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自在に設計可能な分子ノギスによるグラフェンの層数に基づく分離

Research Project

Project/Area Number 13F03339
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Research Field Functional materials chemistry
Research InstitutionKyoto University (2014-2015)
Shiga University of Medical Science (2013)

Principal Investigator

小松 直樹  京都大学, 人間・環境学研究科(研究院), 教授 (30253008)

Co-Investigator(Kenkyū-buntansha) LIU GANG  京都大学, 人間・環境学研究科(研究院), 外国人特別研究員
LIU Gang  京都大学, 人間・環境学研究科(研究院), 外国人特別研究員
LIU Gang  滋賀医科大学, 医学部, 外国人特別研究員
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2015: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2014: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2013: ¥400,000 (Direct Cost: ¥400,000)
Keywordsフラーレン・ナノチューブ / 分子認識 / 分離
Outline of Annual Research Achievements

平成27年度は、グラフェンや六方晶窒化ホウ素、二硫化モリブデンなどをヘキサヒドロキシトリフェニレンという平面状の分子をはく離剤として用いることによる2次元ナノシートの合成を行った。さらに、グラファイトをクロリンe6 という平面性の光増感剤ではく離して、グラフェン上に担持し、これを細胞に混ぜ、光照射を行ったところ、ごく少量で強い抗がん作用がみられた。
以上、平成27年度は、グラフェンのはく離とはく離されたグラフェンの分析に重きを置いて研究を行った。

Research Progress Status

27年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

27年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (46 results)

All 2016 2015 2014 2013 Other

All Journal Article (11 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 5 results,  Open Access: 2 results) Presentation (31 results) (of which Int'l Joint Research: 16 results,  Invited: 12 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Readily available “stock solid” of MoS2 and WS2 nanosheets through solid phase exfoliation for highly concentrated dispersion in water2016

    • Author(s)
      Gang Liu and Naoki Komatsu
    • Journal Title

      ChemNanoMat

      Volume: 2 Issue: 6 Pages: 500-503

    • DOI

      10.1002/cnma.201600116

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] An efficient and scalable production of 2D material dispersions using hexahydroxytriphenylene as a versatile exfoliant and dispersant2016

    • Author(s)
      Gang Liu, Naoki Komatsu
    • Journal Title

      ChemPhysChem

      Volume: 17 Issue: 11 Pages: 1557-1567

    • DOI

      10.1002/cphc.201600187

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Direct Fabrication of the Graphene-Based Composite for Cancer Phototherapy through Graphite Exfoliation with a Photosensitizer2015

    • Author(s)
      G. Liu, H. Qin, T. Amano, T. Murakami, and N. Komatsu
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 7 Issue: 42 Pages: 23402-23406

    • DOI

      10.1021/acsami.5b07432

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Structural Discrimination of Double-Walled Carbon Nanotubes by Chiral Diporphyrin Nanocalipers2014

    • Author(s)
      G. Liu, Y. Saito, D. Nishio-Hamane, A. K. Bauri, E. Flahaut, T. Kimura, and N. Komatsu
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 44 Pages: 19067-19074

    • DOI

      10.1039/c4ta04407j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Drastic change in photoluminescence properties of graphene quantum dots by chromatographic separation2014

    • Author(s)
      N. Fuyuno, D. Kozawa, Y. Miyauchi, S. Mouri, R. Kitaura, H. Shinohara, T. Yasuda, N. Komatsu, K. Matsuda
    • Journal Title

      Advanced Optical Materials

      Volume: 2 Issue: 10 Pages: 983-989

    • DOI

      10.1002/adom.201400200

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 超音波で分離した環状カーボンナノチューブ2014

    • Author(s)
      小松直樹
    • Journal Title

      空気清浄

      Volume: 52 Pages: 57-57

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Separation of left- and right-handed carbon nanotubes2014

    • Author(s)
      N. Komatsu
    • Journal Title

      Symmetry: Culture and Science

      Volume: 25 Pages: 87-90

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Sonochemical Preparation of carbon spheres2014

    • Author(s)
      M. Fujita, N. Komatsu, and T. Kimura
    • Journal Title

      Ultrason. sonochem.

