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Mechanism of Adsorption of Endocrine Disruptors and their treatment by clay

Research Project

Project/Area Number 13660244
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Irrigation, drainage and rural engineering/Rural planning
Research InstitutionOsaka University (2003)
Kagawa University (2001-2002)

Principal Investigator

KAWASE Masaya (2003)  Osaka Univ., Grad.Sch.Pharm. Sci., Associate Prof., 薬学研究科, 助教授 (90224782)

石田 智之 (2001-2002)  香川大学, 農学部, 教授 (40184535)

Co-Investigator(Kenkyū-buntansha) ISHIDA Tomoyuki  Kagawa Univ., Fac.Agr., Prof., 農学部, 教授 (40184535)
川瀬 雅也  大阪大学, 薬学研究科, 助教授 (90224782)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2003: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2002: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2001: ¥2,500,000 (Direct Cost: ¥2,500,000)
KeywordsEndocrine Disruptors / Clay / Intercalation / Electrochemical treatment / Clay-coated Electrode / 粘土被服電極 / 粘土-有機複合体 / 吸着等温線 / 界面活性剤 / 誘電緩和 / 吸着
Research Abstract

The aim of this study is the prevention of diffusion and clean treatment of endocrine disruptors. 4-ethylphenol and pyrene were employed as model in this study. Absorbant is important for treatment of endocrine disruptors. We employed chemically modified clay as absorbant, and obtained following results.
1. Clay could adsorve model compounds.
2. XRD study showed that model compounds intercalated to clay layer.
3. Chemical modification of clay interlayer was not effective.
4. Chemical modification of clay interlayer affected the state of bound water in clay interlayer.
5. Model compounds could be reduced electrochemically by suspending clay.
From the result No.5, we can propose the novel electrochemical treatment system of endocrine disruptors.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] T.Ishida, M.Kawase 他3名: "Effects of the counterion on dielectric spectroscopy of a montmorillonite suspension over the frequency range 10^5〜10^<10>Hz"Journal of Colloid and Interface Science. 268. 121-126 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishida, M.Kawase et al.: "Effects of the counterion on dielectric spectroscopy of a montmorillonite suspension over the frequency range 10^5〜10^<10>Hz"Journal of colloid and Interface Science. 268(1). 121-126 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ishida, M.Kawase 他3名: "Effects of the counterion on dielectric spectroscopy of a montmorillonite suspension over the frequency range 10^5-10^6 Hz"Journal of Colloid and Interface Science. 268(1). 121-126 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 深田 和宏, 石田 智之: "モンモリロナイト分散液の誘電緩和:対イオン種の効果"日本化学会第83春季年会講演要旨集. 1-163 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Kawase, et al.: "Suppression of apoptosis in hepatocytes by fructose-modified dendrimers"T. Biomed, Materials Res.. 54. 519-524 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Umeda, et al.: "Homology study of two palyhydroxyalkanoate(PHA) synthases from oseudomonas aureofaciens"DNA sequence. 12. 281-284 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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