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Design and Photo-functions of Self-assembled Nanolaminate Films

Research Project

Project/Area Number 14050050
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTokyo Metropolitan University (2006)
Nagoya University (2002-2005)

Principal Investigator

TAKAGI Katsuhiko  Tokyo Metropolitan University, 都市環境科学研究科, Visiting Professor in Guest Chairs (60023264)

Co-Investigator(Kenkyū-buntansha) SEKI Takahiro  Nagoya University, 大学院・工学研究科, Professor (40163084)
FUKUSHIMA Nobuaki  Toyota Central R&D Labs., Inc., 第2特別研究室, Senior fellow (80309004)
SASAI Ryo  Nagoya University, エコトピア研究所, Research Associate (60314051)
由井 樹人  名古屋大学, 工学研究科, 助手 (50362281)
木村 真  名古屋大学, 工学研究科, 助教授 (30144124)
志知 哲也  名古屋大学, 大学院・工学研究科, 助手 (90293654)
菊田 浩一  名古屋大学, 大学院・工学研究科, 助教授 (00214742)
Project Period (FY) 2001 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥84,400,000 (Direct Cost: ¥84,400,000)
Fiscal Year 2006: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2005: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 2004: ¥10,600,000 (Direct Cost: ¥10,600,000)
Fiscal Year 2003: ¥24,600,000 (Direct Cost: ¥24,600,000)
Fiscal Year 2002: ¥28,800,000 (Direct Cost: ¥28,800,000)
KeywordsMesoporous silica(MPS) / Titania nanosheets(TNS) / (MPS / TNS)hybrid film on FTO electrode / Photocurrent / Photo induced charge separation / Dve-sensitized CT systems / 色素増感電荷分離膜系 / メソポーラスシリカ / チタニアナノシート / 無機・無機異種界面 / 紫外光電子移動 / 長寿命電荷分離状態 / ビオロゲン / テトラメチルピリジニウムポルフィリン / 光電流の電気化学測定 / 分子集合体 / 自己組織膜 / 複合材料 / 超分子構造体 / 透明薄膜 / 光誘起電子移動 / 界面電子移動 / 長寿命電荷分離 / 自己組織化膜 / 薄膜 / 電化分離 / 積層化複合体膜 / MCM-MPS細孔内 / 電荷分離 / MV^<2+>還元体 / ニオブ酸カリウム / インターカレーション / ポルフィリン-ビオロゲン交互複合体 / 可視光駆動光化学電荷分離 / 積層複合体 / 交互吸着
Research Abstract

In the present project a stacking hybrid film of mesoporous silica (MPS) and titania nanosheets (TNS) has been investigated, each of which include separately porphyrin dye (TMPyP) and methyl viologen (MV^<2+>), respectively. Under UV light irradiation, thus obtained hybrid film exhibits one electron oxidation of TMPyP accompanied by the simultaneous generation of one electron reduced MV^<2+>. That is, the result suggests an electron transfer through the interface of these inorganic thin films. In this year, the MPS/TNS hybrid film deposited on a FTO electrode was studied from the point of the generation of electric current through the inorganic interface.
(MPS-TMPyP)/(TNS-MV^<2+>) hybrid film on the FTO electrode was immersed in CH_3CN together with Pt working and Ag/AgCl reference electrodes, and analyzed by measuring the photocurrent under UV light. On applying a negative vias voltage, -0.4V, a cathodic current, though weak, has been observed from the FTO electrode to MPS-TMPyP throug … More h TNS conduction band. For the observation of definite electric currents, an inversely stacked (TNS)/(MPS-TMPyP) hybrid film was attempted, where an electron acceptor, MV^<2+>, was removed from TNS interlayers by applying a positive vies voltage. By irradiation of the inversely stacked film by UV light, a strong anodic photocurrent flows through the inorganic interface into the FTO electrode. On the basis of spectroscopic observation, ca. 60% of the photocurrents induced the one-electron oxidation of TMPyP into the corresponding one-electron oxidized species.
The resulting charge separation has been found to be quite stable and survived for a long period in this system. For instance, the formed one-electron oxidized TMPyP and the one-electron reduced MV^<2+> remain for several hours under the aerated conditions and ambient temperature. Especially under deaerated conditions the charge separation has a period of half decay of>several days. Now the present system is under the study for extending to a visible light sensitized charge-separation by visible light excitation of an appropriate organic dye with exothermic electron transfer to the conduction band of TNS semiconductor. Less