      Volume: 21 Issue: 3 Pages: 943-945

    • DOI

      10.1016/j.ultsonch.2013.11.013

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis (tert-butylpyrene) Nanotweezers and Nanocalipers : Enhancde Extraction and Recognition Abilities for Single-Wallde Carbon Nanotubes2013

    • Author(s)
      G. Liu, A. F. M. M. Rahman, S. Chaunchaiyakul, T. Kimaura, Y. Kuwahara, and N. Komatsu
    • Journal Title

      Chem. Eur. j.

      Volume: 19 Issue: 48 Pages: 16221-16230

    • DOI

      10.1002/chem.201302799

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enrichment of Large-Diameter Single-Walled Carbon Nanotubes (SWNTs) with Metallo-Octacthylporphyrins2013

    • Author(s)
      Y. Li, A. F. M. M. Rahman, G. Liu, Z. Xiong, K. Koezuka, Z. Xu, N. Komatsu and F. Wang
    • Journal Title

      Materials

      Volume: 6 Issue: 8 Pages: 3064-3078

    • DOI

      10.3390/ma6083064

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design, synthesis, and preliminary ex vivo and in vivo evaluation of cationic magnetic resonance contrast agent for rabbit articular cartilage imaging2013

    • Author(s)
      T. Irie, K. Oda, A. Shiino, M. Kubo ; S. Morikawa, N. Urushiyama, S. Aonuma, T. Kimura, T. Inubushi, T. Oohashi, and N. Komatsu
    • Journal Title

      Mde. Chem. Commun.

      Volume: 4 Pages: 1508-1512

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Stable Aqueous Dispersion of Graphene-Based Composite through Direct Graphite Exfoliation with a Photosensitizer and Its Application to Cancer Phototherapy2016

    • Author(s)
      Gang Liu, Hongmei Qin, Naoki Komatsu
    • Organizer
      2016 MRS Spring Meeting
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Supramolecular chemistry of graphene and carbon nanotube2015

    • Author(s)
      Naoki Komatsu
    • Organizer
      6th International Collaborative and Cooperative Chemistry Symposium (ICCCS-6)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct Fabrication of the Graphene-Based Compositefor Cancer Phototherapy through Graphite Exfoliation with a Photosensitizer2015

    • Author(s)
      Gang Liu, Hongmei Qin, Naoki Komatsu
    • Organizer
      第3回ナノカーボンバイオシンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Biomedical application of nanodiamond through surface chemical functionalization2015

    • Author(s)
      Naoki Komatsu
    • Organizer
      International Conference on Diamond and Carbon Materials
    • Place of Presentation
      Bad Homburg, Germany
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Functionalization of Nanoparticles and Their Biomedical Applications as an Imaging Probe and a Drug Carrier2015

    • Author(s)
      Naoki Komatsu
    • Organizer
      ICMB2015 (International Conference on Medicine and Biopharmaceuticals)
    • Place of Presentation
      Guilin, China
    • Year and Date
      2015-08-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Optical Resolution of Carbon Nanotubes through Molecular Recognition2015

    • Author(s)
      Naoki Komatsu
    • Organizer
      16th International Symposium on Novel Aromatic Compounds (ISNA-16)
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polyglycerol-functionalized graphene and SWNT complexes for photodynamic therapy2015

    • Author(s)
      H. Qin. K. Nakamura, G. Liu, T. Kimura, N. Komatsu
    • Organizer
      The sixteenth international conference on the science and application of nanotubes
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-07-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A rosette cooling cell: more effective container for solubilization of single-walled carbon nanotubes under probe-type ultrasonic irradiation2015

    • Author(s)
      N. Komatsu, G. Liu, T. Yasumitsu, T. Kimura
    • Organizer
      The sixteenth international conference on the science and application of nanotubes
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Simultaneous discrimination of diameter, handedness, and metallicity of carbon nanotubes by caliper-shaped host molecules through complexation2015

