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New Polymerization Reactions by Dynamic Rare Earth Complexes

Research Project

Project/Area Number 14078224
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionRIKEN

Principal Investigator

HOU Zhaomin  RIKEN, Organometallit Chemistry Laboratory, Chief Scientist, 侯有機金属化学研究室, 主任研究員 (10261158)

Project Period (FY) 2002 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥24,800,000 (Direct Cost: ¥24,800,000)
Fiscal Year 2005: ¥6,400,000 (Direct Cost: ¥6,400,000)
Fiscal Year 2004: ¥6,400,000 (Direct Cost: ¥6,400,000)
Fiscal Year 2003: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 2002: ¥6,000,000 (Direct Cost: ¥6,000,000)
Keywordsrare earth metal / metallocene catalyst / cluster / polymerization / copolymerization / stylene / conjugated diene / cyclic olefin / 希土類ビスアルキル錯体 / ジシクロペンタジエン / エチレン / 三元共重合 / 二酸化炭素 / シクロヘキセンオキシド / カルボキシレート錯体 / シンジオタクチックポリスチレ / ノルボルネン / スカンジウム / π-共役ポリマー / 共重合体 / ポリエンイン / ラクトン / 芳香族ジイン / 希土類触媒 / オレフィン重合 / 希土類シリル錯体 / 二価希土類アルキル錯体 / ハーフメタロセン錯体 / アルキンの二重化 / エンーイン化合物の合成
Research Abstract

1. Synthesis of Rare Earth Metal Bis(alkyl) Complexes and Conversion into Cationic Mono(alkyl) Active Species : Recently, considerable attention has been directed to rare earth metal bis(alkyl) complexes, since such complexes or cationic mono(alkyl) species prepared from them are expected to provide a sterically and electronically more unsaturated metal center and thus to show unique reactivity that differs from those of the conventional metallocenens. In this study, a series of half-sandwich rare earth metal bis(alkyl) complexes have been successfully prepared from Ln(CH_2SiMe_3)_3 (2thf) and C_5Me_4HSiMe_3. Binuclear rare earth metal bis(alkyl) complexes, in which the two metal centers are bridged by two phosphido ligands, and non-metallocene yttrium bis(alkyl) complexes have also been obtained in an analogous way. These bis(alkyl) complexes can be readily converted to the corresponding cationic mono(alkyl) species by treating with 1 equiv of [Ph_3C][B(C_6F_5)_4].
2. Development of Hi … More ghly Selective Copolymerization Reactions Catalyzed by Cationic Rare Erath Metal Mono(alkyl) Species : These cationic rare earth metal species can act as excellent catalysts for the region-and stereospecific polymerization and copolymerization of various olefins. They exhibit excellent activities and selectivity for syndiospecific copolymerization of styrene with ethylene, alternating copolymerization of ethylene with norbornene or dicyclopentadiene, and isospecific 3,4-polymerization and living cis-1,4-polymerization of isoprene. Most of these polymerization reactions are unique to the rare earth metal catalysts, and are difficult to achieve by previously known catalyst systems.
3. Synthesis of Rare Earth Metal Hydride Clusters and Studies on Synergistic Reactivity of These Complexes : In the course of these studies, we found that the half-sandwich rare earth metal bis(alkyl) complexes can readily react with H_2 to afford the corresponding tetranuclear octahydrido complexes. These hydride clusters exhibit high reactivities towards various multiple bonds. For example, the reaction with carbon monoxide afforded selectively ethylene under mild conditions. Less

Report

(5 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (115 results)

All 2007 2006 2005 2004 2003 2002 Other

All Journal Article (86 results) Book (4 results) Patent(Industrial Property Rights) (12 results) Publications (13 results)

  • [Journal Article] Modeling η^5-C_5Me_4SiMe_3 with η^3-C_3H_5 for DFT Study of a Tetranuclear Yttrium Polyhydrido Complex[(η^5-C_5Me_4SiMe_3)YH_2]_42007

    • Author(s)
      Luo Y.
    • Journal Title

      Int. J. Quantum Chem 107

      Pages: 374-381

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Rare Earth Metal Bis(Alkyl) Complexes Bearing a Monodentate Arylamido Ancillary Ligand : Synthesis, Structure, and Olefin Polymerization Catalysis.2007

    • Author(s)
      Lou Y.
    • Journal Title

      Journal of Organometallic Chemistry 692

      Pages: 536-544

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare Earth Metal Alkyls bearing a Bis-(phosphinophenyl) amido (PNP) Ancillary Ligand. An Excellent Catalyst System for Living cis-1,4-Polymerization and Copolymerization of Isoprene and Butadiene2007

    • Author(s)
      Zhang L.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 1909-1913

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Modeling η5-C5Me4SiMe3 with η3-C3H5 for DFT Study of a Tetranuclear Yttrium Polyhydrido Complex [(η5-05Me4SiMe3)YH2]42007

    • Author(s)
      Luo Y., Hou Z.
    • Journal Title

      Int. J. Quantum Chem. 107

      Pages: 374-381

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Rare Earth Metal Bis(alkyl) Complexes Bearing a Monodentate Arylamido Ancillary Ligand. Synthesis, Structure, and Olefin Polymerization Catalysis2007

    • Author(s)
      Luo Y., Nishiura M., Hou Z.
    • Journal Title

      J. Organomet. Chem. (Special Issue), 692

      Pages: 536-544

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare Earth Metal Alkyls bearing a Bis-(phosphinophenyl)amido (PNP) Ancillary Ligand. An Excellent Catalyst System for Living cis- 1,4-Polymerization and Copolymerization of Isoprene and Butadiene2007

    • Author(s)
      Zhang L., Suzuki T., Luo Y., Nishiura M., Hou Z.
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 1909-1913

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines2006

    • Author(s)
      Zhang W.
    • Journal Title

      Chem. Commun 36

      Pages: 3812-3814

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence2006

    • Author(s)
      Liu Y.
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 5592-5593

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters2006

    • Author(s)
      Shima T.
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 8124-8125

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Five-Center Rather than a Four-Center Transition State for Alkene Insertion into the Metal-Alkyl Bond of a Cationic Binuclear Yttrium Complex2006

    • Author(s)
      Luo Y.
    • Journal Title

      Organometallics 25

      Pages: 6162-6165

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare-Earth Polyhydrido Complexes : Synthesis, Structure, and Catalytic Activity for the cis-1,4-Selective Polymerization of 1,3-Cyclohexadiene2006

    • Author(s)
      Li X.
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 8184-8188

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare Earth Metal Alkyls as Novel Catalysts for Olefin Polymerization and Copolymerization2006

    • Author(s)
      Hou Z.
    • Journal Title

      Journal of Organometallic Chemistry 691

      Pages: 3114-3121

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Catalytic Addition of Secondary Amines to Carbodiimides by a Half-Sendwich Yttrium Complex : An Efficient Route to N, N', N", N"-Tetra-substituted Guanidines2006

    • Author(s)
      Zhang W.
    • Journal Title

      SYNLETT 8

      Pages: 1213-1216

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Polymerization of l-Hexen and Copolymerization of Ethylene with l-Hexene Catalyzed by Cationic Half-Sandwich Scandium Alkyls2006

    • Author(s)
      Luo Y.
    • Journal Title

      Studies in Surface Science and Catalysis 161

      Pages: 95-104

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Studies on a System with a 4-Coordinate Hydrogen Atom in an Yttrium Cluster2006

    • Author(s)
      Yousufuddim M.
    • Journal Title

      Physica B 385-386

      Pages: 231-233

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines2006

    • Author(s)
      Zhang W, Nishiura M., Hou Z.
    • Journal Title

      Chem. Commun. 36

      Pages: 3812-3814

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] π-Conjugated Aromatic Enynes as a Single Emitting-Component for White Electroluminescence2006

