• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Structure control in atomic scale of relaxors with morphotropic phase boundary composition

Research Project

Project/Area Number 14204031
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionWaseda University

Principal Investigator

UESU Yoshiaki  Waseda Unversity, Faculty of Science & Engineering, Prof, 理工学術院, 教授 (10063744)

Project Period (FY) 2002 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥49,660,000 (Direct Cost: ¥38,200,000、Indirect Cost: ¥11,460,000)
Fiscal Year 2005: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2004: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2003: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2002: ¥40,430,000 (Direct Cost: ¥31,100,000、Indirect Cost: ¥9,330,000)
KeywordsRelaxor / Perovskite oxide / Pulse-laser deposition method / Thin films / Morphotropic phase boundary / Dielectric constant / Electric-field-induced resistant switching / 強誘電体薄膜 / レーザーデポジション成膜装置 / 圧電性 / 誘電率 / 量子常誘電体 / 強誘奄体薄膜
Research Abstract

(1)Syntheses of super lattice thin films of Pb(Sc1/2Nb1/2)O3/PbTiO3 and dielectric properties
Highly oriented Pb(Sc_<1/2>Nb_<1/2>)O_3 (PSN) and PbTiO_3 (PT) super-lattice thin films are synthesized on single-stepped SrTiO_3 (001) substrates by pulsed laser deposition (PLD) technique. SrRuO_3 is deposited on the substrate as a bottom electrode layer for dielectric measurements. The orientation and structure of the films are checked by X-ray diffraction (XRD) method. Clear super-lattice reflections are observed by XRD and the period of super-lattice, the correlation length and the mosaicity are calculated from XRD profiles of the super-lattice. Real part of the dielectric constant is about 350 at room temperature in the frequency range of 102〜105 Hz.
(2)Electric-field-induced resistance switching observed in transition-metal-oxide thin films
We show that polarity-dependent, nonvolatile resistance switching by electric field occurs in the thin film of various transition-metal oxides in almost the same manner. This result indicates that contrary to the general acceptance, perovskite manganite is by no means a special compound for this phenomenon. It is also suggested that the resistance switching is not dominated by a detailed electronic structure of each sample, but dominated by a more general origin, e.g., crystalline defect.

Report

(5 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (41 results)

All 2006 2005 2004 Other

All Journal Article (22 results) Book (2 results) Publications (17 results)

  • [Journal Article] Observation of Rotation of Polarization in Thin Films of Pb(Scl/2Nb1/2)03-PbTiO3 via a Monoclinic Phase2006

    • Author(s)
      R.Haumont, C.Malibert, B.Dkhil, J.M.Kiat, F.Lemarreci, S.Asanuma, Y.Uesu
    • Journal Title

      Tap. J. Appl. Phys. 45(1)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electric-field-induced resistance switching universally observed in transition-metal-oxide thin films2006

    • Author(s)
      M.Hamaguchi, K.Aoyama, S.Asanuma, Y.Uesu, T.Katsufuji
    • Journal Title

      Appl.Phys.Lett. 88(14)

      Pages: 142508-142508

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Is K_<(1-X)>Li_XTaO_3 a Real Relaxor?2006

    • Author(s)
      Y.Uesu, H.Yokota, J.M..Kiat, C.Malibert
    • Journal Title

      Ferroelectrics (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Observation of Rotation of Polarization in Thin Films of Pb(Sc1/2Nb1/2)O3-PbTiO3 via a Monoclinic Phase2006

    • Author(s)
      R.Haumont, C.Malibert, B.Dkhil, J.M.Kiat, F.Lemarreci, S.Asanuma, Y.Uesu
    • Journal Title

      Jap.J.Appl.Phys. 45(1)

    • NAID

      210000061882

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Is K_<(1-x)>Li_xTaO_3 a Real Relaxor2006

    • Author(s)
      Y.Uesu, H.Yokota, J.M.Kiat, C.Malibert
    • Journal Title

      Ferroelectrics (印刷中)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Structural and Dielectric Characterizations of Pb(Sc_<1/2>Nb_<1/2>)O_3-PbTiO_3 Superlattice Thin Films2006

    • Author(s)
      S.Asanuma, Y.Uesu, J.M.Kiat, C.Malibert
    • Journal Title

      Ferroelectrics (印刷中)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Observation of Rotation of Polarization in Thin Films of Pb(Sc1/2Nb1/2)O3-PbTiO3 via a Monoclinic Phase2006

