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Conversion to Biodegradable Polylactic Acid and High Speed Methane Fermentation of Paper Manufacture Sludge with Sub-Critical Water Treatment

Research Project

Project/Area Number 13480180
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 環境保全
Research InstitutionOsaka Prefecture University

Principal Investigator

YOSHIDA Hiroyuki  Osaka Prefecture University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50081360)

Co-Investigator(Kenkyū-buntansha) SHIGETA Takeshiro  Osaka Prefecture University, Graduate School of Engineering, Assistant Professor, 大学院・工学研究科, 助手 (20316011)
GALINADA Wilmer  Osaka Prefecture University, Graduate School of Engineering, Assistant Professor, 大学院・工学研究科, 助手 (80347509)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥15,200,000 (Direct Cost: ¥15,200,000)
Fiscal Year 2003: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2002: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 2001: ¥10,600,000 (Direct Cost: ¥10,600,000)
KeywordsSub-Critical Water / Hybrolysis / Pulp Sludge / Organic Acids / Lactic Acid / Methane Fermentation / Adsorption / Separation / 酢酸 / 高速・高消化率 / 汚泥 / エネルギー / 生分解性プラスチック
Research Abstract

The objective of this work is to develop zero emission conversion technologies of paper manufacture sludge to resources or energy with sub-critical water treatment.
Pulp sludge was processed with sub-critical and supercritical water using a small batch reactor, and the effect of temperature and reaction time on the products and their amounts were tested. The soluble products showed maximum amounts around 570 K in sub-critical region. The reaction time was enough in 5-20 minutes. In water-phase, sugar such as cellobiose, glucose, fructose, and erythrose and organic acids such as glycolic acid, lactic acid, formic acid, acetic acid, levulinic acid, and propionic acid existed. We also used filter paper, which was pure cellulose, for sub-critical water treatment to compare the above. According to these detail experiments, the reaction mechanism was proposed.
Furthermore, using commercial ion exchange resins and the chitosan adsorbent, which we developed, we tried to develop economical separation method of the products obtained by sub-critical water treatment of pulp sludge. Equilibria, adsorption rate, breakthrough curves, and elution curves for single component systems and multi-component systems were experimentally and theoretically investigated in detail. We found that these components could be separated by using the adsorbents.
We tested the possibility of speeding up the methane fermentation rate drastically by treating pulp sludge with sub-critical water. We used an aqueous acetic acid solution as a model solution and the solution obtained by treating the pulp sludge with sub-critical water and made clear that the sub-critical water treatment before methane fermentation increased the fermentation rate 10 times.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] Yoshida, H., O.Tavakoli: "Sub-critical Water Hydrolysis Treatment for Waste Squid Entrails and Production of Amino Acids, and Fatty Acids"Journal of Chemical Engineering of Japan. 37(2). 253-260 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., Y.Takahashi, M.Terashima: "A Simplified Reaction Model for Production of Oil, Amino Acids, and Organic Acids from Fish Meat by Hydrolysis under Sub-Critical and Supercritical Conditions"Journal of Chemical Engineering of Japan. 36(4). 441-448 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., O.Okamoto, H.Jitsukawa, T.Shigeta: "Complete Adsorptive Separation of L-Pyroglutamic Acid and L-Leucine Using Polyaminated Highly Porous Chitosan Bead - Equilibria -"Fundamentals of Adsorption. 7. 520-527 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., W.A.Galinada: "Equilibria for Adsorption of Phosphates on OH-type Strongly Basic Ion Exchanger"AIChE Journal. 48(10). 2193-2202 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之, 寺嶋正明, 高橋洋平: "亜臨界水加水分解法による魚肉の有機酸・アミノ酸への有価物化におよぼす反応条件の影響"廃棄物学会論文誌. 