    • Author(s)
      Liu Y, Nishiura M., Wang Y., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 5592-5593

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters2006

    • Author(s)
      Shima T., Hou Z.
    • Journal Title

      J. Am. Chem. Soc 128

      Pages: 8124-8125

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Five-Center Rather than a Four-Center Transition State for Alkene Insertion into the Metal-Alkyl Bond of a Cationic Binuclear Yttrium Complex2006

    • Author(s)
      Luo Y., Hou Z.
    • Journal Title

      Organometallics 25

      Pages: 6162-6165

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare-Earth Polyhydrido Complexes : Synthesis, Structure, and Catalytic Activity for the cis-1,4-Selective Polymerization of 1,3-Cyclohexadiene2006

    • Author(s)
      Li X., Baldamus J., Nishiura M., Tardif O., Hou Z.
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 8184-8188

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cationic Rare Earth Metal Alkyls as Novel Catalysts for Olefin Polymerization and Copolymerization2006

    • Author(s)
      Hou Z., Luo Y., Li X.
    • Journal Title

      J. Organomet. Chem. 691

      Pages: 3114-3121

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Catalytic Addition of Secondary Amines to Carbodiimides by a Half-Sandwich Yttrium Complex : An Efficient Route to N,N',N,N-Tetra-substituted Guanidines2006

    • Author(s)
      Zhang W, Nishiura M., Hou Z.
    • Journal Title

      Synlett (a special issue)

      Pages: 1213-1216

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Polymerization of 1-Hexen and Copolymerization of Ethylene with 1-Hexene Catalyzed by Cationic Half-Sandwich Scandium Alkyls2006

    • Author(s)
      Luo Y., Hou Z.
    • Journal Title

      Studies in Surface Science and Catalysis 161

      Pages: 95-104

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Studies on a System with a 4-Coordinate Hydrogen Atom in an Yttrium Cluster2006

    • Author(s)
      Yousufuddin M., Baldamus J., Tardif O., Hou Z., Mason S.A., Mcintyre G.J., Bau R.
    • Journal Title

      Physica B 385-386

      Pages: 231-233

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lanthanide-Imedo Complexes and their Reactions with Benzonitrile2005

    • Author(s)
      Cui D.
    • Journal Title

      Angew. Chem., Int. Ed. 44

      Pages: 959-962

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alternating Ethylene-Norbounene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes2005

    • Author(s)
      Li X.
    • Journal Title

      Angew. Chem., Int. Ed. 44

      Pages: 962-965

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Organo Rare Earth Metal Complexes2005

    • Author(s)
      Cui D.
    • Journal Title

      Macromolecules 38

      Pages: 4089-4095

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] DFT Study of the Tetranuclear Lutetium and Yttrium Polyhydride Cluster Complexes [(C_5Me_4SiMe_3)_4Ln_4H_8](Ln = Lu, Y) that Contain Four-Coordinate Hydrogen Atom2005

    • Author(s)
      Luo Y.
    • Journal Title

      Organometallics 24

      Pages: 4362-4366

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene and Styrene2005

    • Author(s)
      Li X.
    • Journal Title

      Macromolecules 38

      Pages: 6767-6769

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor2005

    • Author(s)
      Zhang L.
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 14562-14563

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes2005

    • Author(s)
      Zhang W.
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 16788-16789

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lanthanide-Imido Complexes and their Rreactions with Benzonitrile2005

    • Author(s)
      Cui D., Nishiura M., Hou Z.
    • Journal Title

      Angew. Chem., Int. Ed. 44

      Pages: 959-962

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes2005

    • Author(s)
      Li X., Baldamus J., Hou Z.
    • Journal Title

      Angew. Chem., Int. Ed. 44

      Pages: 962-965

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Organo Rare Earth Metal Complexes2005

