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Creation of Multifunctional Photochromic Metal Complexes

Research Project

Project/Area Number 14204066
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

NISHIHARA Hiroshi  The University of Tokyo, School of Science, Department of Chemistry, Professor, 大学院・理学系研究科, 教授 (70156090)

Co-Investigator(Kenkyū-buntansha) MURATA Masaki  The University of Tokyo, School of Science, Department of Chemistry, Assistant Professor, 大学院・理学系研究科, 助手 (70345263)
YONEZAWA Tetsu  The University of Tokyo, School of Science, Department of Chemistry, Associate Professor, 大学院・理学系研究科, 助教授 (90284538)
栗原 正人  山形大学, 理学部, 助教授 (50292826)
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥55,510,000 (Direct Cost: ¥42,700,000、Indirect Cost: ¥12,810,000)
Fiscal Year 2004: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2003: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2002: ¥27,950,000 (Direct Cost: ¥21,500,000、Indirect Cost: ¥6,450,000)
Keywordsphotochromizm / Multiple functions / transition metal complexes / bipyridine / ditiolato complex / photoelectronic conversion / optical sense / protonation / ジチオラト錯体 / カテコラト錯体 / アゾ / 錯体 / 光異性化 / レドックス
Research Abstract

This project aims at the creation of new photochromic metal complexes, the investigation of their unique multiple functionalities, and the fabrication of novel types of molecular switches and memories by organizing them at the electrode surfaces. Summary of the results obtained is as follows, 1)Azobenzene-bound tris(bipyridine)cobalt complexes and ferrocenylazobenzenes underwent novel reversible trans-cis isomerization of azobenzene moieties using the combination of photoirradiation with a single light source and redox reaction of a metal complex moiety. 2)Photoluminescence properties of azobenzene-bound terpyridine platinum complexes were turned on and off by the reversible trans-cis isomerization of the azobenzene moiety. 3)A mixture of an azobenzene-attached bipyridine ligand, dmpAB, unsubstituted bipyridine, and Cu ions underwent reversible ligand exchange reactions by redox reaction of Cu(II)/Cu(I), and consequently, trans-cis isomerization of azobenzene moieties using the combina … More tion of photoirradiation with a single light source was achieved. 4)Azo-conjugated dithiolato and catecolato complexes underwent proton-catalized cis-to-trans isomerization. 5)SAMs of azobenzene-bound metal terpyridine complexes and ferrocenylazobenzene derivatives were prepared and their photochemical reactions investigated. 6)A new "molecular photo-electro transducer", working in a cyclic manner totally powered with light irradiation, has been constructed. The UV/blue controlled repetitive motion of azobenzene moieties in 6,6'-bis(4"-tolylazo)-4,4'-bis(4-tert-butylphenyl)-2,2'-bipyridine causes reciprocal Cu(I) translocation between two coordination environments, resulting in pumping of the redox potential of Cu(I). Therefore, UV/blue light information can be successfully transformed into an electrode potential change and positive/negative current response, which is closely related to natural visual transduction both functionally and mechanically. 7)A new platinum complex with both an azo-bound dithiolato ligand and an azobenzene-bound bipyridine ligand exhibits testability reversibly controllable using different energy lights. Less

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (71 results)

All 2005 2004 2003 2002 Other

All Journal Article (47 results) Book (4 results) Publications (20 results)

  • [Journal Article] Reversible Photoelectronic Signal Conversion Based on Photoisomerization-Controlled Coordination Change of Azobenzene-bipyridine Ligands to Copper2005

    • Author(s)
      S.Kume, M.Murata, T.Ozeki, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 490-491

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Photo-controllable Tristability of a Dithiolato-Bipyridine-Pt(II) Complex Molecule Containing Two Azobenzene Moieties2005

    • Author(s)
      R.Sakamoto, M.Murata, S.Kume, H.Sampei, M.Sugimoto, H.Nishihara
    • Journal Title

      Chem.Commun. 2005

      Pages: 1215-1217

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface2005

    • Author(s)
      K.Kanaizuka, M.Murata, Y.Nishimori, I.Mori, K.Nishio, H.Masuda, H.Nishihara
    • Journal Title

      Chem.Lett. 34

      Pages: 534-535

    • NAID

      10015515306

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Combination of redox- and photo-chemistry of azo-conjugated metal complexes2005

    • Author(s)
      H.Nishihara
    • Journal Title

      Coord.Chem.Rev. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electron Transfer in Ferrocene-Containing π-Conjugated Polymers2005

    • Author(s)
      H.Nishihara, M.Murata
    • Journal Title

      Inorg.Organomet.Chem. 1581

      Pages: 147-156

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Reversible Photoelectronic Signal Conversion Based on Photoisomerization-Controlled Coordination Change of Azobenzene-bipyridine Ligands to Copper2005

    • Author(s)
      S.Kume, M.Murata, T.Ozeki, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc. 127(2)

      Pages: 490-491

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photo-controllable Instability of a Dithiolato-Bipyridine-Pt(II) Complex Molecule Containing Two Azobenzene Moieties2005

    • Author(s)
      R.Sakamoto, M.Murata, S.Kume, H.Sampei, M.Sugimoto, H.Nishihara
    • Journal Title

      Chem.Commun.

