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Design and development of metallic crystals composed of single-component molecules

Research Project

Project/Area Number 14103005
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field 機能・物性・材料
Research InstitutionThe University of Tokyo

Principal Investigator

KOBAYASHI Akiko  The University of Tokyo, Research Centre for Spectrochemistry, Graduate School of Science, Professor, 大学院・理学系研究科, 教授 (50011705)

Co-Investigator(Kenkyū-buntansha) FUJIWARA Emiko  The University of Tokyo, Research Centre for Spectrochemistry, Graduate School of Science, Research Assistant, 大学院・理学系研究科, 助手 (30361562)
Project Period (FY) 2002 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥72,020,000 (Direct Cost: ¥55,400,000、Indirect Cost: ¥16,620,000)
Fiscal Year 2005: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2004: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2003: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2002: ¥37,180,000 (Direct Cost: ¥28,600,000、Indirect Cost: ¥8,580,000)
KeywordsSingle-Component Molecular Metals / Molecular Conductors / Dithiolate Metal Complex / Antiferromagnetic Phase Transition / Molecular Alloy Systems / Three-Dimensional Fermi Surfaces / 中性単一分子性金属 / ジチオレン錯体 / 混晶 / 単一成分分子性金属 / 拡張型ジチオレン錯体 / 粉末X線回折 / ^1HNMR / 電気伝導度 / 第一原理バンド計算 / 電子吸収スペクトル / HOMO-LUMO gap / 拡張型TTF / 中性単一分子 / 中性単一成分分子金属
Research Abstract

In this work, in order to realize the single-component metallic molecular magnets and molecular superconductors with various extended-TTF ligands, the structures, physical properties and molecular functions of a series of new developed single-component complexes were investigated.
To obtain direct evidence for the existence of Fermi surfaces in the first neutral metal complex molecule [Ni(tmdt)_2] (tmdt=trimethylenetetrathiafulvalenedithiolate), we have carried out experiments to measure magnetic quantum oscillations, namely de Haas-van Alphen (dHvA) oscillations, in high magnetic fields up to 33 T using a microcantilever. The observation of the dHvA signal in [Ni(tmdt)_2] demonstrates that it is a single-component molecular crystal which not only shows metallic conductivity behavior down to low temperatures, but also exhibits high-quality quantum oscillations characteristic of a Fermi surface. These results unambiguously show the existence of 3D Fermi surfaces for both holes and electr … More ons in this molecular crystal.
To create the single-component metallic molecular magnets with a high transition temperature, [Au(tmdt)_2] was developed, which is isostructural to that of [Ni(tmdt)_2]. Unlike the neutral bis (dithiolato) nickel complex, the neutral bis (dithiolato) gold complex has an odd number of total electrons. The spin susceptibilities study of [Au(tmdt)_2] showed an unusual antiferromagnetic phase transition around 110K, which is higher than that of the classical antiferromagnetic metal Mn around 100K. More recently, the metallic behavior down to phase transition temperature was observed by the resistivity measurements on a microcrystal of [Au(tmdt)_2], which indicate that the single-component metallic molecular magnets have been realized.
Since the Fermi surfaces of [Ni(tmdt)_2] are quite different from those of [Au(tmdt)_2], the molecular alloy system will be expected to be the single-component molecular superconductor. We have succeeded to prepare the first "single-component alloy system" [Ni_<1-x>Au_x(tmdt)_2](0<x<1). The resistivity of single crystal of [Ni_<0.75>Au_<0.25>(tmdt)_2] was abruptly deceasing below 2K, and the magnetic susceptibility was also slightly decreasing at the temperature range form 1.8 to 0.8K, which maybe stem from the partially appeared superconducting state. We think the "single-component molecular superconductor" may be realized in such an alloy system. Less

Report

(5 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (70 results)

All 2006 2005 2004 2003 2002 Other

All Journal Article (58 results) Publications (12 results)

  • [Journal Article] Superconductivity and Bortex Phases in the Two-dimensional Organic conductor -(BETS)_2Fe_xGa_1-xCl_4 (x=0.45)2006

    • Author(s)
      S.Uji et al.
    • Journal Title

      Phys. Rev. B 71

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ab Initio Electronic Structure Calculation for Single-Component Molecular Conductor Au(tmdt)_2 (tmdt = trimethylenetetrathiafulvalenedithiolate)2005

