Photoemission studies of magnetic semiconductors
Project/Area Number |
14076209
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | University of Tokyo |
Principal Investigator |
FUJIMORI Atsushi U. of Tokyo, Graduate School of Frontier Sciences, Professor, 大学院新領域創生科学研究科, 教授 (10209108)
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Co-Investigator(Kenkyū-buntansha) |
MIZOKAWA Takashi U. of Tokyo, Graduate School of Frontier Sciences, Associate Proffessor, 大学院新領域創生科学研究科, 助教授 (90251397)
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Project Period (FY) |
2002 – 2005
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Project Status |
Completed (Fiscal Year 2005)
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Budget Amount *help |
¥19,500,000 (Direct Cost: ¥19,500,000)
Fiscal Year 2005: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2004: ¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 2003: ¥9,800,000 (Direct Cost: ¥9,800,000)
Fiscal Year 2002: ¥3,700,000 (Direct Cost: ¥3,700,000)
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Keywords | Magnetic semiconductors / Photoemission spectroscopy / Soft xjray magnetic circular dichroism / High-temperature ferromagnetism / Nano-struictures / 磁気伝導 / 室温強磁性 / 軌道混成 |
Research Abstract |
* Soft x-ray absorption (XAS) and soft x-ray magnetic circular dichroism (XMCD) studies at the Co 2p core absorption edges of Zn1-xCoxO (x=0.05) prepared by the pulsed laser deposition (PLD) method were performed and the obtained spectra were analyzed using cluster-model calculations. We have found that the temperature and the magnetic field dependences of the XMCD intensity were very different from non-interacting Co ions and that ferromagnetic and antiferromagnetic interactions between the Co ions coexist inhomogeneously. * XAS and resonance photoemission studies at the Mn 2p core absorption edges of Ga1-xMnxN prepared by the molecular-beam epitaxy (MBE) method were performed, and the obtained spectra were analyzed using cluster-model calculations. We found that the valence of the Mn ion was 2+ and that the Mn 3d states were largely distributed within the valence band of the GaN host. Acceptor levels formed by the Mn doping above the valence-band maximum Mn were found to be occupied b
… More
y electrons, indicating that the high-temperature ferromagnetism predicted by theory was nor realized because of the compensation effect. * XAS, XMCD and resonance photoemission studies were performed at the Cr 2p core absorption edges of Ga1-xCrxN (x=0.015). The Cr 2p XAS spectra indicated that the Cr was in the 3+ valence state. The Cr 3d partial density of states (PDOS) were largely distributed within the band gap of GaN, in striking contrast with Ga1-xMnxN. The Cr 3d PDOS was found to be suppressed at the Fermi level, and no Fermi-edge feature as predicted by band-structure calculations was observed. * XAS and XMCD measurements were made on Zn1-xVxO (x=0.05) which exhibited weak ferromagentism. The V ions substituting Zn2+ were found to be responsible for the magnetic properties. From comparison of the XMCD spectra with the magnetic susceptibility, we found that 10% of V ions were paramagnetic and 90 % were strongly coupled with each other antiferromagnetically. Furthermore, the paramagnetic V ions were found to be influenced by the axial crystal field of the hexagonal ZnO host. Less
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Report
(5 results)
Research Products
(53 results)
