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精密合成による環拡張ポルフィリンの機能設計

Research Project

Project/Area Number 13J00514
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

森 裕貴  京都大学, 理学研究科, 特別研究員(DC1)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2015: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2014: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2013: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywordsポルフィリン / 環拡張ポルフィリン / π拡張ポルフィリン / ヘキサフィリン / らせん共役 / オリゴチオフェン / 近赤外色素 / 金属錯体 / 縮環 / アヌレノアヌレン / ハイブリッド / ポルフィリンテープ
Outline of Annual Research Achievements

本研究において申請者は1および2年度目に、1)複数の共役系を有する分子内架橋型環拡張ポルフィリンの合成と物性、2)ポルフィリン-ヘキサフィリンハイブリッド多量体の合成と物性、3)非環状らせん共役系を有するオリゴチエニル置換26πヘキサフィリンの合成と物性、4)5,20-ピロリル置換26πヘキサフィリンおよびその金属二核錯体の合成と物性、といったテーマで研究を行い、新規な環拡張ポルフィリンの合成と物性評価を通じて様々な知見を得てきた。なかでも環拡張ポルフィリンのπ電子系の拡張とその近赤外光吸収スペクトルの長波長シフトの相関に関して得られた知見は非常に興味深く、3年度目においては5)近赤外領域に強い光吸収を示すメゾオリゴチエニル置換ポルフィリンの合成と物性、6)電子不足ポルフィリンテープ3量体および4量体の合成と物性、といったように、得られた知見を通常のポルフィリン類縁体への応用と展開を行った。これら5)および6)で得られた知見は一般性が高く、今後申請者が所属する研究室においてもさらに応用がなされ、体系だった研究が展開されることが期待される。
また3年度目は上記のメインテーマ5)および6)に加えて、自身の研究1)から6)に関連する共同研究などにも精力的に参画し、原著論文9報告を発表した。加えて従来通り各学会においても積極的に参加し、2件の研究発表を行った。

Research Progress Status

27年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

27年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (33 results)

All 2016 2015 2014 2013 Other

All Journal Article (21 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 21 results,  Acknowledgement Compliant: 11 results,  Open Access: 1 results) Presentation (10 results) Remarks (2 results)

  • [Journal Article] A very rapid electronic relaxation process in a highly conjugated Zn(II)porphyrin–[26]hexaphyrin–Zn(II)porphyrin hybrid tape2016

    • Author(s)
      S. Lee, H. Mori, T. Lee, M. Lim, A. Osuka, and D. Kim
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 4 Pages: 3244-3249

    • DOI

      10.1039/c5cp07417g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Switchable π-Electronic Network of Bis(α-oligothienyl)-substituted Hexaphyrins between Helical versus Rectangular Circuit2016

    • Author(s)
      Juwon Oh, Hirotaka Mori, Young Mo Sung, Woojae Kim, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      Chemical Science

      Volume: 7 Issue: 3 Pages: 2239-2245

    • DOI

      10.1039/c5sc04263a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] meso-meso Directly-Linked Trimeric and Pentameric Electron-Deficient Porphyrin-Hexaphyrin Hybrid Arrays2016

    • Author(s)
      Hirotaka Mori, Atsuhiro Osuka
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 印刷中 Issue: 01n04 Pages: 245-253

    • DOI

      10.1142/s1088424616500024

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] An Ethyne-bridged Porphyrin-Hexaphyrin-Porphyrin Triad That Undergoes A Thermal Transannular Cyclization2016

    • Author(s)
      Kazuma Honjo, Hirotaka Mori, Atsuhiro Osuka
    • Journal Title

      Journal of Asian Organic Chemistry

      Volume: 5 Issue: 2 Pages: 196-200

    • DOI

      10.1002/ajoc.201500509

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Trimeric and Tetrameric Electron-Deficient Porphyrin Tapes2016

    • Author(s)
      Hirotaka Mori, Taeyeon Kim, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Chemistry -An Asian Journal

      Volume: 印刷中 Issue: 9 Pages: 1454-1463

    • DOI

      10.1002/asia.201600241

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin2015

    • Author(s)
      Y. Tanaka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 37 Pages: 10908-10911

    • DOI

      10.1002/anie.201505130

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 5,20-Di(pyridin-2-yl)-[28]Hexaphyrin(1.1.1.1.1.1): A Stable Huckel Antiaromatic Hexaphyrin Stabilized by Intramolecular Hydrogen Bonding and Protonation Induced Conformational Twist to Gain Mobius Aromaticity2015

    • Author(s)
      Koji Naoda, Hirotaka Mori, Juwon Oh, Kyu Hyung Park, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Journal of Organic Chemistry

      Volume: 80 Issue: 23 Pages: 11726-11733

    • DOI

      10.1021/acs.joc.5b01348

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Switching between Aromatic and Antiaromatic 1,3-Phenylene-Strapped [26]- and [28]Hexaphyrins upon Passage to the Singlet Excited State2015

    • Author(s)
      Y. M. Sung, J. Oh, W. Kim, H. Mori, A. Osuka, and D. Kim
    • Journal Title

      J. Am. Chem. Soc

      Volume: 137 Issue: 37 Pages: 11856-11859

    • DOI

      10.1021/jacs.5b04047

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of [n]Cyclo-5,15-porphyrinylene-4,4'-biphenylenes Displaying Size-dependant Excitation Energy Hopping2015

    • Author(s)
      Hua-Wei Jiang, Takayuki Tanaka, Taeyeon Kim, Young Mo Sung, Hirotaka Mori, Dongho Kim, and Atsuhiro Osuka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 54 Issue: 50 Pages: 15197-15201

    • DOI

      10.1002/anie.201507822

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 5,20-Bis(α-Oligothienyl)-Substituted [26]Hexaphyrins(1.1.1.1.1.1): 26π Aromatic Hexaphyrin Circuit versus Acyclic Helical Conjugation2015

    • Author(s)
      Hirotaka Mori, Masaaki Suzuki, Woojae Kim, Jong Min Lim, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Chemical Science

      Volume: 6 Issue: 3 Pages: 1696-1700

    • DOI

      10.1039/c4sc03394a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] meso-meso Linked Porphyrin–[26]Hexaphyrin–Porphyrin Hybrid Arrays and Their Triply Linked Tapes Exhibiting Strong Absorption Bands in NIR Region2015

    • Author(s)
      Hirotaka Mori, Takayuki Tanaka, Sangsu Lee, Jong Min Lim, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 5 Pages: 2097-2106

    • DOI

      10.1021/ja5130034

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cyclic 2,12-Porphyrinylene Nanorings As a Porphyrin Analogue of Cycloparaphenylenes2015

    • Author(s)
      Hua-Wei Jiang, Takayuki Tanaka, Hirotaka Mori, Kyu Hyung Park, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 6 Pages: 2219-2222

    • DOI

      10.1021/ja513102m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bis-Metal Complexes of 5,20-Bis(5-formyl-2-pyrrolyl) [26]Hexaphyrin(1.1.1.1.1.1) Exhibiting Strong NIR Absorptions2015

    • Author(s)
      Hirotaka Mori, Atsuhiro Osuka
    • Journal Title

      Chemistry – A European Journal

      Volume: 未確定 Issue: 19 Pages: 7007-7011

    • DOI

      10.1002/chem.201500433

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ABC-type meso-Triaryl Substituted Subporphyrins2014

    • Author(s)
      Kota Yoshida, Hirotaka Mori, Takayuki Tanaka, Tadashi Mori, Atsuhiro Osuka
    • Journal Title

      European Journal of Organic Chemistry

      Volume: なし Issue: 19 Pages: 3997-4004

    • DOI

      10.1002/ejoc.201402435

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Probing the Rotational Dynamics of meso-(2-Substituted)aryl Substituents in A2B-type Subporphyrins2014

    • Author(s)
      K. Yoshida, G. Copley, H. Mori, and A. Osuka
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 32 Pages: 10065-10072

    • DOI

      10.1002/chem.201402778

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nucleophilic Aromatic Substitution Reactions of meso-Bromosubporphyrin: Synthesis of A Thiopyrane-Fused Subporphyrin2014

    • Author(s)
      Daiki Shimizu, Hirotaka Mori, Masaaki Kitano, Won-Young Cha, Juwon Oh, Takayuki Tanaka, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Chemistry – A European Journal

      Volume: 20 Issue: 49 Pages: 16194-16202

    • DOI

      10.1002/chem.201405110

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diprotonated [28] Hexaphyrins (1.1. 1.1. 1.1) : Triangular Antiaromatic Macrocycles2014

    • Author(s)
      S. -i. Ishida, T. Higashino, S. Mori, H. Mori, N. Aratani, T, Tanaka, J. M. Lim, D. Kim, A. Osukat
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 13 Pages: 3427-3431

    • DOI

      10.1002/anie.201400301

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold (III)-Iridium (III) Hybrid Complexes of Hexaphyrin (1.1. 1.1. 1)2013

