| Project/Area Number |
13650914
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
FUCHIGAMI Toshio Tokyo institute of Technology, Interdisciplinary Graduate School of Science and Engineering, Professor, 大学院・総合理工学研究科, 教授 (10016701)
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| Co-Investigator(Kenkyū-buntansha) |
ATOBE Mahito Interdisciplinary Graduate School of Science and Engineering, Lecturer, 大学院・総合理工学研究科, 講師 (90291351)
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| Project Period (FY) |
2001 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 2002: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2001: ¥1,800,000 (Direct Cost: ¥1,800,000)
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| Keywords | Green Chemistry / lonic liquide / Room temperature molten salts / Polythiophene / Polypyrrole / Electropolymerization / Conducting polymer in Electrochemical fluorination / イオン性液体 / イミダゾール塩 / キャパンタ / 常温溶媒塩 / フッ素化エーテル / フッ素化ラクトン / フッ素化環状カーボナート / フッ素化フタリド |
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| Research Abstract |
Solvent free electroorganic synthesis is highly desirable from an enviromental aspect. In this project, we have achieved the following subjects.
1) Hardly oxidizable cyclic carbonates and lactones were anodically fluorinated in Et_4NF・4HF without any solvents with execellent current efficiencies. Biologically interesting phthalides were also successfully fluorinated only in a mixture of imidazolium molten salts and Et_4NF・nHF (n=4,5).
2) Conducting polymers were prepared by anodic oxidation of pyrrole and thiophene in room temperature molten salts like 1-ethyl-3-methy limidazolium trifloromethanesulfonate. The morphological stuructures of polypyrrole and polythiophene prepared in the room temperature molten salts are quite different from those obtatined in organic solvents and water. The electrochemical capacity and electroconductivity were greatly increased.
3) We have demonstrated the reuse of room temperature molten salts for organic electrosynthesis.
Thus, we have achieved solvent free organic etectrosynthesis and the results seem to be useful for future study on solvent free organic electrode processes.
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