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[Journal Article] Soft X-Ray Magnetic Circular Dichroism Study of Weakly Ferromagnetic Zn_<1-x>V_xO Thin Film2007
Author(s)
Y.Ishida, J.I.Hwang, M.Kobayashi, Y.Takeda, K.Mamiya, J.Okamoto, S.-I.Fujimori, T.Okane, K.Terai, Y.Saitoh, Y.Muramatsu, A.Fujimori, A.Tanaka, H.Saeki, T.Kawai, H.Tabata
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Journal Title
Description
「研究成果報告書概要(和文)」より
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[Journal Article] Soft X-Ray Magnetic Circular Dichroism,Study of Weakly Ferromagnetic Zni-xVx0 Thin Film2007
Author(s)
Y.Ishida, J.I.Hwang, M.Kobayashi, Y.Takeda, K.Mamiya, J.Okamoto, S.-I.Fujimori, T.Okane, K.Terai, Y.Saitoh, Y.Muramatsu, A.Fujimori, A.Tanaka, H.Saeki, T.Kawai, H.Tabata
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Journal Title
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Photoemission and X-Ray Absorption Studies of the Electronic Structure of GaN-Based Diluted Magnetic Semiconductors.2006
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, Y.Osafune, T.Mizokawa, A.Fujimori, Y.Takeda, K.Terai, S-i.Fujimori, Y.Saitoh, Y.Muramatsu, A.Tanaka, T.Kondo, H.Munekata, M.Hashimoto, H.Tanaka, S.Hasegawa, H.Asahi
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Journal Title
Physica Status Solidi B 383
Pages: 140-141
Description
「研究成果報告書概要(和文)」より
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[Journal Article] Photoemission and X-Ray Absorption Studies of the Electronic Structure of GaN-Based Diluted Magnetic Semiconductors2006
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, Y.Osafune, T.Mizokawa, A.Fujimori Y.Takeda, K.Terai, S-i, Fujimori, Y.Saitoh, Y.Muramatsu, A.Tanaka, T.Kondo, H.Munekata, M.Hashimoto, H.Tanaka, S.Hasegawa, H.Asahi
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Journal Title
Physica Status Solidi B 383
Pages: 140-141
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Photoemission and Core-Magnetic Circular Dichroism Studies of Diluted Magnetic Semiconductors2005
Author(s)
A.Fujimori, J.Okabayashi, Y.Takeda, T.Mizokawa, J.Okamoto, K.Mamiya, Y.Saitoh, Y.Muramatsu, M.Oshima, S.Ohya, M.Tanaka
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Journal Title
J. Electron Spectrosc. Relat. Phenom. 144-147
Pages: 701-705
Description
「研究成果報告書概要(和文)」より
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[Journal Article] High-Energy Spectroscopic Study of the III-V Nitride-Based Diluted Magnetic Semiconductor Ga_<1-X>Mn_xN2005
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, H.Hirata, K.Takubo, T.Mizokawa, A.Fujimori, J.Okamoto, K.Mainiya, Y.Saito, Y.Muramatsu, H.Ott, A.Tanaka, T.Kondo, H.Munekata
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Description
「研究成果報告書概要(和文)」より
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[Journal Article] Characterization of Magnetic Components in the Diluted Magnetic Semiconductor Zn_<1-x>Co_xO by X-ray Magnetic Circular Dichroism2005
Author(s)
M.Kobayashi, Y.Ishida, J.I.Hwang, T.Mizokawa, A.Fujimori, J.Okamoto, K.Mamiya, Y.Takeda, T.Okane, Y.Saitoh, Y.Muramatsu, A.Tanaka, H.Saeki, H.Tabata, T.Kawai
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Description
「研究成果報告書概要(和文)」より
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[Journal Article] Photoemission and Core-Level Magnetic Circular Dichroism Studies of Diluted Magnetic Semiconductors2005
Author(s)
A.Fujimori, J.Okabayashi, Y.Takeda, T.Mizokawa, J.Okamoto, K.Mamiya, Y.Saitoh, Y.Muramatsu, M.Oshima, S.Ohya, M.Tanaka
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Journal Title