    • Author(s)
      S.Ishibashi et al.
    • Journal Title

      J. Phys. Soc. Joa., 74

      Pages: 843-846

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Crystal Structures and Physical Prooerties of Single-component Molecular Conductors consisting of Nickel and Gold Complexes with Bis(trifluoromethyl) tetrathiafulvalenedithiolate Ligands2005

    • Author(s)
      M.Sasa et al.
    • Journal Title

      J. Mater. Chem. 15

      Pages: 155-163

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of Metallic Crystals Composed of Single-component Molecules2005

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J. Mater. Chem. 15

      Pages: 3449-3451

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Single-Component Molecular Conductor [Zn(tmdt)_2] and Related Zn complexes2005

    • Author(s)
      K.Yamamoto et al.
    • Journal Title

      Chem. Lett. 34

      Pages: 1090-1091

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Molecular Conductors Based on prei-Ditellurium Bridged Donors. 2,3-DMTTeA and TMTTeN2005

    • Author(s)
      E.fujiwara et al.
    • Journal Title

      Eur. J. Inorg. Chem. 2005

      Pages: 3435-3449

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ab Initio Electronic Structure Calculation for Single-Component Molecular Conductor Au(tmdt)_2 (tmdt=trimethylenetetrathiafulvalenedithiolate)2005

    • Author(s)
      S.Ishibashi et al.
    • Journal Title

      J.Phys.Soc.Jpn. 74

      Pages: 843-846

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Crystal Structures and Physical Properties of Single-component Molecular Conductors Consisting of Nickel and Gold Complexes with Bis (trifluoromethyl) tetrathiafulvalenedithiolate Ligands2005

    • Author(s)
      M.Sasa et al.
    • Journal Title

      J.Mater.Chem. 15

      Pages: 155-163

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Development of Metallic Crystals Composed of Single- Component Molecules2005

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Mater.Chem. 15

      Pages: 3449-3451

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Single-Component Molecular Conductor [Zn(tmdt)_2] and Related Zn Complexes2005

    • Author(s)
      K.Yamamoto et al.
    • Journal Title

      Chem.Lett. 34

      Pages: 1090-1091

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Molecular Conductors Based on prei-Ditellurium Bridged Donors, 2,3-DMTTeA and TMTTeN2005

    • Author(s)
      E.Fujiwara et al.
    • Journal Title

      Eur.J.Inorg.Chem. 2005

      Pages: 3435-3449

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Superconductivity and Vortex Phases in the Two-dimensional Organic Conductor ?-(BETS)_2Fe_xGa_<1-x>Cl_4 (x=0.45)2005

    • Author(s)
      S.Uji et al.
    • Journal Title

      Phys.Rev. B 71

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ab Initio Electrionic Structure Calculation for Single-Component Molecular Conductor Au(tmdt)_2 (tmdt = trimethylenetetrathiafiulvalenedithiolate)2005

    • Author(s)
      S.Ishibash et al.
    • Journal Title

      J.Phys.Soc.Jpn., 74

      Pages: 843-846

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Crystal Structures and Physical Properties of Single-component Molecular Conductors Consisting of Nickel and Gold Complexes with Bis(trifluoromethyl)telrathiafulvalenedithiolate Ligands2005

    • Author(s)
      M.Sasa et al.
    • Journal Title

      J.Mater.Chem. 15

      Pages: 155-163

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Development of Metallic Crystals Composed of Single-Component Molecules2005

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Mater.Chem. 15

      Pages: 3449-3451

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Superconductivity and Vortex Phases in the Two-dimensional Organic Conductor λ-(BETS)_2 Fe_xGa_<1-x>Cl_4 (x=0.45)2005

    • Author(s)
      S.Uji et al.
    • Journal Title

      Phys.Rev.B 71

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structures and Magnetic Properties of First-Row Transition Metal Complexes with Bridging Ligands, Squarate or Pyrazine.2005

    • Author(s)
      Jimbo-Kobayashi et al.
    • Journal Title

      Bull.Chem.Soc.Jpn. 78

      Pages: 445-450

    • NAID

      10015431964

    • Related Report
      2005 Annual Research Report
  • [Journal Article] New BETS salt with the square planar [Ni(CN)_4]^<2-> anion.2005