      Pages: 1215-1217

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface2005

    • Author(s)
      K.Kanaizukam M.Murata, Y.Nishimori, I.Mori, K.Nishio, H.Masuda, H.Nishihara
    • Journal Title

      Chem.Lett. (印刷中)

    • NAID

      10015515306

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Combination of redox-and photo-chemistry of azo-conjugated metal complexes2005

    • Author(s)
      H.Nishihara
    • Journal Title

      Coord.Chem.Rev. (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Electron Transfer in Ferrocene-Containing π-Conjugated Polymers2005

    • Author(s)
      H.Nishihara, M.Murata
    • Journal Title

      Inorg.Organomet.Chem. (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Multi-mode Molecular Switching Properties and Functions of Azo-conjugated Metal Complexes2004

    • Author(s)
      H.Nishihara
    • Journal Title

      Bull.Chem.Soc.Jpn. 77(3)(印刷中)

    • NAID

      10012725462

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Large Solvent and Potential Effects on the Collective Surface Plasmon Band of Gold Nanoparticle Films2004

    • Author(s)
      K.Yamada, H.Nishihara
    • Journal Title

      ChemPhysChem. 2004

      Pages: 555-559

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Kinzokugenso ga hiraku 21seiki no atarashii kagaku no sekai ; Sakutai kara bunshidebaisu he2004

    • Author(s)
      H.Nishihara
    • Journal Title

      Kubapro(Tokyo) 215

      Pages: 190-1989

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Shusekigatakinzokusakutai no kagaku ; Hikari ya puroton ni outousuru redokkususakutai2004

    • Author(s)
      H.Nishihara
    • Journal Title

      Kagakudojin(Kyoto) 268

      Pages: 51-57

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Protonation-Induced Intramolecular Electron Transfer in the Ferrocene-Quinone Conjugated Systems2004

    • Author(s)
      H.Nishihara
    • Journal Title

      Macromolecular Nanostructured Materials(edited by N.Ueyama and A.Harada, Kodansha(Tokyo)(Springer(New York))

      Pages: 209-223

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Large Solvent and Potential Effects on the Collective Surface Plasmon Band of Gold Nanoparticle Films2004

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Chem.Phys.Chem. 2004

      Pages: 555-559

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis of Azo-Conjugated Metalladithiolenes and Their Photo- and Proton-Responsive Isomerization Reactions2003

    • Author(s)
      M.Nihei, M.Kurihara, J.Mizutani, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc 125

      Pages: 2964-2973

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Coordination-Syncronized Trans/cis Photoisomerization of Bipyridylazobenzene Driven by a Cu(II)/Cu(I) Redox Change2003

    • Author(s)
      S.Kume, M.Kurihara, H.Nishihara
    • Journal Title

      Inorg.Chem. 42(7)

      Pages: 2194-2196

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photochemical Behavior of Azobenzene-Conjugated Co(II), Co(III), and Fe(II) Bis(terpyridine) Complexes2003

    • Author(s)
      T.Yutaka, I.Mori, M.Kurihara, N.Tamai, H.Nishihara
    • Journal Title

      Inorg.Chem. 42(20)

      Pages: 6306-6313

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis of Azo-conjugated Catecholate Complexes and their Photon- and Proton-responses2003

    • Author(s)
      S.Nagashima, M.Nihei, T.Yamada, M.Murata, M.Kurihara, H.Nishihara
    • Journal Title

      Macromol.Symp. 204

      Pages: 93-101

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrochemical Deposition of Biferrocene Derivative-Attached Gold Nanoparticles and The Morphology of the Formed Film2003

    • Author(s)
      M.Yamada, T.Tadera, K.Kubo, H.Nishihara
    • Journal Title

      J.Phys.Chem.B 107

      Pages: 3703-3711

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Novel Intramolecular Electron-transfer Equilibrium in a Spatially Interacting Binary System of a Metal-free Porphyrin and a Ruthenium Trichloro Terpyridyl2003

    • Author(s)
      K.Mizuno, M.Kurihara, S.Takagi, H.Nishihara
    • Journal Title

      Chem.Lett. 32(9)

      Pages: 788-789

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Core size effects on electrodeposition of gold nanoparticles attached with biferrocene derivatives2003

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Eur.Phys.J.D. 24

      Pages: 257-260

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrodeposition of Biferrocene Derivative-Attached Gold Nanoparticles : Solvent Effects and Lithographic Assembly2003

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Langmuir 19(19)

      Pages: 8050-8056

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrochemical Deposition of Metal Nanoparticles Functionalized with Multiple Redox Molecules2003

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Compt.Rend.Chim. 6

      Pages: 919-934

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis of Azo-Conjugated Metalladithiolenes and Their Photo-and Proton-Responsive Isomerization Reactions2003

    • Author(s)
      M.Nihei, M.Kurihara, J.Mizutani, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc. 125(10)

      Pages: 2964-2973

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photochemical Behavior of Azobenzene-Conjugated Co(II),Co(III) and Fe(II) Bis(terpyridine) Complexes2003

    • Author(s)
      T.Yutaka, I.Mori, M.Kurihara, N.Tamai, H.Nishihara
    • Journal Title

      Inorg.Chem. 42(20)

      Pages: 6306-6313

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis of Azo-conjugated Catecholate Complexes and their Photon-and Proton-responses2003

    • