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Reaction Control of Dynamic Complexes

Research Project

Project/Area Number 14078101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNagoya University

Principal Investigator

TUTSUMI Kazuyuki  Nagoya University, Research Center for Materials Science, Professor, 物質科学国際研究センター, 教授 (10155096)

Co-Investigator(Kenkyū-buntansha) KIRA Mitsuo  Tohoku University, Graduate School of Science, Professor (April 2002-March 2004), 大学院理学研究科, 教授 (40004452)
IKARIYA Takao  Tokvo Institute of Technology, Graduate School of Science and Engineering, Professor, 大学院理工学研究科, 教授 (30107552)
OSHIMA Koichi  Kyoto University, Graduate School of Engineering, Professor, 大学院工学研究科, 教授 (00111922)
CHUJO Yoshiki  Kyoto University, Graduate School of Engineering, Professor, 大学院工学研究科, 教授 (70144128)
FUMIYUKI Ozawa  Kyoto University, Institute for Chemical Research, Professor, 化学研究所, 教授 (40134837)
Project Period (FY) 2002 – 2005
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥199,600,000 (Direct Cost: ¥199,600,000)
Fiscal Year 2006: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2005: ¥29,000,000 (Direct Cost: ¥29,000,000)
Fiscal Year 2004: ¥28,000,000 (Direct Cost: ¥28,000,000)
Fiscal Year 2003: ¥23,900,000 (Direct Cost: ¥23,900,000)
Fiscal Year 2002: ¥115,700,000 (Direct Cost: ¥115,700,000)
KeywordsDynamic Complex / Transition Metal Complex / Main Group Element / Chemical Reaction / Inorganic Chemistry / Organic Chemistry / Catalytic Chemistry / Oreanometallic Chemistry / 反応制御 / 触媒反応 / 金属酵素 / 反応 / 環境対応 / 触媒・化学プロセス / メゾスコピック系 / 自在制御
Research Abstract

We have established a new methodology for the manipulation of heavy-element compounds, the reactions of which have been thought difficult to control. A family of heavy-element compounds is stereoelectronically "dynamic" and rich in functionality, and our mission have lead to the development of environmentally-benign catalysts and new functional materials, and to the construction of model metalloenzymes. The newly-exploited reactions and compounds of heavy elements have provided the bases for the development of societally important research areas, such as environmental chemistry, life sciences, and nanoscience.
Under the leadership of the head investigator, the objectives and targets of this research project was well taken by every member of the organization, and numerous outstanding research outputs have been published. Aside from research activity, this project held 5 symposia in public periodically, 3 international symposia in 2003, 2004, 2005. In addition, yearly research reports and 6 PR brochures have been published.
The project body consisted of 4 sub-groups, two of which have dealt with creation and fundamental aspects of dynamic complexes, and the other two of which carried out research on application of the dynamic complexes. Close cooperation between the sub-groups was successfully achieved, and inter-group meetings were organized. This project also encouraged young researchers to form cooperative joint research plans, and provided them with extra financial support upon a request base. The accomplishments of the project are beyond what we anticipated, and they have been rated high by the evaluation committee.

Report

(6 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (48 results)

All 2006 2005 2004 Other

All Journal Article (36 results) Publications (12 results)

  • [Journal Article] New nickel(II) thiolates with a flexible cyclo-Ni_<10>S_<20> framework2006

    • Author(s)
      Zhang, C., Takada, S., Kolzer, M., Matsumoto, T., Tatsumi, K.
    • Journal Title

      Angew. Chem.,Int. Ed. 45

      Pages: 3768-3772

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis of Oxo- and Sulfido-Bridged Germanium-Ruthenium Complexes and Reactions on the Chalcogenido Bridges2006

    • Author(s)
      Matsumoto, T., Nakaya, Y., Tatsumi, K.
    • Journal Title

      Organometallics 25

      Pages: 4835-4845

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Palladium-Catalysed Stereo- and Regiospecific Allylation of Aryl Halides with Homoallyl Alcohols via Retro-Allylation2006