    • Author(s)
      Cui D., Nishiura M., Hou Z.
    • Journal Title

      Macromolecules 38

      Pages: 4089-4095

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] DFT Study of the Tetranuclear Lutetium and Yttrium Polyhydride Cluster Complexes [(C5Me4SiMe3)4Ln4H8] (Ln = Lu, Y) that Contain Four-Coordinate Hydrogen Atom2005

    • Author(s)
      Luo Y, Baldamus J., Tardif O., Hou Z.
    • Journal Title

      Organometallics 24

      Pages: 4362-4366

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene and Styrene2005

    • Author(s)
      Li X., Hou Z.
    • Journal Title

      Macromolecules 38

      Pages: 6767-6769

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor2005

    • Author(s)
      Zhang L., Luo Y., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 14562-14563

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Catalytic Additon of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes2005

    • Author(s)
      Zhang W, Nishiura M., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 16788-16789

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor2005

    • Author(s)
      L.Zhang, Y.Luo, Z.Hou
    • Journal Title

      J.Am.Chem.Soc. 42

      Pages: 14562-14563

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes2005

    • Author(s)
      W.Zhang, M.Nishiura, Z.Hou
    • Journal Title

      J.Am.Chem.Soc. 48

      Pages: 16788-16789

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene, and Styrene2005

    • Author(s)
      X.Li, Z.Hou
    • Journal Title

      Macromolecules 16

      Pages: 6767-6769

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Organo Rare Earth Metal Complexes2005

    • Author(s)
      D.Cui, M.Nishiura, Z.Hou
    • Journal Title

      Macromolecules 10

      Pages: 4089-4095

    • Related Report
      2005 Annual Research Report
  • [Journal Article] DFT Study of the Tetranuclear Lutetium and Yttrium Polyhydride Cluster Complexes[(C_5Me_4SiMe_3)_4Ln_4H_8](Ln=Lu,Y)that Contain a Four-Coordinate Hydrogen Atom2005

    • Author(s)
      Y.Luo, J.Baldamus, O.Tardif, Z.Hou
    • Journal Title

      Organometallics 18

      Pages: 4362-4366

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Half-Sandwich Rare Earth Metal Catalysts for Olefin Polymerization and Copolymerization2005

    • Author(s)
      Z.Hou
    • Journal Title

      有機合成協会誌 11

      Pages: 68-80

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Cationic Half-Sandwich Scandium Catalyzed Alternating E thylene-Norbornene Copolymerization2005

    • Author(s)
      X.Li, J.Baldamus, Z.Hou
    • Journal Title

      Angew.Chem., Int.Ed. 44

      Pages: 962-964

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Rare Earth Metal Imido Complexes and their Reactions with Benzonitrile2005

    • Author(s)
      D.Cui, M.Nishiura, Z.Hou
    • Journal Title

      Angew.Chem., Int.Ed. 44

      Pages: 959-961

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of "(C_5Me_4SiMe_3)LnH_2" Units. Unique Reactivities Toward Unsaturated Bonds2004

    • Author(s)
      Cui D.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 1312-1313

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Novel Binuclear Samarium(II) Complex Bearing Mixed Cyclopentadienide/siloxide Ligands : [(C_5Me_5)Sm{μ-OSi(O^tBu)_3}_3Sm].2004

    • Author(s)
      Nishiura M.
    • Journal Title

      Organometallics 23

      Pages: 1359-1368

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Organolanthanide Catalyzed Regio- and Stereoselective Dimerization of Terminal Alkynes and Polymerization of Aromatic Diynes2004

    • Author(s)
      Nishiura M.
    • Journal Title

      J. Mol. Cat. A : Chem. 213

      Pages: 101-106

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex.2004

    • Author(s)
      Tardif O.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 8080-8081

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization :2004

    • Author(s)
      Luo Y.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 13910-13911

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Diels-Alder Reaction and Double Phenylation in Reaction of Thiophenes with Diphenyliodonium Triflate2004

