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Materials for new semiconductor lasers; atomically-controlled, growth of rare-earth-doped III-V semiconductors with high quality

Research Project

Project/Area Number 13555002
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University (2003)
Nagoya University (2001-2002)

Principal Investigator

FUJIWARA Yasufumi  Osaka University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (10181421)

Co-Investigator(Kenkyū-buntansha) TAKAHEI Ken-ichiro  Anritsu Co., Central Research Center, Head Researcher, 研究所, 主席研究員
TAKEDA Yoshikazu  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (20111932)
YOSHIDA Hiroshi  Osaka University, he Institute of Scientific and Industrial Research, Professor, 産業科学研究所, 教授 (30133929)
野々垣 陽一  岡崎国立共同研究機構, 分子科学研究所, 助手 (40300719)
田渕 雅夫  名古屋大学, 工学研究科, 講師 (90222124)
町田 英明  (株)トリケミカル研究所, 技術開発本部, 主席研究員
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 2003: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2002: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2001: ¥7,700,000 (Direct Cost: ¥7,700,000)
Keywordsrare-earth-doped III-V / semiconductors / materials for new semiconductor lasers / atomically-controlled growth / stimulated emission / erbium / doubleheterostructures / control of heterointerface
Research Abstract

Rare-earth (RE) doped semiconductors have gained significant attention as a promising new class of materials that emit light from the RE 4f shell by means of electrical injection, in which the energy of electron-hole pairs is transferred to the RE shell. The intra-4f shell transitions of RE ions give rise to sharp emission lines whose wavelengths are largely independent of both the host materials and temperature. This stability occurs because the filled outer 5s and 5p electron shells. screen transitions within the inner 4f electron shell from the interaction with the host. The intra-4f shell transitions from the first excited state (4^I_<13/2>) to the ground state (4^I_<15/2>) of Er^<3+> ions at around 1.5 μm is of special interest because the wavelength matches the minimum loss region of silica fibers used in optical communications.
In this research project, we investigated atomically-controlled growth of Er-doped GaAs with high quality for new-type light-emitting devices. Results obt … More ained experimentally are summarized as follows
1)By optimizing reactor structure and growth temperature, the abrupt change in composition at the heterointerface consisting of different group-V elements was successfully obtained.
2)Er-20 configuration was selectively formed by codoping Er and O to GaAs, resulting in the increase in PL intensity by two orders in magnitude: The amount of O in growth ambient played an important role for the intensity increase.
3)Er-related luminescence was observed in GaInP/GaAs : Er, O/GaAs doubleheterostructures by injecting, current at room temperature. The EL spectrum was dominated by Er-20 lines, suggesting a successful formation of the Er-20 center and a preferential excitation of the center by current injection.
4)The current density dependence of the EL intensity revealed an extremely large excitation cross section of Er ions by current injection, approximately 10^<-15> cm^2. The large excitation cross section was confirmed by time-resolved measurements. of the EL intensity. It is by two orders in magnitude larger than that of Er-doped Si LEDs (6x10^<-17> cm^2). Less