    • Author(s)
      Hayashi, S., Hirano, K., Yorimitsu, H., K.Oshima
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 2210-2211

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides : A Complement to the Heck Reaction2006

    • Author(s)
      Affo, W., Ohmiya, H., Fujioka, T., Ikeda, Y., Nakamura, T., Yorimitsu, H., Oshima, K., Imamura, Y., Mizuta, T., Miyoshi K.
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 8068-8077

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Bifunctional Transition Metal-Based Molecular Catalysts for Assymmetric Syntheses2006

    • Author(s)
      Ikariya, T., Murata, K., Noyori, R.
    • Journal Title

      Org. Biomol. Chem 4

      Pages: 393-406

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Cyclodehydration of cis-2-Butene-1,4-diol with Active Methylene Compounds Catalyzed by a Diphophinidenecyclobutene-coordinated Palladium Complex2006

    • Author(s)
      Murakami, H., Matsui, Y., Ozawa, F., Yoshifuji, M.
    • Journal Title

      J. Organometal. Chem. 691

      Pages: 3151-3156

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thermal, Structural, and Viscoelastic Characterization of cis-Poly(phenylene vinylene) Related to its Photo-Isomerization2006

    • Author(s)
      Katayama H., Ozawa, F., Matsumiya, Y., Watanabe, H.
    • Journal Title

      Polymer J. 38

      Pages: 184-189

    • NAID

      10017286223

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Bifunctional transition metal-based molecular catalysts for asymmetric syntheses2006

    • Author(s)
      T.Ikariya, K.Murata, R.Noyori
    • Journal Title

      Org. Biomol. Chem. 4

      Pages: 393-406

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Molybdenum Carbonyl Complexes with Citrate and its Relevant Carboxylates2005

    • Author(s)
      Takuma, M., Ohki, Y., Tatsumi, K..
    • Journal Title

      Organometallics. 24

      Pages: 1344-1347

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)_2(CN)_2(μ-SCH_2CH_2CH_2S)Ni(S_2CNR_2)]~- Modeling the Active Site of [NiFe]2005

    • Author(s)
      Li, Z., Ohki, Y., Tatsumi, K
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 8950-8951

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Sulfido-bridged Dinuclear Molybdenum-Copper Complexes Related to the Active Site of CO Dehydrogenase : [(dithiolate)Mo(O)S_2Cu(SAr)]~<2->(dithiolate = 1,2-S_2C_6H_4, 1,2-S_2C_6H_2-3,6-Cl_2, 1,2-S_2C_2H_4)2005

    • Author(s)
      Takuma, M., Ohki, Y., Tatsumi, K.
    • Journal Title

      Inorg. Chem. 44

      Pages: 6034-6043

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions with Azide and Azo Compounds : Formation of a Sulfenamide Complex via Cleavage of an Azo N=N Bond2005

    • Author(s)
      Komuro, T., Matsuo, T., Kawaguchi, H., Tatsumi, K
    • Journal Title

      Inorg. Chem. 44

      Pages: 175-177

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stereocontrolled Synthesis and Optical Properties of All-cis Poly(phenylene vinylene)s (PPVs) : A Method for Direct Patterning of PPVs2005

    • Author(s)
      Katayama, H., Nagao, M., Nishimura, T., Matsui, Y., Umeda, K., Akamatsu, K., Tsuruoka, T., Nawafune, H., Ozawa, F
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 4350-4353

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Insertion of Phenylacetylene into Pt(SnMe_3)_2(PMe_2Ph)_22005

    • Author(s)
      Sagawa, T., Ohtsuki, K., Ishiyama, T., Ozawa, F.
    • Journal Title

      Organometallics. 24

      Pages: 1670-1677

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Double Stimuli-responsive Behavior of Aliphatic Poly(urethane-amine)s Derived from Supercritical Carbon Dioxide2005

    • Author(s)
      O.Ihata, Y.Kayaki, T.Ikariya
    • Journal Title

      Chem Commun..