Report

(6 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (43 results)

All 2007 2006 2005 2004 Other

All Journal Article (24 results) (of which Peer Reviewed: 3 results) Presentation (2 results) Book (2 results) Patent(Industrial Property Rights) (1 results) Publications (14 results)

  • [Journal Article] ReversibleRedoxProcessesofPoly(anilines)inLayeredSemiconductorNiobateFilms underAlternateUV-VisLightIllumination2007

    • Author(s)
      Y. Inui, T. Yui, T. Itoh, K. Higuchi, T. Seki, K. Takagi
    • Journal Title

      J. Phys. Chem. B 111

      Pages: 12162-12169

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Pyrene-to-porphyrin Excited Singlet Energy Transfer in LBL-deposited LDH Nano sheets2007

    • Author(s)
      T. Yui, T. Kameyama。T. Sasaki, T. Torimoto, K. Takagi
    • Journal Title

      J, Porphyrins and Phthalocyanines 11

      Pages: 428-433

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Microscopic Structure of Separately Accommodated Porphyrins and Viologens in Mesoporous Silica and Titania Nanosheet Hybrid Films2007

    • Author(s)
      T. Yui. T. Kaiino, T. Tsuchino, K. Okazaki, T. Torimoto, Y. Fukushima, K. Takagi
    • Journal Title

      Trans. Mat. Res. Soc Jpn 32[2]

      Pages: 449-452

    • NAID

      130007922780

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Reversible Redox Processes of Poly(anilines) in Layered Semiconductor Niobate Films under Alternate UV-Vis Light Illumination2007

    • Author(s)
      Y. Inui, T. Yui, T. Itoh, K. Higuchi, T. Seki, K. Takagi
    • Journal Title

      J. Phys. Chem. B 111

      Pages: 12162-12169

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Pyrene-to-porphyrin Excited Singlet Energy Transfer in LBL-deposited LDH Nanosheets2007

    • Author(s)
      T. Yui, T. Kameyama, T. Sasaki, T. Torimoto, K. Takagi
    • Journal Title

      J. Porphyrins and Phthalocyanines 11

      Pages: 428-433

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 「研究成果報告書概要(欧文)」より2007

    • Author(s)
      T. Yui, T. Kajino, T. Tsuchino, K. Okazaki, T. Torimoto, Y. Fukushima, K. Takagi
    • Journal Title

      Trans. Mat. Res. Soc Jpn 32[2]

      Pages: 449-452

    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photochemical Electron Transfers through the Interface of Hybrid Films of Titania Nanosheets and Mono-dispersed Spherical Mesoporous Silica Particles2006

    • Author(s)
      T.Yui, Y.Kobayashi, T.Tsuchino, T.Kajino, Y.Fukushima, H.Inoue, K.Takagi, et al.
    • Journal Title

      Phys.Chem.Chem.Phys 8

      Pages: 4585-4590

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Chelation of spironaphthoxazine with zinc ions during the sol-gel-xerogel transitions in silicon alkoxide systems2006

    • Author(s)
      H.Nishikiori, R.Sasai, K.Takagi, T.Fujii
    • Journal Title

      J.Photochem. & Photobiol., A : Chemistr 183

      Pages: 53-58

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Zinc chelation and photofluorochromic behavior of spironaphthoxazine intercalated into hydrophobically-modified montmorillonite2006

    • Author(s)
      H.Nishikiori, R.Sasai, K.Takagi
    • Journal Title

      Langmuir 22(7)

      Pages: 3376-3380

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photocatalytic Activity of TiO2-containing Al-Mesoporous Silica Thin Films2006

    • Author(s)
      T.Hattori, N.Oyaizu, Y.Adachi, T.Shichi, K.Takagi
    • Journal Title

      J.Oleo.Sci 55, (No.4)

      Pages: 199-209

    • NAID

      130000055573

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hybridization of Layered Niobates with Cationic Dyes2006

    • Author(s)
      T.Hattori, Z.Tong, Y.Kasuga, Y.Sugito, T.Yui, K.Takagi
    • Journal Title

      Res.Chem.Intermed 32, (No.7)

      Pages: 653-669

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Visible Light-Induced Electron Transfers in Titania Nanosheet and Mesoporous Silica Integrated Films2006

    • Author(s)
      T.Yui, T.Tsuchino, K.Takagi
    • Journal Title

      Bull.Chem.Soc.Japn. 79 (No.3)