    • Author(s)
      Zhang B.-X.
    • Journal Title

      Heterocycles 64

      Pages: 199-206

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Tetranuclear rare earth metal polyhydrido complexes composed of (C5Me4SiMe3)LnH2 units. Unique reactivities toward unsaturated C-C, C-N, and C-O bonds2004

    • Author(s)
      Cui D., Tardif O., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 1312-1313

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A novel binuclear samarium(II) complex bearing mixed cyclopentadienide/sikodde ligands : [(C5Me5)Sm{μ-OSi(OtBu)3}3Sm]. Synthesis, structure, electron-transfer, and unusual metal-coordination reactions2004

    • Author(s)
      Nishiura M., Hou Z., Wakatsuki Y
    • Journal Title

      Organometallics 23

      Pages: 1359-1368

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Organolanthanide catalyzed regio-and stereoselective dimerization of terminal alkynes and polymerization of aromatic diynes2004

    • Author(s)
      Nishiura M., Hou Z.
    • Journal Title

      J. Mol Cat. A 213

      Pages: 101-106

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Hydrogenation of carbon dioxide and aryl isocyanates by a tetranuclear tetrahydrido yttrium complex. Isolation, structures, and CO2 insertion reactions of methylene diolate and μ3-oxo yttrium complexes2004

    • Author(s)
      Tardif O., Hashizume D., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 8080-8081

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Scandium half-metallocene-catalyzed syndiospecific styrene polymerization and styrene-ethylene copolymerization : unprecedented incorporation of syndiotactic styrene-styrene sequences in styrene-ethylene copolymers2004

    • Author(s)
      Luo Y., Baldamus, J., Hou Z.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 13910-13911

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Diels-Alder Reaction and Double Phenylation in Reaction of Thiophenes with Diphenyliodonium Triflate2004

    • Author(s)
      Zhang B.-X., Nuka T., Fujiwara Y, Yamaji T., Hou Z., T.Kitamura
    • Journal Title

      Heterocycles 64

      Pages: 199-206

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization....2004

    • Author(s)
      Y.Luo, J.Baldamus, Z.Hou
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 13910-13911

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex.2004

    • Author(s)
      O.Tardif, D.Hashizume, Z.Hou
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 8080-8081

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Novel Binuclear Sm(II) Complex Bearing Mixed Cyclopentadienide/Siloxide Ligands2004

    • Author(s)
      M.Nishiura, Z.Hou, Y.Wakatsuki
    • Journal Title

      Organometallics 23

      Pages: 1359-1368

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Organolanthanide-Catalyzed Dimerization of Terminal Alkynes and Polymerization of Aromatic Diynes2004

    • Author(s)
      M.Nishiura, Z.Hou
    • Journal Title

      J.Mol.Cat.A : Chem. 213

      Pages: 101-106

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Isolation and Structural Characterization of a Polyhydrido Lanthanide Cluster Complex Consisting of "(C_5Me_4SiMe_3)LuH_2" Units2003

    • Author(s)
      Tardif O.
    • Journal Title

      Organometallics 22

      Pages: 1171-1173

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Halfmetallocene Complexes2003

    • Author(s)
      Nishiura M.
    • Journal Title

      J. Am. Chem. Soc. 125

      Pages: 1184-1185

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] (Pentamethylcyclopentadienyl) Lanthanide(II) Alkyl and Silyl Complexes : Synthesis, Structures, and Catalysis in Polymerization of Ethylene and Syyrene2003

    • Author(s)
      Hou Z.
    • Journal Title

      Organometallics 22

      Pages: 129-135

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Pronounced Enhancement Brought in by Substituents on the Cyclopentadienyl Ligand : Catalyst system (C_5Me_4R)_"Sm(THF)x/MMAO2003

    • Author(s)
      Kaita S.
    • Journal Title

      Macromolecules 36

      Pages: 7923-7926

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Theoretical Study of Coordination and Insertion of Butadiene to Bis(pentamethylcyclopentadienyl) Samarium Hydride2003