    • Author(s)
      G. Liu, T. Kimura, N. Komatsu
    • Organizer
      The sixteenth international conference on the science and application of nanotubes
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of polyglycerol-functionalized graphene and SWNTs, and their application to carrier of a photosensitizer in photodynamic therapy2015

    • Author(s)
      H. Qin. K. Nakamura, G. Liu, T. Kimura, N. Komatsu
    • Organizer
      Sixth Symposium on Carbon Nanomaterials Biology, Medicine & Toxicology
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hexahydroxytriphenylene as a versatile and commercial exfoliant for 2D materials in aqueous and organic solvents through wet and dry processes2015

    • Author(s)
      Gang Liu, Takahide Kimura, Naoki Komatsu
    • Organizer
      Sixth graphene and 2D materials satellite symposium
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンナノチューブの光学分割2015

    • Author(s)
      Gang Liu, Naoki Komatsu, Takahide Kimura
    • Organizer
      モレキュラー・キラリティー2015
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-06-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] Simultaneous Discrimination of Diameter, Handedness, and Metallicity of SWNTs with Chiral Diporphyrin Nanocalipers2015

    • Author(s)
      G. Liu. T. Kimura, N. Komatsu
    • Organizer
      9th INTERNATIONAL Conference on New Diamond and Nano Carbons (NDNC2015)
    • Place of Presentation
      Shizuoka
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hexahydroxytriphenylene and its derivetives as versatile exfoliants for graphene exfoliation in both aqueous and organic media2015

    • Author(s)
      Gang Liu, Takahide Kimura, Naoki Komatsu
    • Organizer
      9th INTERNATIONAL Conference on New Diamond and Nano Carbons (NDNC2015)
    • Place of Presentation
      Shizuoka
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hexahydroxytriphenylene and its derivetives for graphene exfoliation in aqueous and organic media2015

    • Author(s)
      Gang LIU, Takahide KIMURA, Naoki KOMATSU
    • Organizer
      第48回 フラーレン・ナノチューブ・グラフェン
総合シンポジウム
    • Place of Presentation
      東大
    • Year and Date
      2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Functionalization, Characterization and Biomedical Application of Nanodiamond2014

    • Author(s)
      Naoki Komatsu
    • Organizer
      The International Workshop on Novel Carbons
    • Place of Presentation
      Enshi, China
    • Year and Date
      2014-10-20
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polyglycerol grafting on various nanoparticles for in vivo applications as a drug carrier and an imaging probe2014

    • Author(s)
      Naoki Komatsu
    • Organizer
      The EMN meeting
    • Place of Presentation
      Chengdu, China
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Biomedical application of nanocarbons2014

    • Author(s)
      Naoki Komatsu
    • Organizer
      第75回応用物理学会秋季学術講演会における日韓共同シンポジウム
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子ノギスによる2 層カーボンナノチューブの構造分離2014

    • Author(s)
      Gang LIU, Takahide KIMURA, Naoki KOMATSU
    • Organizer
      第47回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Host-guest chemistry of carbon nanotubes with diporphyrin nanotweezers and nanocalipers for the structural separation2014

    • Author(s)
      Naoki Komatsu, Gang Liu, Takahide Kimura
    • Organizer
      EMRS SPRING meeting
    • Place of Presentation
      Lille, France
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diporphyrin and Dipyrene Nanocalipers for Discrimination of Diameter and Metallicity in Single-Wallde Carbon Nanotubes2014

    • Author(s)
      Naoki Komatsu, Liu Gang
    • Organizer
      225 Electrochemical Society Meeting
    • Place of Presentation
      Orlando, US
    • Year and Date
      2014-05-13
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Diporphyrin and Dipyrene Nanocalipers for Discrimination of Diameter and Metallicity in Single-Walled Carbon Nanotubes2014