    • Author(s)
      K. Naoda, H. Hori, A. Osuka
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 8 Issue: 7 Pages: 1395-1398

    • DOI

      10.1002/asia.201300320

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bottom-Up Synthesis of Bis (triisopropylsilyI) ethynyl Hexaphyrin Bearing an Unsubstitutod meso-Carbon2013

    • Author(s)
      H. Mori, K. Naoda, A. Osuka
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 2 Issue: 7 Pages: 600-605

    • DOI

      10.1002/ajoc.201300061

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Marriage of Peripherally Metallated and Directly Linked Porphyrins : Bromidobis (phosphine) platinum (II) as a Cation-Stabilizing Substituent on Directly Linked and Fused Triply Linked Diporphyrins2013

    • Author(s)
      R. D. Hartnell, T. Yoneda, H. Mori. A. Osuka, D. P. Arnold
    • Journal Title

      Chemistry An Asian Journal

      Volume: 8 Issue: 11 Pages: 2670-2679

    • DOI

      10.1002/asia.201300633

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of Dual Electronic Circuits of [26] Hexaphyrins Using Internal Aromatic Straps2013

    • Author(s)
      H. Mori, J. M. Lim, D. Kim, A. Osuka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 49 Pages: 12997-13001

    • DOI

      10.1002/anie.201308545

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 近赤外領域に強い光吸収を示すメゾオリゴチエニル置換ポルフィリンの合成と物性2015

    • Author(s)
      森裕貴、大須賀篤弘
    • Organizer
      日本化学会秋期事業 第5回 CSJフェスタ2015
    • Place of Presentation
      東京都、船堀タワーホール
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 近赤外領域に強い光吸収を示すメゾオリゴチエニル置換ポルフィリンの合成と物性2015

    • Author(s)
      森裕貴、大須賀篤弘
    • Organizer
      第26回 基礎有機化学討論会
    • Place of Presentation
      愛媛県、愛媛大学
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 非環状らせん共役系を有するヘキサフィリンの合成と物性2015

    • Author(s)
      森 裕貴, 鈴木 優章, 大須賀 篤弘
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 非環状らせん共役系を有する26πヘキサフィリンの合成と物性2014

    • Author(s)
      森 裕貴, 大須賀 篤弘
    • Organizer
      第25回 基礎有機化学討論会
    • Place of Presentation
      東北大学(宮城)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and Characterization of Porphyrin–Hexaphyrin Hybrid Arrays2014

    • Author(s)
      Hirotaka Mori, Takayuki Tanaka, Atsuhiro Osuka
    • Organizer
      8th International Conference on Porphyrin and Phthalocyanines
    • Place of Presentation
      イスタンブール(トルコ)
    • Year and Date
      2014-07-22 – 2014-07-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポルフィリン-ヘキサフィリンハイブリッド多量体の合成と物性2014

    • Author(s)
      森 裕貴, 田中 隆行, 大須賀 篤弘
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2014-03-29
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Properties of Porphyrin-Hexaphyrin-Porphyrin Triads2014

    • Author(s)
      Hirotaka Mori and Atsuhiro Osuka
    • Organizer
      2014 KAIST-KYOTO-NTHU Junior Chemist Symposium
    • Place of Presentation
      Paejeon (Korea)
    • Year and Date
      2014-02-11
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポルフィリン-ヘキサフィリンハイブリッド多量体の合成と物性2013

    • Author(s)
      森 裕貴, 大須賀 篤弘
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Year and Date
      2013-09-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Characterization of Porphyrin-Hexaphyrin-Porphyrin Triads2013

    • Author(s)
      Hirotaka Mori and Atsuhiro Osuka
    • Organizer
      15th International Symposium on Novel Arometic Compounds (ISNA15)
    • Place of Presentation
      Taipei (Taiwan)
    • Year and Date
      2013-08-01
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Characterization of Porphyrin-Hexaphyrin-Porphyrin Triad2013

    • Author(s)
      Hirotaka Mori and Atsuhiro Osuka
    • Organizer
      Challenges in Organic Materials and Supramolecular Chemistry in the International Symposia on Advancing the Chemical Sciences (ISACSlO)
    • Place of Presentation
      Kyoto University (Japan)
    • Year and Date
      2013-06-21
    • Related Report
      2013 Annual Research Report
  • [Remarks] 京都大学大学院理学研究科化学専攻 集合有機分子機能研究室 ホームページ

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu/

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-01-29   Modified: 2024-03-26  

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