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Synthesis of new degradable polymers containing azo-group in a polymer chain

Research Project

Project/Area Number 13650940
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionFukui University of Technology

Principal Investigator

KAMACHI Mikiharu  Fukui University of Technology, Professor, 工学部, 教授 (40028163)

Co-Investigator(Kenkyū-buntansha) HARADA Akira  Osaka University Graduate School of Science, Professor, 大学院・理学研究科, 教授 (80127282)
Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2002: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2001: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsAzabutadiene / Ionic Polymerization / Degradable Polymer / Stereoregular Polymer / Crystalline Polymer / Grignard Reagent / 1.4-trans-addition / Functional Polymer / アニオン重合 / アザブタジエン誘導体 / 結晶性ポリマー / 立体規則性
Research Abstract

Azine compounds (azabutadienes) are not polymerized by radical initiators or cationic initiators, but easily polymerized by anionic initiators. In the extension of this finding, anionic polymerizations of α, ω-dialkylazabutadiene were performed with various kinds of initiator, indicating that stereoregular polymers with 1,4-trans monomer unit were obtained with some of anionic initiators. Accordingly, the optimum conditions for the preparation of the stereoregular polymers was investigated by various kinds of anionic initiators, which indicates that alkyl magnesium iodide was the best initiator for the stereoregular polymer with high molecular weight. The thermal degradability of the polymers was investigated by DSC and thermogravitomeric analysis. The stereoregular polymers were completely decomposed to the corresponding olefins and nitrogen above 150℃.
The stereoregular have azo-group in trans-form, which can is allowed to isomerize reversibly from trans to cis under irradiation of UV light. The expansion and contraction of polymer molecule was found along with the isomerization from trans to cis. Practical application was investigated in this work.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (7 results)

All Other

All Publications (7 results)

  • [Publications] 蒲池幹治, 松田健太朗, 橋爪章仁: "アザブタジエン誘導体の重合-分子量および構造制御の検討"Polymer Preprints. 51. 357-357 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Mikiharu Kamachi, Kentaro Matsuda, Akihito Hashidsume: "Polymerization of Azabutadienes - Control of molecular weight and structure"Polymer Preprints, Japan. 51. 357 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 蒲池幹治, 松田健太朗, 橋瓜章仁: "アザブタジエン誘導体の重合-分子量および構造制御の検討"Polymer Preprints. 51. 357-357 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 蒲池幹治, 道下岳史, 原田 明: "アザブタジエン誘導体の重合とポリマーの熱分解性"Polym. Prepr. Japan. 50,7. 1194-1194 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Mikiharu.Kamachi: "Search for Highly Resolved Electron Spin Resonance Spectra of Transient Radical in Radical Polymerization"J. Polym. Sci., Polym. Chem.. 40,3. 269-285 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yamamoto, Y.Toda, T.Yamambe, M.Kamachi: "The Effects of tacticity of poly(vinyl alcohol)s on their reactivity"Res. Adv. Macromolecules. 2,1. 11-19 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Yamamoto, M.Kamachi, T.Yamambe, T.Tsukuda: "Solvent Effects and Substituent Effects on the Rate of Radical Polymerizations of Vinyl Esters"Res. Adv. Macromolecules. 2,1. 20-25 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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