| Project/Area Number |
13650331
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Electronic materials/Electric materials
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| Research Institution | Tohoku University |
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Principal Investigator |
KITAKAMI Osamu Tohoku University, Institute of Multidisciplinary Research for Advanced Materials, Associate Professor, 多元物質科学研究所, 助教授 (70250834)
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| Co-Investigator(Kenkyū-buntansha) |
SHIMADA Yutaka Tohoku University, Institute of Multidisciplinary Research for Advanced Materials, Professor, 多元物質科学研究所, 教授 (00006157)
OKAMOTO Satoshi Tohoku University, Institute of Multidisciplinary Research for Advanced Materials, Assistant Professor, 多元物質科学研究所, 助手 (10292278)
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| Project Period (FY) |
2001 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2002: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2001: ¥2,400,000 (Direct Cost: ¥2,400,000)
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| Keywords | magnetic memory / nanoparticles / thermal agitation / surface anisotropy / magnetic recording / hydrogenation |
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| Research Abstract |
We have studied magnetic surface anisotropy (MSA) at 3d transition metals (TM)/Pd, Pt, SiO_2 interfaces, and investigated the surface effect on the effective magnetic anisotropy of nanopartocles.
1. MSA at TM/Pd, Pt, interfaces The MSA strongly depends on the valence electron number of TM and reaches a maximum of 〜0.5 erg/cm^2 for TM = Co, which is consistent with the first principles calculation so far reportd. R is also found that addition of very small amount of rare earth elements (RE) into TM omsiderahly enhanoes the MSA due to the enhancement of orbital moment of Co.
2. MSA at TM/nonmagnetic oxide (SiO_2) The MSA at TM/SiO_2 strongly depends on the valence electron number of TM. With increasing the valence electron number from TM = Fe, Co to Ni the easy axis changes from the film normal to the film plane. The maximum perpendicular anisotropy reaches 0.4〜0.8 erg/cm2 for TM = Fe, Co, which is one order of magnitude higher than the magnetocrystalline anisotropy of bulk bcp Co. The dep
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endence of the MSA on the valence electron number of TM has been successfully explained by considering the electronic states of TM combined with SiO_2 at the interface.
3. MSA in TM/ nonmagnetic oxide granular films It is found that Fe/SiO_2 granular films (Fe particle size 5〜30 nm) exhibit very high coercibity of Hc〜500 Oe which is much higher than the anisotropy field (〜100 Oe) of bulk bccFe. By considering the measured MSA of 0.4 erg/cm^2 for Fe/SiO_2 we have quantitatively explained their large Hc and the particle size dependence. This result indicates that MSA effectively enhances the magnetic anisotropy of nanoparticles embedded in granular films.
4. MSA in TM nanoparticles We have prepared isolated TM (Fe, Co, Ni) nanopartides with the diameter of D = 5〜30 nm and determined their magnetic anisotropy by the newly developed anisotropy measurement method. It is found that all the nanoparticles exhibit strong uniaxial magnetic anisotropy compared with that of bulk materials. Such anisotropy enhanoement is mainly due to the surface effect. From the micromagnetic calculations and experiments, we have confirmed that the magnetic behaviors of the nanopartivles perfectly follows the coherent rotation (Stoner Wohlfarth) model when the particle diameter Dis less than 15 nm.
All the results mentioned above indicate that magnetic surface anisotropy significantly enhanoes the effective magnetic anisotropy of nanopartocles even when the bulk anisotropy is quite small. Such nanoparticles with large surface anisotropy would be very promising for development of ultra high density recording media. Less
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