heterostructure based on these materials. Principal results obtained in this project are summarized as follows ;
1. For the InN growth on sapphire by RF-MBE, single crystalline InN with high quality crystalliniy and excellent electrical properties were successfully grown by optimizing growth condition such as nitridation, low-temperature grown buffer layer, growth temperature etc.
2. Based on systematic studies on structural and optical characterizations using TEM, XRD, Raman scattering, EXAFS, PL and optical absorption, true bandgap energy of InN with ideal wurtzite structure is found to be approximately 0.65 eV.
3. Single-crystalline InN was successfully grown on Si by introducing brief nitridation and AIN buffer.
4. High quality In-rich InGaN without phase separation was obtained by using low-temperature grown InN buffer. It was also found that insertion of the InN template was very effective in improving the crystalline quality and surface morphology of In-rich InGaN.
5. InN/InGaN quantum well structures were successfully fabricated on the InN template grown on sapphire, and PL emissions from the InN well layers were observed for the first time.
6. Influences of thermal oxidation of InN on the chemical properties of InN surface and structural and optical properties were studied. The oxidation of InN was confirmed to promote the formation of In_2O_3, which had a remarkable influence on optical properties of the InN.
7. Monte Carlo simulation of electrical properties of InN with narrow bandgap showed that InN has higher mobility and saturation velocity than GaN, indication excellent potential for HFET application.

Report

(5 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • 2001 Annual Research Report

Research Products

(36 results)

All 2005 2004 2003 2002 Other

All Journal Article (19 results) Book (1 results) Publications (16 results)

  • [Journal Article] Fabrication and Characterization of InN-Based Quantum Well Structures Grown by Radio-Frequency Plasma-Assisted Molecular-Beam Epitaxy2005

    • Author(s)
      M.Kurouchi, H.Naoi, T.Araki, T.Miyajima, Y.Nanishi
    • Journal Title

      Jpn.J.Appl.Phys. 44

      Pages: 230-232

    • NAID

      10014421076

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Growth of polycrystalline InN on silica glass by ECR-MBE2005

    • Author(s)
      T.Araki, T.Ueno, H.Naoi, Y.Nanishi
    • Journal Title

      phys.stat.sol.(c) 2

      Pages: 2316-2319

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Fabrication and Characterization of InN-Based Quantum Well Structures Grown by Radio-Frequency Plasma-Assisted Molecular-Beam Epitaxy2005

    • Author(s)
      M.Kurouchi, H.Naoi, T.Araki, T.Miyajima, Y.Nanishi
    • Journal Title

      Jpn.J.Appl.Phys.(Express Letter) 44

    • NAID

      10014421076

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Correlation among Growth Conditions, Crystal Structures and Optical Properties2005

    • Author(s)
      H.Naoi, M.Kurouchi, T.Araki, T.Yamaguchi, Y.Nanishi
    • Journal Title

      phys.stat.sol.(c) 2

      Pages: 841-844

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Band-Gap Energy and Physical Properties of InN Grown by RE-Molecular Beam Epitaxy2004

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, F.Matsuda, T.Araki, H.Naoi 他3名
    • Journal Title

      Mat.Res.Soc.Symp.Proc. 798

      Pages: 189-200

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Radio frequency-molecular beam epitaxial growth of InN epitaxial films on (0001) sapphire and their properties2004

    • Author(s)
      T.Araki, Y.Saito, T.Yamaguchi, M.Kurouchi, Y.Nanishi, H.Naoi
    • Journal Title

      J.Vac.Sci.Tech.B 22

      Pages: 2139-2143

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Recent Development of InN RF-MBE Growth and its Structural and Property Characterization2004

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, T.Araki, T.Miyajima
    • Journal Title

      phys.stat.sol.(c) 1

      Pages: 1487-1495

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Band-Gap Energy and Physical Properties of InN Grown by RF-Molecular Beam Epitaxy2004