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] 藤原 康文: "希土類添加III-V族半導体による電流注入型発光デバイス"応用物理. 73(2). 224-228 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.FUJIWARA: "Room-temperature 1.5μm electroluminescence from GaInP/Er,O-codoped GaAs/GaInP double heterostructure injection-type light emitting diodes grown by OMVPE"Materials Science and Engineering B. 105(1-3). 57-60 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.FUJIWARA: "Extremely large Er excitation cross section in Er,O-codoped GaAs light emitting diodes grown by organometallic vapor phase epitaxy"Materials Research Society Symposium Proceedings, Progress in Semiconductors II, Electronic and Optoelectronic Applications. 744. 149-154 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.KOIZUMI: "Room-temperature electroluminescence properties of Er,O-codoped GaAs injection-type light emitting diodes grown by organometallic vapor phase epitaxy"Applied Physics Letters. 83(22). 4521-4523 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.KOIZUMI: "Room-temperature 1.54μm light emission from Er,O-codoped GaAs/GaInP LEDs grown by low-pressure organometallic vapor phase epitaxy"Japanese Journal of Applied Physics. 42(4B). 2223-2225 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.KOIZUMI: "Luminescence properties of Er,O-codoped GaAs/GaInP double heterostructures grown by organometallic vapor phase epitaxy"Physica B. 308-310. 891-894 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, Y.Fujiwara, A.Urakami, K.Inoue, T.Yoshikane, Y.Takeda: "Effects of active layer thickness on Er excitation cross section in GaInP/GaAs : Er, O /GaInP DH structure light-emitting diodes"Physica B. 340-342. 309-314 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Fujiwara, A.Koizumi, K.Inoue, A.Urakami, T.Yoshikane, Y.Takeda: "Extremely large Er excitation cross section in Er, O-codoped GaAs light emitting diodes grown by organometallic vapor phase epitaxy"Materials Research Society Symposium Proceedings, Progress in Semiconductors II--Electronic, Optoelectronic Applications (edited by B.D.Weaver, M.O.Manasreh, C.C.Jagadish, S.Zollnei) (Materials Research Society) (Pittsburgh). Vol.744. 149-154 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Fujiwara, A.Koizumi, A.Urakami, T.Yoshikane, K.Inoue, Y.Takeda: "Room-temperature 1.5μm electroluminescence from GaInP/Er, O-codoped GaAs/GaInP double heterostructure injection-type light emitting diodes grown by organometallic vapor phase epitaxy"Materials Science, Engineering B. 105(1-3). 57-60 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, Y.Fujiwara, A.Urakami, K.Inoue, T.Yoshikane, Y.Takeda: "Room-temperature electroluminescence properties of Er, O-codoped GaAs injection-type light emitting diodes grown by organometallic vapor phase epitaxy"Applied Physics Letters. 82(22). 4521-4523 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Fujiwara, Y.Nonogaki, R.Oga, A.Koizumi, Y.Takeda: "Reactor structure dependence of interface abruptness in GaInAs/InP, GaInP/GaAs grown by organometallic vapor phase epitaxy"Applied Surface Science. 216. 564-568 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, Y.Fujiwara, K.Inoue, T.Yoshikane, A.Urakami, Y.Takeda: "Growth sequence dependence of GaAs-on-GaInP interface characteristics in GaAs/GaInP/GaAs structures grown by low-pressure organometallic vapor phase epitaxy"Applied Surface Science. 216. 560-563 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, Y.Fujiwara, K.Inoue, A.Urakami, T.Yoshikane, Y.Takeda: "Room-temperature 1.54μm light emission from Er, O-codoped GaAs/GaInP LEDs grown by low-pressure organometallic vapor phase epitaxy"Japanese Journal of Applied Physics. 42(4B). 2223-2225 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.Yoshikawa, S.Okubo, H.Ohta, T.Koide, T.Kawamoto, Y.Fujiwara, Y.Takeda: "ESR study of heavily doped GaAs : Er grown by organometallic vapor phase epitaxy"EPR in the 21st Century : Basics, Applications to aterial, Life, Earth Sciences (edited by A.Kawamori, J.Yamauchi, H.Ohta) (Elsevier, Amsterdum). 302-305 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, H.Moriya, N.Watanabe, Y.Nonogaki, Y.Fujiwara, Y.Takeda: "Luminescence properties of Er, O-codoped InGaAs/GaAs multi-quantum-well structures grown by organometallic vapor phase epitaxy"Applied Physics Letters. 80(9). 1559-1561 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] P.G.Eliseev, S.V.Gastev, A..Koizumi, Y.Fujiwara, Y.Takeda: "Stimulated emission from GaAs : Er, O at 1538nm"Quantum Electronics. 31(11). 