      Pages: 373-385

    • NAID

      10017309903

    • Related Report
      2006 Annual Research Report
  • [Journal Article] The Template Polymerization of 12-Methacryloxydodecanoate Ions in LDH Clay2005

    • Author(s)
      Itoh, T., Yamashita, M., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      Chem. Lett 1

      Pages: 990-991

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structural Study of Dicetylphosphate Self-Assembled in Layered Double Hydroxide2005

    • Author(s)
      Itoh, T., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      J. Colloid Interface Sci 291

      Pages: 218-222

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Odd-Even Effect of the Methylene Chain Number in the Template Polymerization of alpha, beta-diacetylenecarboxylates Incorporated in Layered Double Hydroxide Clay2005

    • Author(s)
      Itho, T., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      Langmuir 21

      Pages: 3217-3220

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The Reversible Color Changes in Lamella Hybrids of Poly(diacetylenecarboxylates) in Corporated in Layered Double Hydroxide Nanosheets2005

    • Author(s)
      Itoh, T, Shichi, T., Yui, T., Inui, Y., Takagi, K.
    • Journal Title

      J.Phys.Chem. B 109

      Pages: 3199-3206

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The Design of Photofunctional Laminated Organized Thin Films : The Photochromism of Ammoniumazobenzene Arenecarboxylates Cast on Silica Glass2005

    • Author(s)
      Ohtani, O., Itoh, T., Monna, Y., Sasai, R., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      Bull. Chem. Soc. Jpn 78

      Pages: 698-702

    • NAID

      10015463630

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Novel Soft Chemical Method for Optically Transparent Ru(bpy)3-K4Nb6O17 Thin Film2005

    • Author(s)
      Tong, Z., Takagi, S., Tachibana, H., Takagi, K., Inoue, H.
    • Journal Title

      J. Phys. Chem.B 109

      Pages: 21612-21617

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The Organized Intercalation and Thermochromism of Poly(diacetylenecarboxylates) in Hydrotalcite Clays2005

    • Author(s)
      Itoh, T., Shichi, T., Yui, T., Inui, M., Tkahasi, H., Takagi, K.
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 3199-3199

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Photofunctional Titania Nanosheets by Electrophoretic Deposition2005

    • Author(s)
      Yui, T., Mori, Y., Tsuchino, T., Itoh, T., Hattri, T., Fukusimia, Y., Takagi, K.
    • Journal Title

      Chem.Mater. 17

      Pages: 206-206

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Color Changes Dependent on the Anisotropic Intercalationof Poly(diacetylenecarboxylates) in LDH Clay Hybrids2004

    • Author(s)
      Itoh, T., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      Chem.Lett.

      Pages: 1269-1269

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Photoinduced One-electron Reduction of MV2+ in Titania Nanosheets using Porphyrin in Mesoporous Silica Thin Films

    • Author(s)
      Yui, T., Tsuchino, T., Itoh, T., Ogawa, M., Fukushima, T., Takagi, K.
    • Journal Title

      Langmuir (Web released)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Intercalation and Photochromism of Single Cationic-Site Carrying Diarylethene in Clay Layer

    • Author(s)
      Yui, T., Sasai, R., Shindachi, I., Takagi, K.
    • Journal Title

      Mol.Cryst Liq.Cryst (In press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] The Design of Photofunctional Laminated Organized Thin Films : The Photochromism of Ammoniumazobenzene Arenecarboxylates Cast Silica Glass

    • Author(s)
      Ohtani, O., Itoh, T., Monna, Y., Sasai R., Shichi, T., Yui, T., Takagi, K.
    • Journal Title

      Bull.Chem.Soc.Jpn. (In press)

    • NAID

      10015463630

    • Related Report
      2004 Annual Research Report
  • [Presentation] TNS-MPS複合接合面を介する光触媒電子輸送2007

    • Author(s)
      平野琢也, ○高木克彦, 井上晴夫, 由井樹人, 岡崎健一, 鳥本司
    • Organizer
      光化学協会
    • Place of Presentation
      長野県信州大学キャンパス
    • Year and Date
      2007-09-26
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Photo-catalytic Electron Transport Through TNS-MPS Hybrid Interface2007