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, F.Matsuda, T.Araki, H.Naoi, A.Suzuki, H.Harima, T.Miyajima
    • Journal Title

      Mat.Res.Soc.Symp.Proc. 789

      Pages: 189-200

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] The effect of substrate polarity on the growth of InN by RF-MBE2004

    • Author(s)
      H.Naoi, F.Matsuda, T.Araki, A.Suzuki, Y.Nanishi
    • Journal Title

      J.Cryst.Growth 269

      Pages: 155-161

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Band-Gap Energy and Physical Properties of InN Grown by RF-Molecular Beam Epitaxy2004

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, F.Matsuda, T.Araki, H.Naoi, A.Suzuki, H.Harima, T.Miyajima
    • Journal Title

      Mat.Res.Soc.Symp.Proc. 798

      Pages: 189-200

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Radio frequency-molecular beam epitaxial growth of InN epitaxial films on (0001) sapphire and thier properties2004

    • Author(s)
      T.Araki, Y.Saito, T.Yamaguchi, M.Kurouchi, Y.Nanishi, H.Naoi
    • Journal Title

      J.Vac.Sci.Tech.B 22

      Pages: 2139-2143

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Growth and properties of In-rich InGaN films grown on (0001) supphire by RF-MBE2004

    • Author(s)
      M.Kurouchi, T.Araki, H.Naoi, T.Yamaguchi, A.Suzuki, Y.Nanishi
    • Journal Title

      phys.stat.sol.(b) 241

      Pages: 2843-2848

    • Related Report
      2004 Annual Research Report
  • [Journal Article] RF-Molecular Beam Epitaxy Growth and Properties of InN and Related Alloys2003

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi
    • Journal Title

      Jpn.J.Appl.Phys. 42

      Pages: 2549-2559

    • NAID

      10010715464

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] MBE-Growth, Characterization and Properties of InN and InGaN2003

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, M.Hori, F.Matsuda, T.Araki 他2名
    • Journal Title

      phys.stat.sol.(a) 200

      Pages: 202-208

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] MBE-Growth, Characterization and Properties of InN and InGaN2003

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi, M.Hori, F.Matsuda, T.Araki, A.Suzuki, T.Miyajima
    • Journal Title

      phys.stat.sol.(a) 200

      Pages: 202-208

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Single crystalline InN films grown on Si substrates by using a brief substrate nitridation process2003

    • Author(s)
      T.Yamaguchi, K.Mizuo, Y.Saito, T.Noguchi, T.Araki, Y.Nanishi
    • Journal Title

      Mat.Res.Soc.Symp.Proc. 743

      Pages: 163-168

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] RF-MBE Growth and Characterization of Indium Nitride on (0001) sapphire substrate2002

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi
    • Journal Title

      Vacuum Science and Technology ; Nitrides as seen by technology

      Pages: 201-220

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Growth Temperature Dependence of Indium Nitride Crystalline Quality Grown by RF-MBE2002

    • Author(s)
      Y.Saito, H.Harima, E.Kurimoto, T.Yamaguchi, N.Teraguchi, A.Suzuki, T.Araki, Y.Nanishi
    • Journal Title

      phys.stat.sol.(b) 234

      Pages: 796-800

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Optical properties of InxGa1-xN with entire alloy composition on InN buffer layer grown by RF-MBE2002

    • Author(s)
      M.Hori, K.Kano, T.Yamaguchi, Y.Saito, T.Araki, Y.Nanishi, N.Teraguchi, A.Suzuki
    • Journal Title

      phys.stat.sol.(b) 234

      Pages: 750-754

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] Vacuum Science and Technology ; Nitrides as seen by technology2002

