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Arsenic, antimony and mercury chemical forms and behavior in volcanic emissions

Research Project

Project/Area Number 13640490
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 地球化学
Research InstitutionKagoshima University

Principal Investigator

SAKAMOTO Hayao  Kagoshima University, Faculty of Science, Professor, 理学部, 教授 (50041231)

Co-Investigator(Kenkyū-buntansha) ANAZAWA Katsuro  Kagoshima University, Faculty of Science, Research associate, 理学部, 助手 (90325762)
TOMIYASU Takashi  Kagoshima University, Faculty of Science, Associate professor, 理学部, 助教授 (60217552)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2003: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2002: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2001: ¥2,400,000 (Direct Cost: ¥2,400,000)
KeywordsMercury / Arsenic / Antimony / Fumarolic gases / Environmental samples / 噴気孔ガス凝縮水 / 火山ガス凝縮水 / ヒ素・アンチモン / 火山発散物 / 凝縮水 / 非凝縮ガス
Research Abstract

21 fumarolic gases which temperature differed from Satsuma Iwojima Volcano were collected. The mercury concentration in the condensed water is 120〜135,000 ng/l. There was high positive correlation between mercury and chloride ions concentration. This fact indicates the possibility in which the mercury in the fumarolic gas is discharged in the form of chloride. However, the possibility of the emission in the form of the chloride was denied that mercury chemical form in fumarolic gas from the calculation of chemical equilibrium using thermodynamic data. However, mercury emission root is not simple, because there is no correlation between fumarolic temperature and mercury concentration. The result which the mercury existed in the reductive fumarolic gas in the form of metallic mercury vapor, as the temperature is high, was obtained. And, the speciation analysis method of geothermal water mainly on South Kyushu and surface water around the mine and arsenic in the groundwater, antimony were examined in detail, and the analysis method was established. As the result, arsenic, antimony reflect the geologic feature of the region. And, it was proven that the chemical form of the low oxidation condition was leading for arsenic, antimony in reductive atmosphere such as the underground.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] H.Sakamoto, S.Fujita, T.Tomiyasu, K.Anazawa: "Mercury concentration in fumarolic gas condensates and mercury Chemical forms in fumarolic gases"Bull.Volcanol.Japan. 48,1. 27-33 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Tomiyasu, M.Okada, R.Imura, H.Sakamoto: "Vertical variations in the concentration of mercury in soils Around Sakurajima Volcano, Southern Kyushu, Japan"Sci.Total Environment. 304. 221-230 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 藤田俊一, 坂元隼雄: "霧島火山硫黄谷・林田周辺地区熱水系の形成機構の地球化学的研究"温泉科学. 52. 20-28 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Sakarnoto, Y.Susa, H.Ishiyama, T.Tomiyasu, K.Anazawa: "Determination of trace amounts of total arsenic in environmental Samples by hydride generation flow injection-AAS using a mixed acid"Anal.Sciences. 17. 1067-1071 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Anazawa, Y.Kaida, Y.Shinomura, T.Tomiyasu, H.Sakamoto: "Hevy metal distribution in river waters and sediments around a "firefly Village", Shikoku, Japan : Application of multivariate analysis"Anal.Sciences. 52. 887-890 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Sakamoto, S.Fujita, T.Tomiyasu, Anazawa: "Mercury concentration in fumarolic gas condensates And mercury chemical forms in fumarolic gases"Bull.Volcanol.Soc.Japan. 48. 27-33 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Tomiyasu, M.Okada, R.Imura, H.Sakamoto: "Vertical variations in the concentration of Mercury in soils around Sakurajima Volcano, Southern Kyushu, Japan"Sci.Total Environment. 304. 221-230 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Sakamoto, Y.Susa, H.Ishiyama, T.Tomiyasu, Anazawa: "Determination of trace amounts of total arsenic in Environmental samples by hydride generation Flow injection-AAS using a mixed acid"Anal.Sciences. 17. 1067-1071 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Anazawa, Y.Kaida, Y.Shinomura, T.Tomiyasu, H.Sakamoto: "Heavy metal distribution in river waters and Sediments around a "firefly Village", Shikoku, Japan : Application of multivariate analysis"Anal.Sciences. 20. 79-84 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Sakamoto, S.Fujita, T.Tomiyasu, K.Anazawa: "Mercury concentration in fumarolic gas condensates and mercury Chemical forms in fumarolic gases"Bull.Volcanol.Soc.Japan. 48,1. 27-33 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Tomiyasu, M.Okada, R.Imura, H.Sakamoto: "Vertical variations in the concentration of mercury in soils around Sakurajima Volcano, Southern Kyushu, Japan"Sci.Total Environment. 304. 221-230 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 藤田俊一, 坂元 隼雄: "霧島火山硫黄谷・林田周辺地区熱水系の形成機構の地球化学的研究"温泉科学. 52,1. 20-28 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Sakamoto, Y.Susa, H.Ishiyama, T.Tomiyasu, K.Anazawa: "Determination of trace amounts of total arsenic in environmental samples by hydride generation flow injection-AAS using a mixed acid."Anal.Sciences. 17. 1067-1071 (2001)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Anazawa, Y.Kaida, Y.Shinomura, T.Tomiyasu, H.Sakamoto: "Heavy-metal distribution in river waters and sediments around a "firefly Village", Shikoku, Japan : Application of multivariate analysis."Anal.Sciences. 20. 79-84 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 清原拓二, 穴澤活郎, 坂元隼雄, 冨安卓滋: "緑茶殻及びコーヒー豆殻への水銀吸着能"分析化学. 52,10. 887-890 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Hayao Sakamoto, Shun-ichi, Fujita, Takashi Tomiyasu, Katsuro Anazawa: "Mercuy concentration in fumarolic gas condensates and mercury chemical forms in fumarolic gases"Bull. Volcanol. Soc. Japan. 48, No1. (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Sakamoto, et al.: "Determination of trace amounts of total arsenic in environmentalsamples by hydride generation flow injection-AAS using a mixedacid as a pretreatment agent"Analytical Sciences. 17. 1067-1071 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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