    • Author(s)
      A.D.Dubrovskii AD et al.
    • Journal Title

      Synth.Met. 148

      Pages: 213-218

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dielectric Properties of Porous Molecular Crystals That Contain Polar Molecules.2005

    • Author(s)
      H.-B.Cui et al.
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 6508-6512

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Molecule-based Weak Ferromagnet with Unique Magnetic Multiphases.2005

    • Author(s)
      T.Kusamoto et al.
    • Journal Title

      Chem.Lett. 34

      Pages: 858-859

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Magnetic-field-induced Superconductivity and Phase diagrams of λ-(BETS)_2FeCl_<4-x>Br_x.2005

    • Author(s)
      S.Uji et al.
    • Journal Title

      Phys.Rev.B. 72

      Pages: 184505-184505

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Observation of Spin-flop Transition in Antiferromagnetic Organic Molecular Conductors Using AFM Micro-cantilever.2005

    • Author(s)
      M.Tokumoto et al.
    • Journal Title

      Polyhedron 24

      Pages: 2793-2785

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structures and Physical Properties of New β"-BEDT-TTF Tris-Oxalatometallate (III) Salts Containing Chlorobenzene and Halomethane Guest Molecules.2005

    • Author(s)
      A.Akutsu-Sato et al.
    • Journal Title

      Synth.Met. 152

      Pages: 373-376

    • Related Report
      2005 Annual Research Report
  • [Journal Article] EMR Measurements of Field-Induced Superconductor λ-(BETS)_2Fe_xGa_<1-x>Cl_42005

    • Author(s)
      Y.Oshima et al.
    • Journal Title

      Synth.Met. 153

      Pages: 365-368

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Infrared Electronic Absorption in a Single-Component Molecular Metal.2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 426-427

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Syntheses, Structures, and Physical Properties on Nickel Bis(dithiolen) Complexes Containing Tetrathiafulvalene (TTF) Units2004

    • Author(s)
      E.fujiwara et al.
    • Journal Title

      Inorg. Chem. 43

      Pages: 1122-1129

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Progress in Development of Single-Component Molecular Metals2004

    • Author(s)
      a.Kobayashi et al.
    • Journal Title

      J. Phys. IV France 114

      Pages: 419-424

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Obserbation of Three-dimensional Fermi Surfaces in a Single-component Molecular Metal, [Ni(tmdt)_2]2004

    • Author(s)
      H.Tanaka et al.
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 10518-10519

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Single-component Molecular Metals with Extended-TTF dithiolate Ligands2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      Chem. Rev. 104

      Pages: 5243-5264

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Organic Metals and Superconductors Based on BETS (BETS-bis(ethylenedithio9tetraselenafulvalene)2004

    • Author(s)
      H.Kobayashi et al.
    • Journal Title

      Chem. Rev. 104

      Pages: 5265-5288

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Infrared Electronic Absorption in a Single-Component Molecular Metal.2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 426-427

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Syntheses, Structures, and Physical Properties of Nickel Bis (dithiolene) Complexes Containing Tetrathiafulvalene (TTF) Units2004

    • Author(s)
      E.Fujiwara et al.
    • Journal Title

      Inorg.Chem. 43

      Pages: 1122-1129

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Progress in Development of Single-Component Molecular Metals2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Phys. IV France 114

      Pages: 419-424

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Observation of Three-dimensional Fermi Surfaces in a Single-component Molecular Metal, [Ni(tmdt)_2]2004

    • Author(s)
      H.Tanaka et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 10518-10519

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Single-component Molecular Metals with Extended-TTF Dithiolate Ligands2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      Chem.Rev. 104

      Pages: 5243-5264

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Organic Metals and Superconductors Based on BETS (BETS=bis (ethylenedithio) tetraselenafulvalene)2004

    • Author(s)
      H.Kobayashi et al.
    • Journal Title

      Chem.Rev. 104

      Pages: 5265-5288

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Infrared Electronic Absorption in a Single-Component Molecular Metal2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 426-427

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Syntheses, Structures, and Physical Properties of Nickel Bis(dithiolene) complexes Containing Tetrathiafulvalene (TTF) Units2004

    • Author(s)
      E.Fujiwara et al.
    • Journal Title

      Inorg.Chem. 43

      Pages: 1122-1129

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Recent Progress in Development of Single-Component Molecular Metals2004

    • Author(s)
      A.Kobayashi et al.
    • Journal Title

      J.Phys.IV France 114

      Pages: 419-424

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Organic Metals and Superconductors Based on BETS(BETS=bis(ethylenedithio)tetraselenafulvalene)2004

    • Author(s)
      H.Kobayashi et al.
    • Journal Title

      Chem.Rev. 104

      Pages: 5265-5288

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Highly Conducting Crystals Based on Single-Component Gold Complexes with Extended-TTF Dithiolate Ligands2003

    • Author(s)
      W.Suzuki et al.
    • Journal Title

      J. Am. Chem. Soc. 125

      Pages: 1486-1487

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Novel TTP Donor Containing a PROXYL Radical for Magnetic Molecular Conductors2003

    • Author(s)
      H.Fujiwara er al.
    • Journal Title

      Chem. Lett. 32

      Pages: 482-483

    • NAID

      10012816545

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Structural, electrical, and magnetic properties of a series of molecular conductors based on BDT-TTP and Lanthanoid nitrate complex anions (BDT-TTP = 2,5-bis (1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene)2003

    • Author(s)
      H.Cui et al.
    • Journal Title

      Inorg. Chem. 42

      Pages: 6114-6122

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Structures of a Single-component Palladium Complex with Extended TTF-type Dithiolate Ligands, Bis8tetrathiafulvalenedithiolat)palladium Determined by Powder X-ray Diffraction2003

    • Author(s)
      W.Suzuki et al.
    • Journal Title

      Chem. Lett. 32

      Pages: 1106-1107

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Highly Conducting Crystals Based on Single-Component Gold Complexes with Extended-TTF Dithiolate Ligands2003

    • Author(s)
      W.Suzuki et al.
    • Journal Title

      J.Am.Chem.Soc. 125

      Pages: 1486-1487

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Novel TTP Donor Containing a PROXYL Radical for Magnetic Molecular Conductors2003

    • Author(s)
      H.Fujiwara et al.
    • Journal Title

      Chem.Lett. 32

      Pages: 482-483

    • NAID

      10012816545

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Structural, electrical, and magnetic properties of a series of molecular conductors based on BDT-TTP and lanthanoid nitrate complex anions (BDT-TTP=2,5-bis (1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene)2003

    • Author(s)
      H.Cui et al.
    • Journal Title

      Inorg.Chem. 42

      Pages: 6114-6122

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Structures of a Single-component Palladium Complex with Extended TTF-type Dithiolate Ligands, Bis (tetrathiafulvalenedithiolato) palladium Determined by Powder X-ray Diffraction2003

    • Author(s)
      W.Suzuki et al.
    • Journal Title

      Chem.Lett. 32

      Pages: 1106-1107

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual-Action Molecular Supercondutors with Magnetic Anions2002

    • Author(s)
      B.Zhang et al.
    • Journal Title

      J. Am. Chem. Soc. 124

      Pages: 9982-9983

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A conducting crystal based on a single-component paramagnetic molecule, [Cu(dmdt)_2] (dmdt = dimethyltetrathiafulualenedithiolate)2002

    • Author(s)
      T.Tanaka et al.
    • Journal Title

      J. Am. Chem. Soc. 124

      Pages: 10002-10003

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Syntheses, structures and physical properties of palladium complexes with an extended-TTF dithiolate ligand, bis (di-n-propylthiotetrathiafulvalenedithiolato) palladate2002

    • Author(s)
      W, Suzuki et al.
    • Journal Title

      Chem. Lett.