    • Author(s)
      Kaita S.
    • Journal Title

      Organometallics 22

      Pages: 3077-3082

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Reduction of Ketimines by Samarium(II) Complexes. Isolation and Structural Characterization of Samarium(III) Complexes2003

    • Author(s)
      Hou Z.
    • Journal Title

      Organometallics 22

      Pages: 3586-3592

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Rare Earth Alkyl and Hydride Complexes Bearing Silylene-Linked Cyclopentadienyl-Phosphido Ligands.2003

    • Author(s)
      Tardif O.
    • Journal Title

      Tetrahadron 59

      Pages: 10525-10539

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] New Reactions of l-Alkynes Catalyzed by Transition Metal Complexes2003

    • Author(s)
      Wakatsuki Y.
    • Journal Title

      Chem. Record 3

      Pages: 144-157

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Progress in the Chemistry of Rare Earth Metal Alkyl and Hydrido Complexes Bearing Mono(Cyclopentadienyl)Ligands2003

    • Author(s)
      Hou Z.
    • Journal Title

      Bull. Chem. Soc. Jpn. 76

      Pages: 2253-2266

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ultimately Specific 1,4-cis Polymerization of 1,3-Butadiene with a Novel Gadolinium Catalyst2003

    • Author(s)
      Kaita S.
    • Journal Title

      Macromol. Rapid Commun. 24

      Pages: 180-184

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Isolation and Structural Characterization of a Polyhydrido Lanthanide Cluster Complex Consisting of (C5Me4SiMe3)LuH2 Units2003

    • Author(s)
      Tardif O., Nishiura M., Hou Z.
    • Journal Title

      Organometallics 22

      Pages: 1171-1173

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel Z-selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Halfmetallocenecomplexes2003

    • Author(s)
      Nishiura M., Hou Z., Wakatsuki Y., Yamaki T., Miyamoto T.
    • Journal Title

      J. Am. Chem. Soc. 125

      Pages: 1184-1185

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] (Pentamethylcyclopentadienyl) Lanthanide(II) Alkyl and Silylcomplexes : Synthesis, Structures, and Catalysis in Polymerization of Ethylene and Styrene2003

    • Author(s)
      Hou Z., Zhang Y., Nishiura M., Wakatsuki Y.
    • Journal Title

      Organometallics 22

      Pages: 129-135

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Pronounced Enhancement Brought in by Substituents on the Cyclopentadienyl ligand : Catalyst system (C5Me4R)2Sm(THF)x/MMAO (R=Et, iPr, nBu, TMS; MMAO = modified methylaluminoxane) for 1,4-cis stereospecific polymerizaion of 1,3-butadiene in cyclohexane solvent2003

    • Author(s)
      Kaita S., Takeguchi Y., Hou Z., Nishiura M., Doi Y., Wakatsuki Y.
    • Journal Title

      Macromolecules 36

      Pages: 7923-7926

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Theoretical study of coordination and insertion of butadiene to bis(pentamethylcyclopentadienyl) samarium hydride2003

    • Author(s)
      Kaita S., Koga N., Hou Z., Doi Y., Wakatsuki Y.
    • Journal Title

      Organometallics 22

      Pages: 3077-3082

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Reduction of ketimines by samarium(II) complexes. Isolation and structural haracterization of samarium(III) η1-aminehil-ketimido and 2-ketimine complexes2003

    • Author(s)
      Hou Z., Yoda C, Koizumi T., Nishiura M., Wakatsuki Y., Fukuzawa S., Takats J.
    • Journal Title

      Organometallics 22

      Pages: 3586-3592

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Rare earth alkyl and hydride complexes bearing silylene-linked cydlopentadienyl-phosphido ligands. Synthesis, structures, and catalysis in olefin hydrosilylation and ethylene polymerization2003