    • Author(s)
      T. Hirani, K. Takagi, H. Inoue, T. Yui, K. Okazaki, T. Torimoto
    • Organizer
      The Symposium of Japanese Photochemisry Association
    • Place of Presentation
      Nagano, Shinshu Univ.
    • Year and Date
      2007-09-26
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Encyclopedia of Nanoscience and Nanotechnology ; Bottom-Up Nanofabrication, Chapter61 : “Photochemistry and Photofunctions of Organic Inorganic Hybrid Films"2007

    • Author(s)
      T. Yui, K, Takagi
    • Publisher
      American Scientific Publishers (Edited by Drs K. Ariga and. H. s. Nalwa)(印刷中)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 「無機ナノシートの科学と応用」中「層間光化学反応」を分担執筆2005

    • Author(s)
      由井樹人, 高木克彦 著, 黒田一幸, 佐々木高義 編
    • Total Pages
      13
    • Publisher
      シーエムシー出版(東京)
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 国内特許2006

    • Inventor(s)
      由井, 福島, 高木, 梶野
    • Industrial Property Rights Holder
      由井, 福島, 高木, 梶野
    • Filing Date
      2006
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Publications] O.Ohtani, H.Kato, T.Yui, K.Takagi: "Reversible Light Driven Structural Changes between the Mono^- and Bilayer Stacking Alignment in 4-Octadecyoxylstilbazolium Arylcarboxylate Films"J.Am.Chem.Soc.. 125. 14465-14472 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] O.Ohtani, T.Furukawa, R.Sasai, E.Hayashi, T.Shichi, T.Yui, K.Takagi: "Effect of Fluorinated Ammonium Counterions upon the Reversibility in E-Z Photoisomerization of Azobenzene Ion Pair Films"J.Mat.Chem.. 14. 196-200 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Itoh, N.Ohta, T.Shichi, T.Yui, K.Takagi: "The Self-Assembling Properties of Stearate Ions in Hydrotalcite Clay Composites"Langmuir. 19. 9120-9126 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] L.A.Lucia, T.Yui, R.Sasai, S.Takagi, K.Takagi, H.Yoshida, D.G.Whitten, H.Inoue: "Enhanced Aggregation Behavior of Antimony(V) Porphyrins in Polyfluorinated Surfactant/Clay Hybrid Microenvironment"J.Phys.Chem.B. 107. 3789-3797 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Shichi, Y.Minamikawa, N.Yasuda, N.Yamada, Y.Okamoto, K.Takagi: "Enantioselective Photopinacolization of Benzophenone and Benzhydrol Intercalated in Mg-Al LDH Interlayers"Chem.Lett.. 240-241 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Z.Tong, T.Shichi, K.Takagi: "Oxidation Catakysis of a Manganese (III) Porphyrin Intercalated in Layered Double Hydroxide Clays"Mat.Lett,. 57. 2258-2261 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 由井樹人, 高木克彦: "ラミネート型有機/無機複合体の光化学,66(4)"日本写真学会誌. 326-340 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] O.Ohtani, H.Katoh, K.Takagi: "Reversible Morphological Changes Induced by the Photodimerization of Bis(4-Octadecyloxystilbazolium) Isophthalate Films"Chemistry Letters. 48-49 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] O.Ohtani, R.Sasai, T.Adachi, I.Hatta, K.Takagi: "Self-Assembled Thin Solid Films of Dioctadecyldimethylammonium Cinnamate Lamella Units That Control the Photostationary State of E-Z Photoisomerizations"Langmuir. 18. 1165-1170 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Kikuta, K.Ohta, K.Takagi: "Synthsis of Transparent Magadiite-Silica Hybrid Monoliths"Chemistry Materials. 14. 3123-3127 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Z.Tong, T.Shichi, K.Takagi: "The visible-Light Induced Charge-Separation between Porphrin and Methyl Viologen Separately Intercalated in Different Layeres of the Titanoniobates"Journal of the Physical Chemistry (B). 106. 13336-13310 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Z.Tong, T.Shichi, Koji Oshika, K.Takagi: "A Nanostructured Hybrid Material Synthesized by the intercalation of Porphyrin into Layered Titanoniobate"Chemistry Letters. 876-877 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] R.Sasai, T.Fujita, N.Iyi, Z.Tong, H.Itoh, K.Takagi: "Aggregated Structures of Rhodamine 6G Intercalated in a Fluor-Taeniolite Thin Film"Langmuir. 18. 6578-6583 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 該当なし: "Synthesized by the Intercalation of Porphyrin into Layered Titanoniobate"

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2018-03-28  

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