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Vibrational Dynamics of Electronic Excited Molecules

Research Project

Project/Area Number 13640518
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionWaseda University

Principal Investigator

TSUCHIYA Soji  Waseda University, Advanced Research Institute for Science and Engineering, Professor, 理工学総合研究センター, 教授 (40012322)

Co-Investigator(Kenkyū-buntansha) YAMAKITA Nami  Faculty of Science, Japan Women's Univ., Assistant, 理学部, 助手 (90277674)
OBI Kinichi  Faculty of Science, Japan Women's Univ., Professor, 理学部, 教授 (10016090)
TAKAHASHI Hiroaki  Waseda Unviersity, School of Science and Engineering, Professor, 理工学部, 教授 (40063622)
Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2002: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2001: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsVibronic State / Acetylene / Anharmonic coupling / Photodissociation / Predissociation / 前期解離
Research Abstract

Vibrational and reaction dynamics of electronic excited acetylene have been investigated.
1. The vibrational level structure of acetylene in the electronic excited A^^〜 state was believed to be the progressions of the 2^n3^m vibrational states. However, in this work it was proved that the V_3' mode couples anharmonically with the ungerade v_4'/v_6' mode to form a polyad structure composed of the 2^m3^n, 2^m3^<n-1>(4/5)^2, 2^m3^<n-2>(4/6)^4, ………. The same type of the anharmonic coupling was found for the ungerade vibrational states which were investigated by an IR-UV double resonance spectroscopy. In this case, the (4/6) states having odd quantum numbers couple with the 3^n state.
2. The predissociation rate constants of acetylene in respective rovibronic levels of the A^^〜 state were determined through observation of the spectral line-widths. The rate constants were found to be independent of the vibrational parity gerade or ungerade. This can be attributed to the anharmonic coupliig between the V_3' and V_4'/V_6' modes which causes the gerade and ungerade states to have a similar vibrational chracteristics.
3. It was found that the triplet state-mediated predissociation of excited acetylene toward C_2H(X^^〜)+H ceases around the excitation energy of 51100 cm^<-1> which is far beyond the adiabatic dissociation threshold of the A state. At this energy, acetylene still predissociates at a rate of around 10^<10> s^<-1> to form C_2H(A^^〜) + H.
4. A new experimental technique, Differential Temperature Laser Induced Fluorescence Spectroscopy, was developed which is capable of separating overlapping cold and hot bands of a LIF spectrum.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] N.Yamakita, S.Tsuchiya: "Zeeman quantum beat observed by IR-UV double resonance LIF spectroscopy of acetylene in the ^1A_u3v_3'+v_4' and 3v_3'+v_6' ungerade vibrational states"Chem.Phys.Lett.. 348・1. 53-59 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Yamakita et al.: "Predissociation of Excited Acetylene in the A^1A_u State around the Adiabatic Dissociation Threshold as Studied by LIF and H-Atom Action Spectroscopy"J.Phys.Chem.A. 107(印刷中). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.J.Merer et al.: "New vibrational assignments in the A^1A_u-X^1Σ_g^+ electronic transition of acetylene"Mol.Phys.. (印刷中). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Yamakita and S. Tsuchiya: "Zeeman Quantum beat observed by IR-UV double resonance LIF spectroscopy of acetylene in the A^1A_0 3v_3+v_6 and 3v_3+v_4 ungerade vibrational states"Chem. Phys. Lett.. 348. 53-59 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Yamakita, S. Iwamoto and S. Tsuchiya: "Predissociation of Excited Acetylene in the A^3 A_0 State around the Adiabatic Dissociation Threshold as Studied by LIF and H-atom Action Spectroscopy"J. Phys. Chem. A. 107, in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.J. Merer, N. Yamakita, S. Tsuchiya, J.R Stanton, Z. duan and R.W. Field: "New vibrational assignments in the A^1 A_U-X^1Σ_g^+ electronic transition of acetylene ; the V_1 frequency"Mol. Phys.. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Yamakita et al.: "Predissociation of Excited Acetylene in the A^1A_u State around the Adiabatic Dissociation Threshold as Studied by LIF and H-atom Action Spectroscopy"J. Phys. Chem. A. 107(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.J.Merer et al.: "New vibrational assignments in the A^1A_u-X^1Σ_g^+ electronic transition of acetylene"Mol. Phys.. (印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] N.Yamakita, S.Tsuchiya: "Zeeman quantum beat observed by IR-UV double resonance LIE spectroscopy of acetylene in the ^1Au3ν_3'+ν_4' and 3ν_3'+ν_6' ungerade vibrational states"Chem. Phys. Lett.. 348・1. 53-59 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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