      Pages: 2268-2270

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Cp*Ru(PN) Complexes-catalyzed Isomerization of Allylic Alcohols and Its Application to the Asymmetric Synthesis of Muscone2005

    • Author(s)
      M.Ito, S.Kitahara, T.Ikariya
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 6172-6173

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Microporous Nanocomposites of Pd and Au Nanoparticles via Hierarchical Self-Assembly2005

    • Author(s)
      Wang, X., Naka, K., Zhu, M., Itoh, H., Chujo, Y.
    • Journal Title

      Langmui. 21

      Pages: 12395-12398

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Self-Assembly of Gold Nanoparticles Utilizing a Charge-Transfer Interaction between Carbazolyl and Dinitrophenyl Units2005

    • Author(s)
      Naka, K., Itoh, H., Chujo, Y.
    • Journal Title

      Bull. Chem. Soc. Jpn. 78

      Pages: 501-505

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Phosphorus-Bridged [1.1]Ferrocenophane with syn and anti Conformations2005

    • Author(s)
      Mizuta, T., Imamura, Y., Miyoshi, K., Yorimitsu, H., Oshima, K
    • Journal Title

      Organometallic. 24

      Pages: 990-996

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis of medium-and large-sized lactones in an aqueous-organic biphasic system2005

    • Author(s)
      Konoshita, H., Shinokubo, H., Oshima, K
    • Journal Title

      Angew. Chem. Int. Ed. 44

      Pages: 2397-2400

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Molybdenum Carbonyl Complexes with Citrate and its Relevant Carboxylates2005

    • Author(s)
      Takuma, M., Ohki, Y., Tatsumi, K.
    • Journal Title

      Organometallics. 46

      Pages: 1344-1347

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)2(CN)2 (R-SCH2CH2CH2S)Ni(S2CNR2)J- Modeling the Active Site of [Ni Fe] Hydrogenase2005

    • Author(s)
      Li, Z., Ohki, Y., Tatsumi, K
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 8950-8951

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Sulfido-bridged Dinuclear Molybdenum佑opper Complexes Related to the Active Site of CO Dehydrogenase : [(dithiolate)Mo(0)S2Cu (SAr)12-(dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-C12, 1,2-S2C2H4)2005

    • Author(s)
      Takuma, M., Ohki, Y., Tatsumi, K.
    • Journal Title

      Inorg. Chem. 44

      Pages: 6034-6043

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Insertion of Phenylacetylene into Pt(SnMe3)2(PMe2Ph)22005

    • Author(s)
      Sagawa, T., Ohtsuki, K., Ishiyama, T., Ozawa, F.
    • Journal Title

      Organometallics. 24

      Pages: 1670-1677

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Double Stimuli-responsive Behavior of Aliphatic Poly(urethane- amine)s Derived from Supercritical Carbon Dioxide2005

    • Author(s)
      O.Ihata, Y.Kayaki, T.Ikariya
    • Journal Title

      Chem Commun.

      Pages: 2268-2270

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis of medium-and large-sized lactones in an aqueous- organic biphasic system2005

    • Author(s)
      Kinoshita, H., Shinokubo, H., Oshima, K.
    • Journal Title

      ngew. Chem. Int. Ed. 44

      Pages: 2397-2400

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)_2 (CN)_2(μ-SCH_2CH_2CH_2S)Ni(S_2CNR_2)]^-Modeling the Active Site of [NiFe] Hydrogenase2005

    • Author(s)
      Li, Z., Ohki, Y., Tatsumi, K
    • Journal Title

      Chem. Lett. 34

      Pages: 172-173

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Molybdenum Carbonyl Complexes with Citrate and its Relevant Carboxylates2005

    • Author(s)
      Takuma, M., Ohki, Y., Tatsumi, K
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 8950-8951

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Microporous Nanocomposites of Pd and Au Nanoparticles via Hierarchical Self-Assembly2005

    • Author(s)
      Wang, X., Naka K., Zhu, M., Itoh, H., Chujo, Y.
    • Journal Title

      Langmuir 21

      Pages: 12395-12398

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Recent Rapid Progress in Asymmetric Allylic Substitutions Catalyzed by Chiral Copper Complexes2005

