| Project/Area Number |
13F03371
|
|---|
| Research Category |
Grant-in-Aid for JSPS Fellows
|
| Allocation Type | Single-year Grants |
|---|
| Section | 外国 |
|---|
| Research Field |
Inorganic materials/Physical properties
|
|---|
| Research Institution | Hokkaido University |
|---|
Principal Investigator |
忠永 清治 北海道大学, 工学(系)研究科(研究院), 教授 (90244657)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
ROSERO-NAVARRO NATALY CAROLINA 北海道大学, 工学(系)研究科(研究院), 外国人特別研究員
ROSERO-NAVARRO Nataly Carolina 北海道大学, 工学(系)研究科(研究院), 外国人特別研究員
ROSERO-NAVARRO Nataly Carolina 北海道大学, 大学院工学研究院, 外国人特別研究員
|
|---|
| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2015: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2014: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2013: ¥500,000 (Direct Cost: ¥500,000)
|
|---|
| Keywords | 固体電解質 / リチウム電池 / ゾル－ゲル法 / 低温合成 / リチウムイオン電池 / ゾルーゲル法 |
|---|
| Outline of Annual Research Achievements |
Lithium garnet-type oxides Li7-xLa3Zr2-xNbxO12 (LLZNbO, x=0-1) were prepared by a sol-gel process at low temperatures. Then, glass additives, LiO2-B2O3-SiO2 glass and BaO-B2O3-SiO2 glass, were used to stimulate the sintering of the ceramic electrolyte retaining the cubic phase stable at low temperatures.
The cubic garnet phase was formed by a heat-treatment of sol-gel derived precursor powders at 600 - 700 degree C. The presursor powders and glass additives, 53LiO2･31B2O3･12SiO2 (mol%) (LiO2-B2O3-SiO2 glass) or 35BaO･10CaO･5Al2O3･15B2O3･10SiO2 (mol%) (BaO-B2O3-SiO2 glass) were pressed into pellets and sintered at 900 degree C.
The relatative density of 86% was achieved by the sintering with glass additives at 900 degree C. In the composites sintered with the BaO-B2O3-SiO2 glass, the presence of La2Zr2O7 was detected at concentration higher of 4 wt%, while the single cubic phase was obtained for the composites sintered with the LiO2-B2O3-SiO2 glass.
The ionic conductivity of the obtained composite was 8x10^-5 S/cm at 30 degree C using 4 wt.% of LiO2-B2O3-SiO2 glass. The conductivity is 20% lower than the material reported by the solid state reaction process, but the heat treatment used is about 300 degree C lower than that required by the conventional solid state reaction process. This represents an important contribution to further application of the LLZNbO solid electlolyte to all-solid-state battery.
|
| Research Progress Status |
27年度が最終年度であるため、記入しない。
|
| Strategy for Future Research Activity |
27年度が最終年度であるため、記入しない。
|
Report
(3 results)
Research Products
(9 results)