    • Author(s)
      R.Haumant, C.Malibert, J.M.Kiat, S.Asanuma, Y.Uesu et al.
    • Journal Title

      Japanese Journal of Applied Physics 45, No.1

    • NAID

      210000061882

    • Related Report
      2005 Annual Research Report
  • [Journal Article] SHG microscopic observations of polar state in Li-doped KTaO_3 under electric field2005

    • Author(s)
      H.Yokota, T.Oyama, Y.Uesu
    • Journal Title

      Phys. Rev. B72 (B72)

      Pages: 144103-144103

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] リラクサーの謎-不均一構造をもつ誘電体の巨大応答-2005

    • Author(s)
      上江洲由晃
    • Journal Title

      パリティ(丸善) 20

      Pages: 18-24

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] SHG microscopic observations of polar state in Li-doped KTaO3 under electric field2005

    • Author(s)
      H.Yokota, T.Oyama, Y.Uesu
    • Journal Title

      Phys.Rev. B72

      Pages: 144103-144103

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Apparent Colossal Dielectric Relaxation in SrTiO_3 at High Temperature2005

    • Author(s)
      M.Fukunaga, Y.Uesu, W.Kobayashi, I.Terasaki
    • Journal Title

      Jpn.J.Appl.Phys. No.9

      Pages: 44-44

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] SHG microscopic observations of polar state in Li-doped KTaO3 under electric field2005

    • Author(s)
      H.Yokota, T.Oyama, Y.Uesu
    • Journal Title

      Physical Review B B72

      Pages: 144103-144103

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Determination of a merocianin J-aggregate structure and the significant contribution of the electric dipole interaction to the exiton band wavelength2005

    • Author(s)
      N.Kato, K.Yuasa, Y.Uesu et al.
    • Journal Title

      Physical Review Letters 94

      Pages: 136404-136404

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Apparent Colossal Dielectric Relaxation in SrTiO3 at High Temperature2005

    • Author(s)
      M.Fukunaga, Y.Uesu, W.Kobayashi, I.Terasaki
    • Journal Title

      Japanese Journal of Applied Physics 44, No.9B

      Pages: 7141-7143

    • NAID

      130004534723

    • Related Report
      2005 Annual Research Report
  • [Journal Article] リラクサーの謎-不均一構造をもつ誘電体の巨大応答-2005

    • Author(s)
      上江洲由晃
    • Journal Title

      パリティ (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Polar order in quantum paraelectric SrTi16O3 and SrTi16O3 at low temperature2004

    • Author(s)
      Y.Uesu, R.Nakai, C.Menoret, J-M.Kiat, M.Itoh, T.Kyomen
    • Journal Title

      J.Phys.Soc.Jpn.(Letters) 73,No.5

      Pages: 1139-1142

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Fablications of Pb(Sc1/2Nb1/2)3/PbTiO3 thin films and their structural characterizations2004

    • Author(s)
      S.Asanuma, M.Fukunaga, Y.Uesu, R.Haumont.et al.
    • Journal Title

      Jpn.J.Appl.Phys. 43,No.9B

      Pages: 6581-6584

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Electric-pulse-induced reflectance change in the thin film of perovskite manganite2004

    • Author(s)
      K.Aoyama, K.Waku, A.Asanuma, Y.Uesu, T.Katsufuji
    • Journal Title

      Appl.Phys.Lett. 85,No.7

      Pages: 1208-1210

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Backward-wave four wave mixing and coherent oscillation in CdF2:Ga,Y2004

    • Author(s)
      Y.Uesu, K.Yasukawa, N.Saito, S.Odoulov et al.
    • Journal Title

      Appl.Phys. B78

      Pages: 601-605

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 3D Images of inverted domain structure in LiNbO3 using SHG interference microscope2004

    • Author(s)
      Y.Uesu, H.Shibata, Y.Suzuki, S.Shimada
    • Journal Title

      Ferroelectrics 304

      Pages: 99-103

    • Related Report
      2004 Annual Research Report
  • [Journal Article] The structural and electric properties of the perovskite system BaTiO3-Ba(Fe1/2Ta1/2)O-32004

    • Author(s)
      GB.Li, SX.Liu, FH.Liao, Y.Uesu et al.
    • Journal Title

      J.Solid State.Chemistry 177,No.4-5

      Pages: 1695-1703

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural and Dielectric Characterizations of Pb(Sc_<1/2>Nb_<l/2>)O_3-PbTiO_3 Superlattice Thin Films