      Pages: 936-937

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetic molecular conductors based on BETS molecules and divalent magnetic anions [BETS = bis(ethylenedithio) tetraselenafulvalene]2002

    • Author(s)
      E.Fujiwara et al.
    • Journal Title

      Inorg. Chem. 41

      Pages: 3230-3238

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetism of metallic molecular crystals with rate-earth complex anions bis(di-n-propylthiotetrathiafulvalenedithiolato) palladate2002

    • Author(s)
      T.Otsuka et al.
    • Journal Title

      J. Solid State Chem. 168

      Pages: 444-449

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dual-Action Molecular Superconductors with Magnetic Anions2002

    • Author(s)
      B.Zhang et al.
    • Journal Title

      J.Am.Chem.Soc. 124

      Pages: 9982-9983

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A conducting crystal based on a single-component paramagnetic molecule, [Cu(dmdt)_2] (dmdt=dimethyltetrathiafulvalenedithiolate)2002

    • Author(s)
      T.Tanaka et al.
    • Journal Title

      J.Am.Chem.Soc. 124

      Pages: 10002-10003

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Syntheses, structures and physical properties of palladium complexes with an extended-TTF dithiolate ligand, bis (di-n-propylthiotetrathiafulvalenedithiolato) palladate2002

    • Author(s)
      W.Suzuki et al.
    • Journal Title

      Chem.Lett. 31

      Pages: 936-937

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetic molecular conductors based on BETS molecules and divalent magnetic anions [BETS=bis (ethylenedithio) tetraselenafulvalene]2002

    • Author(s)
      E.Fujiwara et al.
    • Journal Title

      Inorg.Chem. 41

      Pages: 3230-3238

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetism of metallic molecular crystals with rare-earth complex anions bis(di-n-propylthiotetrathiafulvalenedithiolato)palladate2002

    • Author(s)
      T.Otsuka et al.
    • Journal Title

      J. Solid State Chem. 168

      Pages: 444-449

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] W.Suzuki et al.: "Highly Conducting Crystals Based on Single-Component Gold Complexes with Extended-TTF Dithiolate Ligands"J.Am.Chem.Soc.. 125. 1486-1487 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Fujiwara et al.: "A Novel TTP Donor Containing a PROXYL Radical for Magnetic Molecular Conductors"Chem.Lett.. 32. 482-483 (2003)

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      2003 Annual Research Report
  • [Publications] H.Cui et al.: "Structural, electrical, and magnetic properties of a series of molecular conductors based on BDT-TTP and lanthanoid nitrate complex anions (BDT-TTP = 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene)"Inorg.Chem.. 42. 6114-6122 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] W.Suzuki et al.: "Structures of a Single-component Palladium Complex with Extended TTF-type Dithiolate Ligands, Bis(tetrathiafulvalenedithiolato)palladium Determined by Powder X-ray Diffraction"Chem.Lett.. 32. 1106-1107 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Kobayashi et al.: "Infrared Electronic Absorption in a Single-Component Molecular Metal"J.Am.Chem.Soc.. 126. 426-427 (2004)

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      2003 Annual Research Report
  • [Publications] E.Fujiwara et al.: "Syntheses, Structures, and Physical Properties of Nickel Bis (dithiolene) Complexes Containing Tetrathiafulvalene (TTF) Units"Inorg.Chem.. 43. 1122-1129 (2004)

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      2003 Annual Research Report
  • [Publications] B.Zhang et al.: "Dual-Action Molecular Superconductors with Magnetic Anions"J.Am.Chem.Soc.. 124. 9982-9983 (2002)

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      2002 Annual Research Report
  • [Publications] T.Tanaka et al.: "A Conducting Crystal Based on A Single-Component Paramagnetic Molecule. [Cu(dmdt)_2](dmdt=Dimethvltetrathiafulvalenedithiolate)"J.Am.Chem.Soc.. 124. 10002-10003 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] W.Suzuki et al.: "Syntheses, Structures and Physical Properties of Palladium Complexes with an Extended-TTF Dithiolate Ligand, Bis(di-n-propylthiotetrathiafulvalenedithiolato)palladate"Chem.Lett.. 936-937 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] E.Fujiwara et al.: "Magnetic Molecular Conductors Based on BETS Molecules and Divalent Magnetic Anions [BETS=Bis(ethylenedithio)tetraselenafulvalene]"Inorg.Chem.. 41. 3230-3238 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Otsuka et al.: "Magnetism of Metallic Molecular Clystals with Rare-Earth Complex Anions"J.Solid State Chem. 168. 444-449 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] W.Suzuki et al.: "Highly Conducting Crystals Based on Single-Component Gold Complexes with Extended-TTF Dithiolate Ligands"J.Am.Chem.Soc. (in press). (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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