962-964 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Koizumi, N.Watanabe, K.Inoue, Y Fujiwara, Y.Takeda: "Luminescence properties of Er, O-codoped GaAs/GaInP double heterostructures grown by organometallic vapor phase epitaxy"Physica B. 308-310. 891-894 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Fuj iwara, T.Koide, Y.Takeda: "Luminescence properties of Er, O-codoped GaP grown by organometallic vapor phase epitaxy"Materials Science, Engineering B. 81. 153-156 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 藤原 康文: "希土類添加III-V族半導体による電流注入型発光デバイス"応用物理. 73(2). 224-228 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.FUJIWARA: "Room temperature 1.5 m electroluminescnence from GaInP/Er,O-codoped GaAs/GaInP double heterostructure injection-type light emitting diodes grown by organometallic vapor phase epitaxy"Materials Science and Engineering B. 105(1-3). 57-60 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.FUJIWARA: "Reactor structure dependence of interface abruptness in GaInAs/InP and GaInP/GaAs grown by organometallic vapor phase epitaxy"Applied Surface Science. 216. 564-568 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.FUJIWARA: "Extremely large Er excitation cross section in r,O-codoped GaAs light emitting diodes grown by organometallic vapor phase epitaxy"Materials Research Society Symposium Proceedings, Progress in Semiconductors II, Electronic and Optoelectronic Applications. 744. 149-154 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.KOIZUMI: "Room-temperature electroluminescence properties of Er,O-codoped GaAs injection-type light-emitting diodes grown by organometallic vapor phase epitaxy"Applied Physics letters. 83(22). 4521-4523 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.KOIZUMI: "Room-temperature 1.54μm light emission from Er,O-codoped GaAs/GaInP LEDs-grown by low-pressure organometallic vapor phase epitaxy"Japanese Journal of Applied Physics. 42(4B). 2223-2225 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.FUJIWARA: "Extremely large Er excitation cross section in Er, O-codoped GaAs light emitting diodes grown by organometallic vapor phase epitaxy"Materials Research Society Symposium Proceedings, Progress in Semiconductors II, Electronic and Optoelectronic Applications. 744(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.FUJIWARA: "Reactor structure dependence of interface abruptness in GaInAs/InP and GaInP/GaAs grown by organometallic vapor phase epitaxy"Applied Surface Science. (印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.KOIZUMI: "Room-temperature 1.54μm light emission from Er, O-codoped GaAs/GaInP LEDs grown by low-pressure organometallic vapor phase epitaxy"Japanese Journal of Applied Physics. 42(4B)(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.AKANE: "AFM observation of OMVPE-grown ErP on InP substrates using a new organometal Er(EtCp)_3"Applied Surface Science. (印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.YOSHIKAWA: "ESR study of heavily doped GaAs : Er grown by organometallic vapor phase epitaxy"EPR in the 21st Century : Basics and Applications to Material, Life and Earth Sciences. 302-305 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.KOIZUMI: "Luminescence properties of Er, O-codoped GaAs/GaInP double heterostructures grown by organometallic vapor phase epitaxy"Applied Physics Letters. 80(9). 1559-1561 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.KOIZUMI: "Luminescence properties of Er,O-codoped GaAs/GaInP double heterostructures grown by organometallic vapor phase epitaxy"Applied Physics Letters. 80(9). 1559-1561 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.FUJIWARA: "Luminescence properties of Dy-doped GaAs grown by organometallic vapor phase epitaxy"Physica B. 308-310. 796-799 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] A.KOIZUMI: "Luminescence properties of Er,O-codoped GaAs/GaInP double heterostructures grown by organometallic vapor phase epitaxy"Physica B. 308-310. 891-894 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.FUJIWARA: "Luminescence properties of Er,O-codoped GaP grown by organometallic vapor phase epitaxy"Materials Science and Engineering B. 81. 153-156 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.OHTA: "Codoping effects of O_2 into Er-doped InP epitaxial layer grown by OMVPE"Physica E. 10(1-3). 399-402 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.KOIDE: "OMVPE growth and properties of Dy-doped III-V semiconductors"Physica E. 10(1-3). 406-410 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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