    • Author(s)
      Y.Nanishi, Y.Saito, T.Yamaguchi
    • Total Pages
      20
    • Publisher
      Research Signpost
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] Y.Nanishi, Y.Saito, T.Yamaguchi: "RF-Molecular Beam Epitaxy Growth and Properties of InN and Related Alloys"Jpn.J.Appl.Phys.. 42(Invited). 2549-2559 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nanishi, Y.Saito, T.Yamaguchi, T.Araki, A.Suzuki他3名: "MBE-Growth, Characterization and Properties of InN and InGaN"phys.stat.sol.(a). 200. 202-208 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 名西〓之, 荒木努, 宮嶋孝夫: "InNおよびInGaNの結晶成長と構造および特性の評価"応用物理. 72. 565-571 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Araki, K.Mizuo, T.Yamaguchi, Y.Saito, Y.Nanishi: "TEM Characterization of InN films grown by RF-MBE"phys.stat.sol.(c). 0. 2798-2801 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] F.Matsuda, Y.Saito, T.Araki, Y.Nanishi他4名: "Influence of substrate polarity on growth of InN films by RF-MBE"phys.stat.sol.(c). 0. 2810-2813 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Yamaguchi, Y.Saito, T.Araki, A.Suzuki, Y.Nanishi他2名: "Effect of AIN buffer layer on the growth of InN epitaxial film on Si substrate"phys.stat.sol.(b). 240. 429-432 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Saito, H.Harima, E.Kurimoto, T.Yamaguchi, N.Teraguchi, A.Suzuki 他: "Growth Temperature Dependence of Indium Nitride Crystalline Quality Grown by RF-MBE"phys.stat.sol.(b). 234. 796-800 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Hori, K.Kano, T.Yamaguchi, Y.Saito, T.Araki, Y.Nanishi 他: "Optical Properties of InxGal -xN with Entire Alloy Composition on InN Buffer Layer Grown by RF-MBE"phys.stat.sol.(b). 234. 750-754 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Saito, T.Yamaguchi, H.Kanazawa, K.Kano, T.Araki, Y.Nanishi 他: "Growth of high-quality InN using low-temperature intermediate layers by RF-MBE"J.Cryst.Growth. 237-239. 1017-1021 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yamaguchi, T.Araki, Y.Saito, K.Kano, H.Kanazawa, N.Teraguchi, A.Suzuki 他: "Effect of sapphire substrate nitridation on determining rotation domain in GaN growth"J.Cryst.Growth. 237-239. 993-997 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yamaguchi, T.Araki, Y.Saito, T.Maruyama, Y.Nanishi 他: "Growth Condition Dependence of InN film a-Axis Directions on Sapphire(0001) Substrate"Inst.Phys.Conf.Ser.. 170. 765-770 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 齋藤義樹, 堀正輝, 山口智広, 寺口信明, 鈴木彰, 荒木努, 名西やす之: "RF-MBE成長単結晶InN膜の光学特性"信学技報. 102. 89-92 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Saito, Y.Tanabe, T.Yamaguchi, T.Araki, Y.Nanishi, N.Teraguchi, A.Suzuki: "Polarity of High-quality Indium Nitride grown by RF Molecular Beam Epitaxy"phy. stat. sol. (b). 228. 13-16 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yamaguchi, Y.Saito, K.Kano, T.Araki, N.Teraguchi, A.Suzuki, Y.Nanishi: "Study of epitaxial relationship in InN growth on sapphire (0001) substrate without nitridation process by RF-MBE"phy. stat. sol. (b). 228. 17-20 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yamaguchi, T.Araki, Y.Saito, K.Kano, H.Kanazawa, N.Teraguchi, A.Suzuki, Y.Nanishi: "Effect of sapphire substrate nitridation on determining rotation domain in GaN growth"J. Cryst. Growths. (出版予定). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Saito, T.Yamaguchi, H.Kanazawa, K.Kano, T.Araki, Y.Nanishi, N.Teraguchi, A.Suzuki: "Growth of thicker and high quality InN using low-temperature intermediate layer"J. Cryst. Growths. (出版予定). (2002)

    • Related Report
      2001 Annual Research Report

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Published: 2001-03-31   Modified: 2016-04-21  

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