    • Author(s)
      Tardif O., Nishiura M., Hou Z.
    • Journal Title

      Tetrahedron 59

      Pages: 10525-10539

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] New reactions of 1-alkynes catalyzed by transition metal complexes2003

    • Author(s)
      Wakatsuki Y., Hou Z., Tokunaga M.
    • Journal Title

      Chem. Record 3

      Pages: 144-157

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent progress in the chemistry of rare arth metal alkyl and hydrido complexes bearing mono(cyclopentadienyl) ligands2003

    • Author(s)
      Hou Z.
    • Journal Title

      Bull. Chem. Soc. Jpn. 76

      Pages: 2253-2266

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ultimately specific 1,4-cis polymerization of 1,3-butadiene with a novel gadolinium catalyst2003

    • Author(s)
      Kaita S., Hou Z., Nishiura M., Doi Y., Kurazumi J., Horiuchi A.C, Wakatsuki Y.
    • Journal Title

      Macromol. Rapid Commun. 24

      Pages: 180-184

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Developments in Organolanthanide Polymerization Catalysts2002

    • Author(s)
      Hou Z.
    • Journal Title

      Coord. Chem. Rev. 231

      Pages: 1-22

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lanthanide(II) Complexes Bearing Mixed Linked and Unlinked Cyclopentadienyl-Monodentate-Anionic Ligands2002

    • Author(s)
      Hou Z.
    • Journal Title

      J. Organomet. Chem. 647

      Pages: 61-70

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Developments in Organolanthanide Polymerization Catalysts2002

    • Author(s)
      Hou Z., Wakatsuki Y.
    • Journal Title

      Coord. Chem. Rev. 231

      Pages: 1-22

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lanthanide(II) Complexes Bearing Mixed Linked and Unlinked Cyclopentadienyl-Monodentate-Anionic Ligands2002

    • Author(s)
      Hou Z., Wakatsuki Y.
    • Journal Title

      J.Organomet. Chem. 647

      Pages: 61-70

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Comprehensive Organometallic Chemistry III2007

    • Author(s)
      Hou Z.
    • Total Pages
      891
    • Publisher
      C-C Bond Formation Through Reaction of Co_2 with C≡C and C=C-C=C
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Catalytic and Stoichiometric Transformations by Multimetallic Rare Earth Metal Complexes", in Multimetallic Catalysts in Organic Synthesis2004

    • Author(s)
      Hou Z.
    • Total Pages
      295
    • Publisher
      Wiley-VCH
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Multimetallic Catalysts in Organic Synthesis2004

    • Author(s)
      Z.Hou
    • Total Pages
      295
    • Publisher
      WILEY-VCH
    • Related Report
      2004 Annual Research Report
  • [Book] Product Class 12 : Organometallic Complexes of Scandium, Yttrium, and the Lanthanides In Science of Synthesis2003

    • Author(s)
      Hou Z.
    • Total Pages
      1070
    • Publisher
      Georg Thieme Verlag
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 三座配位子を含む金属錯体重合用触媒2005

    • Inventor(s)
      鈴木俊彰, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2005-014217
    • Filing Date
      2005-01-21
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] アイソタクチック3,4-イソプレン系重合体2005

    • Inventor(s)
      侯召民, 張立新
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2006-510747
    • Filing Date
      2005-03-04
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] メタロセン錯体を含む重合触媒組成物2005

    • Inventor(s)
      羅雲傑, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2006-528868
    • Filing Date
      2005-07-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] ポリアリレンエチニレンビニレンブロック共重合体2004

    • Inventor(s)
      侯召民, 西浦正芳
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2004-034023
    • Filing Date
      2004-02-10
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] アイソタクチック3,4-イソプレン系重合体2004

    • Inventor(s)
      侯召民, 張立新
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2004-060538
    • Filing Date
      2004-03-04
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 重合用触媒2004

    • Inventor(s)
      会田昭二郎, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2004-158940
    • Filing Date
      2004-05-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] メタロセン錯体を含む重合触媒組成物2004

    • Inventor(s)
      羅雲傑, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2004-197271
    • Filing Date
      2004-07-02
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] メタロセン錯体を含む重合触媒組成物2004

    • Inventor(s)
      羅雲傑, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2004-366159
    • Filing Date
      2004-12-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 重合用触媒2003

    • Inventor(s)
      会田昭二郎, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2003-024347
    • Filing Date
      2003-01-31
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] ポリアリレンエチニレンビニレン及びその製造方法2003

    • Inventor(s)
      西浦正芳, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2003-054847
    • Filing Date
      2003-02-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] ポリアリレンエチニレンビニレン, その製造方法2003

    • Inventor(s)
      西浦正芳, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2003-054849
    • Filing Date
      2003-02-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 重合用触媒2002

    • Inventor(s)
      会田昭二郎, 侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      2002-132993
    • Filing Date
      2002-05-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] D.Cui, O.Tardif, Z.Hou: "Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of "(C_5Me_4SiMe_3)LnH_2" Units. Unique Reactivities toward Unsaturated C-C,"J.Am.Chem.Soc.. 126. 1312-1313 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Nishiura, Z.Hou 他3名: "Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes"J.Am.Chem.Soc.. 125. 1184-1185 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] O.Tardif, M.Nishiura, Z.Hou: "Isolation and Structural Characterization of a Polyhydrido Lanthanide Cluster Complex Consisting of "(C_5Me_4SiMe_3)LuH_2" Units"Organometallics. 22. 1171-1173 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] O.Tardif, M.Nishiura, Z.Hou: "Rare Earth Alkyl and Hydride Complexes bearing Silylene-Linked Cyclopentadienyl-Phosphido Ligands. Synthesis, Structures, and Catalysis"Tetrahedron. 59. 10525-10539 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Z.Hou, Y.Zhang 他2名: "Lanthanide(II) Complexes Bearing Mixed Linked and Unlinked Cp-Monodentate-Anionic Ligands. Synthesis, Structures, and Catalysis"Organometallics. 22. 129-135 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kaita, Z.Hou 他5名: "Novel Two-Component Catalyst [(C_5Me_5)_2Ln][B(C_6F_5)_4]/AIR_3 (Ln=Pr,Bd,Sm, or Gd) for Highly 1,4-Cis Specific Living Polymerization of 1,3 -Butadiene"Macromol.Rapid Commun.. 24. 180-184 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Z.Hou, Y.Wakatsuki: "Recent Developments in Organolanthanide Polymerization Catalysts"Coord. Chem. Rev.. 231・1. 1-22 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Z.Hou, Y.Wakatsuki: "Lanthanide (II) Complexes Bearing Mixed Linked and Unlinked Cyclopentadienyl-Monodentate-Anionic Ligands"J. Organomet. Chem.. 647・1. 61-70 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Z.Hou, Y.Zhang, et al.: "(Pentamethylcyclopentadienyl)lanthanide (II) Alkyl and Silyl Complexes : Synthesis, Structures, and Catalysis in Polymerization of Ethylene and Styrene"Organometallics. 22・1. 129-135 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Kaita, Z.Hou, et al.: "Novel Two-Component Catalyst [(C_5Me_5)_2Ln][B (C_6F_5)_4]/AlR_3(Ln=Pr, Bd, Sm, or Gd) for Highly 1,4-Cis Specific Living Polymerization of 1,3 -Butadiene"Macromol. Rapid Commun.. (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Nishiura, Z.Hou, et al.: "Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes"J. Am. Chem. Soc.. 125・7(in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] O.Tardif, M.Nishiura, Z.Hou: "Isolation and Structural Characterization of a Polyhydrido Lanthanide Cluster Complex Consisting of "(C_5Me_4SiMe_3)LuH_2" Units"Organometallics. 22(in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Z.Hou, Y.Wakatsuki: "Science of Synthesis, Vol. 2(分担執筆)"Georg Thieme Verlag. 1070 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2018-03-28  

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