12(4). 163-167 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., Y.Takahashi, M.Terashima: "Reaction Kinetics in Production of Oil, Proteins, Organic Acids and Amino Acids from Fish, Meat by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 199-202 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., M.Atarashi, T.Shigeta: "Conversion of Entrails of Fish Waste to Valuable Resource by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 122-125 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Takatsuji, W., H.Yoshida: "Parallel Transport by Solid-Phase and Macropore Diffusion in a Polyaminated Highly Porous Chitosan Bead in Case of Acetic Acid and Lactic Acid"Journal of Chemical Engineering of Japan. 34(1). 55-65 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之(分担): "化学便覧 第6版 応用化学編"丸善. 1709 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之(分担): "食品への超臨界流体応用ハンドブック"サイエンスフォーラム. 213 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之(分担): "微生物利用の大展開"エヌ・ティー・エス. 1189 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之(分担): "超臨界流体のすべて"テクノシステム. 656 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 吉田弘之(分担): "ゼロエミッション型産業をめざして 産業における廃棄物再資源化の動向"シーエムシー. 350 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., O.Tavakoli: "Sub-critical Water Hydrolysis Treatment for Waste Squid Entrails and Production of Amino Acids, Organic Acids, and Fatty Acids"J.Chem.Eng.Japan. 37(2). 253-260 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., Y.Takahashi, M.Terashima: "A Simplified Reaction Model for Production of Oil, Amino Acids, and Organic Acids From Fish Meat by Hydrolysis under Sub-Critical and Supercritical Conditions"J.Chem.Eng.Japan. 36(4). 441-448 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., O.Okamoto, H.Jitsukawa, T.Shigeta: "Complete Adsorptive Separation of L-pyroglutamic Acid and L-leucine Using Polyaminated Highly Porous Chitosan Bead -Equilibria"Fundamentals of Adsorption. 7. 520-527 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., W.A.Galinada: "Equilibria for Adsorption of Phosphates on OH-Type Strongly Basic Ion Exchanger"AIChE J.. 48(10). 2193-2202 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida H., M.Terashima, Y.Takahashi: "Effects of Reaction Condition on Conversion of Fish Meat into Organic Acids and Amino Acids by Sub-critical Water Hydrolysis"Haikibutsu Gakkai Ronbunshi. 12(4). 163-167 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., Y.Takahashi, M.Terashima: "Reaction Kinetics in Production of Oil, Proteins, Organic Acids and Amino Acids from Fish Meat by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 199-202 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Yoshida, H., M.Atarashi, T.Shigeta: "Conversion of Entrails of Fish Waste to Valuable Resources by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Forth International Conference on Solvo-Thermal Reaction. 122-125 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Takatsuji, W., H.Yoshida: "Parallel Transport by Solid-phase and Macropore Diffusion in a Polyaminated Highly Porous Chitosan Bead in case of Acetic Acid and Lactic Acid"J.Chem.Eng.Japan. 34(1). 55-65 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Yoshida, Y.Takahashi, M.Terashima: "A Simplified Reaction Model for Production of Oil, Amino Acids, and Organic Acids From Fish Meat by Hydrolysis under Sub-Critical and Supercritical Condit"J.Chem.Eng.Japan. 36,No.4. 441-448 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Yoshida, O.Tavakoli: "Sub-critical Water Hydrolysis Treatment for Waste Squid Entrails and Production of Amino acids, organic acids, and Fatty Acids"J.Chem.Eng.Japan. 37,No.2. 253-260 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kishimoto, H.Yoshida: "Adsorption of Acidic Peptide on Crosslinked Chitosan Fiber : Equilibria"Proc.3rd Pac.Basin Conf.Ads.Sci.Tech.. 458-462 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Kitahara, W.Galinada, H.Yoshida: "Equilibria for Adsorption of H_3PO_4,NaH_2PO_4,Na_2HPO_4, and Na_3PO_4 on Highly-Porous PEI Chitosan Resin"Third Intl.Conf.Ion Exch.. 13. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 北原浩之, Wilmer A.Galinada, 吉田弘之: "超多孔性PEIキトサン樹脂におけるH3PO4、NaH2PO4、Na2HPO4及びNa3PO4の吸着平衡"化学工学会第68年会研究発表講演要旨集. S105. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 吉田弘之, 片山裕紀: "亜臨界水・超臨界水処理による廃木材の資源・エネルギー化"化学工学会第36回秋季大会講演要旨集. I1A01. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 吉田弘之, 中橋知美: "亜臨界水処理による肉骨粉の無害化と資源化"化学工学会第36回秋季大会講演要旨集. I1A02. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Yoshida, M.Sai, O.Tavakoli: "Detecting Heavy Metal Ions Concentrations in Scallop Viscera Wastes and Recovery of Those Metals Using Sub- and Supercritical Water Treatments"化学工学会第36回秋季大会講演要旨集. I1A03. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 吉田弘之, 岡本織江: "PEIキトサンビーズによるピログルタミン酸およびアミノ酸の完全吸着分離"化学工学会第36回秋季大会講演要旨集. V3A06. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] O.Tavakoli, H.Yoshida: "Trans-Esterification of Fatty Acids from Squid Oil by Using Trimethylsulfonium Hydroxide (TMSH)"化学工学会第68年会研究発表講演要旨集. G307. (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 吉田弘之(分担): "化学便覧 第6版 応用化学編"日本化学会編. 1709 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 吉田弘之(分担): "第9回実践化学工学講座"化学工学会関西支部編. 434 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Yoshida et al.: "Complete Adsorptive Separation of L-pyroglutamic Acid and L-leucine Using Polyaminated Highly Porous Chitosan Bead -Equilibria -"Fundamentals of Adsorption. 7. 520-527 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Yoshida et al.: "Equilibria for Adsorption of Phosphates on OH-Type Strongly Basic Ion Exchanger"AIChE J.. 48. 2193-2202 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Yoshida et al.: "Sub-critical Water Hydrolysis Treatment for Waste Squid Entrails and Production of Amino Acids, Organic Acids, and Fatty Acids"Proceedings of 9^<th> Asian Pacific Confederation of Chemical Engineering (APCChE) Congress. 260 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Yoshida et al.: "Effective Recovery of Harmful Metal Ions from Squid Wastes Using Sub-critical and Supercritical Water Treatments"Proceedings of 5^<th> International Conference on Solvo-Thermal Reactions. 67-70 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 吉田弘之(分担): "食品への超臨界流体応用ハンドブック"サイエンスフォーラム. 213 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 吉田弘之(分担): "微生物利用の大展開"エヌ・テイー・エス. 1189 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 吉田弘之(分担): "超臨界流体の全て"テクノシステム. 656 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.YOSHJDA et al.: "Parallel Transport by Solid-Phase and Macropore Diffusion in a Polyaminated Highly Porous Chitosan Bead in Case of Acetic Acid and Lactic Acid."J.Chem.Eng.Japan. 34・1. 55-65 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.YOSHIDA et al.: "Conversion of Entrails of Fish Waste to Valuable Resources by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 122-125 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.YOSHJDA et al.: "Reaction Kinetics in Production of Oil, Proteins, Organic Acids and Amino Acids from Fish Meat by Sub-Critical Water Hydrolysis"Proceedings of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 199-202 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.YOSHIDA et al.: "Adsorption of C02 on Composites of Strong and Weak Basic Anion Exchange Resin and. Chitosan"J.Chem.Eng.Japan. 35・1. 32-39 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 吉田弘之: "個別生産プロセスにおけるアウトプット-インプット,インプット-アウトプット解析"環境科学会誌(ゼロエミッション特集号). 14・4. 333-343 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 吉田弘之: "ゼロエミッションを目指した地域物質循農ネットワークの構築とシナリオ策定手法"環境科学会誌(ゼロエミッション特集号). 14・4. 391-401 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 吉田弘之: "亜臨界水加水分解法による魚肉の有機酸・アミノ酸への有価物化に及ぼす反応条件の影響"廃棄物学会論文誌. 12・4. 163-167 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 吉田弘之: "ゼロエミッション型産業をめざして 産業における廃棄物再資源化の動向"シーエムシー. (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2021-04-07  

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