J. Electron Spectrosc. Relat. Phenom 144-147
Pages: 701-705
Description
「研究成果報告書概要(和文)」より
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[Journal Article] High-Energy Spectroscopic Study of the III-V Nitride-Based Diluted Magnetic Semiconductor Ga,Mn.N2005
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, H.Hirata, K.Takubo, T.Mizokawa, A.Fujimori, J.Okamoto, K.Mamiya, Y.Saito, Y.Muramatsu, H.Ott A.Tanaka, T.Kondo, H.Munekata
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Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Characterization of Magnetic Components in the Diluted Magnetic Semiconductor Znio.0 by X-ray Magnetic Circular Dichroism2005
Author(s)
M.Kobayashi, Y.Ishida, J.I.Hwang, T.Mizokawa, A.Fujimoti, J.Okamot( K.Mamiya, Y.Takeda, T.Okane, Y.Saitoh, Y.Muramatsu, A.Tanaka, H.Saeki, H.Tabata, T.Kawai
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Description
「研究成果報告書概要(欧文)」より
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[Journal Article] High-Energy Spectroscopic Study of the III-V Nitride-Based Diluted Magnetic Semiconductor Ga_<1-x>Mn_xN2005
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, H, Hirata, K.Takubo, T.Mizokawa, A.Fujimori, J.Okamoto, K.Mamiya, Y.Saito, Y.Muramatsu, H.Ott, A.Tanaka, T.Kondo, H.Munekata
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Journal Title
Related Report
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[Journal Article] Characterization of Magnetic Components in the Diluted Magnetic Semiconductor Zn_<1-x>Co_xO by X-ray Magnetic Circular Dichroism2005
Author(s)
M.Kobayashi, Y.Ishida, J.I.Hwang, T.Mizokawa, A.Fujimori, J.Okamoto, K.Mamiya, Y.Takeda, T.Okane, Y.Saitoh, Y.Muramatsu, A.Tanaka, H.Saeki, H.Tabata, T.Kawai
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Related Report
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[Journal Article] Photoemission and Core-Level Magnetic Circular Dichroism Studies of Diluted Magnetic Semiconductors, Proceedings of XIV-th International Conference on Vacuum Ultraviolet Radiation Physics2005
Author(s)
A.Fujimori, J.Okabayashi, Y.Takeda, T.Mizokawa, J.Okamoto, K.Mamiya, Y.Saitoh, Y.Muramatsu, M.Oshima, S.Ohya, M.Tanaka
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Journal Title
J.Electron Spectrosc.Relat, Phenom 144-147
Pages: 701-705
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[Journal Article] Photoemission and Core-Level Magnetic Circular Dichroism Studies of Diluted Magnetic Semiconductors2005
Author(s)
A.Fujimori, J.Okabayashi, Y.Takeda, T.Mizokawa, J.Okamoto, K.Mamiya, Y.Saitoh, Y.Muramatsu, M.Oshima, S.Ohya, M.Tanaka
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Journal Title
J.Electron Spectrosc.Relat.Phenom. (印刷中)
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[Journal Article] X-ray absorption spectroscopy of transition-metal- doped dulited Magnetic semiconductors Zn_<1-x>Mn_xO2004
Author(s)
J.Okabayashi, K.Ono, M.Mizuguchi, M.Oshima, T.Mizokawa, A.Fujimori, S.Sen Gupta, D.D.Sarma, M.Yuri, C.T.Chen, T.Fukumura, M.Kawasaki
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Journal Title
J. Appl. Phys. 95
Pages: 3573-3575
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[Journal Article] Novel Spingtronic Materials Based on Ferromagnetic Semiconductor Chalcopyrites2004
Author(s)
G.A.Medvedkin, S.I.Goloshchapov, V.G.Voevodin, K.Sato, T.Ishibashi, S.Mitani, K.Takanashi, A.Fujimori, Y.Ishida, J.Okabayashi, D.D.Sarma
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Journal Title
Interntl. J. Nanoscience 3
Pages: 39-50