    • Author(s)
      Naoki Komatsu, Gang Liu
    • Organizer
      ECS Meeting
    • Place of Presentation
      Orlando, US
    • Year and Date
      2014-05-12
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] トリフェニレン誘導体によるグラファイトからグラフェンの液相剥離2014

    • Author(s)
      船橋 竜介, 劉 剛, 青沼 秀児, 木村 隆英, 小松 直樹
    • Organizer
      第46回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2014-03-05
    • Related Report
      2013 Annual Research Report
  • [Presentation] Polyglycerol-functionalizde single-wallde carbon nanotubes for drugloading and delivery2014

    • Author(s)
      Qin Hongmei, Li Zhao, Keisuke Nakamrua, Takahide Kimura, Naoki Komatsu
    • Organizer
      第46回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2014-03-05
    • Related Report
      2013 Annual Research Report
  • [Presentation] Host-guest chemistry of carbon nanotubes with diporphyrin nanotweezers and nanocalipers for the structural separation2014

    • Author(s)
      Naoki Komatsu, Gang Liu, Takahide Kimura
    • Organizer
      E-MRS
    • Place of Presentation
      Lille, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simultaneous Discrimination of Diameter, Handedness, and Metallicity of Single-Wallde Carbon Nanotubes with Chiral Diporphyrin Nanocalipers2013

    • Author(s)
      Gang Liu, Feng Wang, Songpol Chaunchaiyakul, Takahide Kimura, Yuji Kuwahara, Naoki Komatsu
    • Organizer
      炭素材料学会年会
    • Place of Presentation
      京都教育文化センター
    • Year and Date
      2013-12-04
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation, size-separation and biomedical application of water-soluble nanocarbons2013

    • Author(s)
      Naoki Komats
    • Organizer
      第45回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      大阪大学
    • Year and Date
      2013-08-07
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Bis (tert-butylpyrene) nanotweezers and nanocallpers : Enhancde extraction and recognition abilities for single-wallde carbon nanotubes2013

    • Author(s)
      Gang Liu, A. F. M. Mustafizur Rahman, Takahide Kimura, Naoki Komatsu
    • Organizer
      第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      大阪大学
    • Year and Date
      2013-08-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] Separation of Left-and Right-Handed Carbon Nanotubes2013

    • Author(s)
      Naoki Komatsu
    • Organizer
      SYMMETRY FESTIVAL 2013
    • Place of Presentation
      Delft, The Netherlands
    • Year and Date
      2013-08-02
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Chiral Diporphyrin Nanocalipers : New Host Molecule Next to Nanotweezers for Separation of Single-Wallde Carbon Nanotubes2013

    • Author(s)
      Naoki Komatsu, Gang Liu
    • Organizer
      233 Electrochemical Society Meeting
    • Place of Presentation
      Toronto, Canada
    • Year and Date
      2013-05-13
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Simultaneous Discrimination of Diameter, Handedess, and Metallicity of Single-Wallde Carbon Nanotubes by Chiral Diporphyrin Nanocalipers2013

    • Author(s)
      Naoki Komatsu, Gang Liu
    • Organizer
      233 Electrochemical Society Meeting
    • Place of Presentation
      Toronto, Canada
    • Year and Date
      2013-05-13
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Chemical Functionalization of Carbon Nanomaterials: Chemistry and Applications2015

    • Author(s)
      L. Zhao and N. Komatsu
    • Publisher
      CRC Press
    • Related Report
      2015 Annual Research Report
  • [Book] Magnetic Nanoparticles : Synthsis, Physicochemical Properties and Role in Biomedicine2014

    • Author(s)
      L. Zhao, and N. Komatsu
    • Publisher
      Nova Science Publishers, Inc.
    • Related Report
      2013 Annual Research Report
  • [Remarks] 小松研究室ホームページ

    • URL

      http://www.komatsu.h.kyoto-u.ac.jp/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://www.shiga-med.ac.jp/~nkomatsu/indexj.htm

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2014-01-29   Modified: 2024-03-26  

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