    • Author(s)
      Yorimitsu, H., Oshima, K.
    • Journal Title

      Angew. Chem. Int. Ed. 44

      Pages: 4435-4439

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis of [2Fe-2S] and [4Fe-4S] Clusters Having Terminal Amide Ligands from an Fe(II) Amide Complex2005

    • Author(s)
      Y.Ohki, Y.Sunada, K.Tatsumi
    • Journal Title

      Chem.Lett. 34

      Pages: 172-173

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Homo- and Heteronuclear Complexes of (Pentamethylcyclopentadienyl) rhodium)III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphate2004

    • Author(s)
      Y.Sunada, K.Tatsumi 他
    • Journal Title

      Eur.J.Inorg.Chem.

      Pages: 134-142

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Complex of Half-Sandwich Ruthenium(II)2004

    • Author(s)
      Y.Ohki, K.Tatsumi 他
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 2290-2293

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Structural Characterization of Silanethiolato Complexes Having tert-Butyldimethylsilyl and Trimethylsilyl Groups2004

    • Author(s)
      T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi
    • Journal Title

      J.Chem.Soc., Dalton

      Pages: 1618-1625

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reactions of Rhodium(III) and Iridium(III) Complexes Bearing a P, O-Coordination with Tetracyanoethylene in the Presence of KPF_62004

    • Author(s)
      Y.Sunada, K.Tatsumi 他
    • Journal Title

      Inorg.Chim.Acta 357

      Pages: 2833-2840

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate2004

    • Author(s)
      T.Okuyama, Y.Ohki, K.Tatsumi 他
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 7548-7558

    • Related Report
      2004 Annual Research Report
  • [Publications] Tatsumi, K.et al.: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc.. 125(26). 7978-7988 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Tatsumi, K.et al.: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases"J.Am.Chem.Soc.. 125(14). 4052-4053 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kira, M.et al.: "A stable silicon-based allene analogue with a formally sp-hybridized silicon atom"Nature. 421. 725-727 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Ikariya, T.et al.: "Enhanced Product Selectivity in Continuous N-Methylation of Aminoalcohols over Solid Acid Catalysts with Supercritical Methanol"Angew Chem.Int.Ed.Engl.. 41(18). 3476-3479 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] Oshima, K.et al.: "Cobalt-Catalyzed Heck-Type Reaction of Alkyl Halides with Styrenes"J.Am.Chem.Soc.. 124(23). 6514-6515 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] Ozawa, F.et al.: "(π-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB) : Highly Active Catalysts for Direct Conversion of Allylic Alcohols"J.Am.Chem.Soc.. 124(37). 10968-10969 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc.. 125(8). 2070-2071 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Ishida, T.Iwamoto, C.Kabuto, M.Kira: "A stable silicon-based allene analogue with a formally sp-hybridized silicon atom"Nature. 421(6924). 725-727 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Oku, T.Ikariya: "Enhanced Product Selectivity in Continuous N-Methylation of Aminoalcohols over Solid Acid Catalysts with Supercritical Methanol"Angew Chem.Int.Ed.Engl.. 41(18). 3476-3479 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Kinoshita, H.Shinokubo, K.Oshima: "Pd(0)-Catalyzed Reaction of Alkynes with Trifurylgermane and CO Providing Acylgermanes : The Example of Hydrometalcarbonylation of Alkynes"J.Am.Chem.Soc. 124(16). 4220-4221 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Naka, T.Umeyama, Y.Chujo: "Synthesis of Poly(vnylene-arsine)s. Alternating Radical Copolymerization of Arsenic Atomic Biradical Equivalent and Phenylacetylene"J.Am.Chem.Soc.. 124(23). 6600-6603 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] F.Ozawa, H.Okamoto, S.Kawagishi, S.Yamamoto, T.Minami, M.Yoshifuji: "(π-Allyl) palladium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB) : Highly Active Catalysts for Direct Conversion of Allylic Alcohols"J.Am.Chem.Soc.. 124(37). 10968-10969 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2018-03-28  

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