    • Author(s)
      S.Asanuma, Y.Uesu, J.M.Kiat, C.Malibert
    • Journal Title

      Ferroelectrics (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 分極反転デバイスの基礎と応用2005

    • Author(s)
      上江洲由晃(共著)
    • Total Pages
      383
    • Publisher
      オプトロニクス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] 分極反転デバイス、材料「第1章 強誘電体の分極の概念」「第5章 第2高調波顕微鏡」2005

    • Author(s)
      上江洲 由晃
    • Total Pages
      150
    • Publisher
      オプトエレクトロニクス(社)
    • Related Report
      2004 Annual Research Report
  • [Publications] 上江洲由晃: "特集 J-PARCへの夢-J-PARCが拓くサイエンス・テクノロジー、本質的不均一構造をもつ誘電体のダイナミクス"日本中性子科学会誌. 14, no1. 15-16 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Uesu, K.Yasukawa, N.Saito, S.Odoulov, K.Shcherbin, A.Ryskin: "Backward-wave four-wave mixing and coherent oscillation in CdF2:Ga,Y"Appl.Phys.B. (印刷中). 1-5 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Guobao Li, Yoshiaki Uesu et al.: "The structural and electric properties of the perovskite system BaTiO3-Ba(Fe1/2Ta1/2)O3"J.Phys.Chem.Solids. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Yoshiaki UESU et al.: "Polar Order in Quantum Paraelectric SrTi16O3 and SrTi18O3 at Low Temperatur"J.Phys.Soc.Japan (Letters). (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Uesu.K.Ishikawa, Y.Yamada: "Colossal response induced by hetero-structure fluctuation"Trans.Mat.Res.Soc.Jpn.. 28. 91-96 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Fukushima, Guobao Li, Y.Uesu, K.Kohn: "Structure and dielectric properties of Ba(1-x)La(x)Ti (1-x)Cr(x)O3"Ferroelectrics. 286. 801-806 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Uesu et al.: "SHG microscopic studies on low temperature phase transitions of SrTiO3(16) and SrTiO3(18)"Ferroelectrics. 285. 393-400 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kato, I.Hirosawa, M.Sato, N.Ikeda, Y.Uesu: "Study of 2D phase transition of polar organic dye molecules at the air-water interphase by using grazing-incidence x-ray diffraction"Ferroelectrics. 286. 921-926 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Fukunaga, Y.Uesu: "Compact and simple apparatus for measuring direct piezoelectricity"Jpn.J.Appl.Phys.. 42. 6115-6117 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Uesu, K.Yasukawa, N.Saito, S.Itoh, S.Odoulov, K.Shcherbin, A.Ryskin: "Dynamic grating in semiconductor CdF2:Ga:Y"J.Opt.Soc.Am.. B20. 1905-1911 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 上江洲由晃: "複合ペロブスカイト酸化物の巨大圧電効果"日本物理学会誌. 57巻9号. 646-653 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Uesu et al.: "Symmetry of high-piezoelectric Pb based complex perovskites at the morphotoropic phase boundary I"J.Phys.Soc.Japan. 71,No.3. 960-965 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Yamada, Y.Uesu et al.: "Symmetry of high-piezoelectric Pb based complex perovskites at the morphotoropic phase boundary II"J.Phys.Soc.Japan. 71,No.3. 966-970 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.M, Kiat, Y.Uesu et al.: "Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds"Phys.Rev.B. 65. 641061-641064 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Li GB, Uesu Y, Kohn K: "Structural characterization of the complex perovskites Ba1-xLaxTi1-xCrx03"J.Solid State Chem.. 164(1). 98-105 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] GB.Li GB, XJ.Kuang XJ, SJ.Tian, Y.Uesu, K.Kohn: "Structure and conductivity of perovskites Sr1-xLaxTi1-xCrx03"J.Solid State Chem.. 165. 381-192 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Fukunaga, GB Li, Y.Uesu, K.Kohn: "Structural and dielectric properties of Ni-doped and La-Cr-doped BaTi03"Jpn.J.Appl.Phys.. 41. 6926-6928 (2002)

    • Related Report
      2002 Annual Research Report

URL: 

Published: 2002-04-01   Modified: 2020-05-15  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi