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Synthesis, Structure, and Reactivities of Germylborates

Research Project

Project/Area Number 13640542
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionGakushuin University

Principal Investigator

MOCHIDA Kunio  Faculty of Science, Professor, 理学部, 教授 (20118772)

Co-Investigator(Kenkyū-buntansha) NANJO Masto  Faculty of Science, Assistant Professor, 理学部, 助手 (50302352)
Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
KeywordsGermylborate / Ate complex / X-ray diffraction analysis / Catalytic reaction / X-線構造解析 / ゲルマニウム / ホウ素 / X線結晶構造 / 水溶性 / 反応特異性
Research Abstract

The structure and reactivity of lithium(germyl)triphenylborates, prepared from unsolvated germyllithium and triphenylboran, with organic substrates in methanol were investigated. The germylborates reacted with acetylenes, organic halides, and acyl halides to give the corresponding germyl-substituted compounds. From the reaction with carbonyl compounds, esters, carboxylic acids, and alkenes, germylborates were completely recovered.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (5 results)

All Other

All Publications (5 results)

  • [Publications] Masato Nanjo: "Reactivities of Triethylgermyl borate in Methanol"Chem. Lett.,. 1086-1087 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Masato Nanjo: "Polymeric and Dimeric Structures of Lithium(Triethylgermyl)(triphenyl)borate : Synthesis and Characterization"Inorg. Chem. Commun.,. (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Masato Nanjo, Kazuhiko Matsudo, and Kunio Mochida: "Reactivities of Triethylgermylborate in Methanol"Chem.Lett.. 2001. 1086-1087

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Masato Nanjo, Kazuhiko Matsuo, and Kunio Mochida: "Polymeric and Dimeric Structures of Lithium (triethykgermyl)(triphenyl)borate : Synthesis and Characterization"Inorg.Chem.Commun.. in press. (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 南条真佐人: "Reactivities of Friethylgermylborate in Methanol"Chem. Lett.. 1086-1087 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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