| Project/Area Number |
13640510
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Physical chemistry
|
|---|
| Research Institution | KYOTO UNIVERSITY |
|---|
Principal Investigator |
WAKABAYASHI Tomonari Kyoto Univ., Dept.Chem., Lecturer, 大学院・理学研究科, 助手 (30273428)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
WASHIDA Nobuaki Kyoto Univ., Dept.Chem., Professor, 大学院・理学研究科, 教授 (70101045)
MOMOSE Takamasa Kyoto Univ., Dept.Chem., Associate Professor, 大学院・理学研究科, 助教授 (10200354)
|
|---|
| Project Period (FY) |
2001 – 2003
|
| Project Status |
Completed (Fiscal Year 2003)
|
| Budget Amount *help |
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2003: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2002: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2001: ¥1,500,000 (Direct Cost: ¥1,500,000)
|
|---|
| Keywords | Carbon cluster / Photodissociation / Spectroscopy / Matrix isolation / Infrared absorption / UV / VIS absorption / Fullerene / Polyyne / 赤外スペクトル / 紫外可視スペクトル |
|---|
| Research Abstract |
The photoinduced molecular processes of small carbon clusters in cold rare gas matrices are investigated. The purpose of this project is to determine the specific chemical reaction channels of linear and cyclic clusters and to use the knowledge for identification of the unknown UV/VIS absorption bands of the relevant clusters. In this project, we found that the UV absorption band at 235 nm of a carbon-containing Ne matrix at 6 K diminished upon irradiation with 235 nm photons. At the same time, we observed that the IR bands of linear C6 at 1959 cm-1 and 1199 cm-1 diminished concomitantly. Form this observation we concluded that the UV band is attributable to linear C6. Further investigations of the selective excitation of the UV and VIS bands of matrix-isolated carbon clusters lead to a finding of the new electronic system of C2 in a condensed phase that shows a matrix-dependent characteristic relaxation channel through fluorescent deactivations.
|