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[Journal Article] X-ray absorption spectroscopy of transition-metal-doped dulited magnetic semiconductors Zni,. MnO2004
Author(s)
J.Okabayashi, K.Ono, M.Muzuguchi, M.Oshima, T.Mizokawa, A.Fujimori, S.Sen Gupta, D.D.Sarma, M.Yuri, C.T.Chen, T.Fukumura, M.Kawasaki
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「研究成果報告書概要(欧文)」より
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[Journal Article] Novel Spingtronic Materials Based on Ferromagnetic Semiconductor Chalcopyrites2004
Author(s)
G.A.Medvedkin, S.I.Goloshchapov, V.G.Voevodin, K.Sato T.Ishibashi, S.Mitani, K.Takanashi, A.Fujimori, Y.Ishida, J.Okabayashi, D.D.Sarma
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Journal Title
Internal, J. Nanoscience 3
Pages: 39-50
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Novel Spingtronic Materials Based on Ferromagnetic Semiconductor Chalcopyrites2004
Author(s)
G.A.Medvedkin, S.I.Goloshchapov, V.G.Voevodin, K.Sato, T.Ishibashi, S.Mitani, K.Takanashi, A.Fujimori, Y.Ishida, J.Okabayashi, D.D.Sarma
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Journal Title
Interntl.J.Nanoscience 3
Pages: 39-50
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[Journal Article] Novel Mn-doped chalcopyrites2003
Author(s)
K.Sato, G.A.Medvedkin, T.Ishibashi, S.Mitani, K.Takanashi, Y.Ishida, D.D.Sarma, J.Okabayashi, A.Fujimori, T.Kamatani, H.Akai
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Journal Title
J. Phys. Chem. Solids 64
Pages: 1461-1468
Description
「研究成果報告書概要(和文)」より
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[Journal Article] Novel Mn-doped chalcopyrites2003
Author(s)
K.Sato, G..A.Medvedkin, T.Ishibashi, S.Mitani, K.Takanashi, Y.Ishida, D.D.Sarma, J.Okabayashi, A.Fujimori, T.Kamatani, H.Altai
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Journal Title
J. Phys. Chem. Solids 64
Pages: 1461-1468
Description
「研究成果報告書概要(欧文)」より
Related Report
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[Journal Article] 「研究成果報告書概要(欧文)」より
Author(s)
A.Fujimori, J.Okabayashi, Y.Takeda, T.Mizokawa, J.Okamoto K.Mamiya, Y.Saitoh, Y.Muramatsu, M.Oshima, S.Ohya, M.Tanaka
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Journal Title
J. Electron Sepctrosc. Relat. Phenom 144-147
Pages: 701-705
Related Report
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[Journal Article] Photoemission and X-Ray Absorption Studies of the Electronic Structure of GaN-Based Diluted Magnetic Semiconductors, {Proceedings of 6th International Conference on Nitride Semiconductors
Author(s)
J.I.Hwang, Y.Ishida, M.Kobayashi, Y.Osafune, T.Mizokawa, A.Fujimori, Y.Takeda, K.Terai, S-i.Fujimori, Y.Saitoh, Y.Muramatsu, A.Tanaka, T.Kondo, H.Munekata, M.Hashimoto, H.Tanaka, S.Hasegawa, H.Asahi
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Journal Title
Physica Status Solidi B (印刷中)
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[Publications] O.Rader, C.Pampuch, A.M.Shikin, W.Gudat, I.Okabayashi, T.Mizokawa, A.Fujimori, T.Hayashi, M.Tanaka, A.Tanaka, A.Kimura: "Resonant photoemission of Ga_<1-x>Mn_xAs at the Mn L-edge"Phys.Rev.B. 69. 075202-1-075202-7 (2004)
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[Publications] J.Okabayashi, K.Ono, M.Mizuguchi, M.Oshima, T.Mizokawa, A.Fujimori, S.Sen Gupta, D.D.Sarma, M.Yuri, C.T.Chen, T.Fukumura, M.Kawasaki: "X-ray absorption spectroscopy of transition-metal-doped dulited magnetic semiconductors Zn_<1-x>Mn_xO"J.Appl.Phys.. (印刷中). (2004)
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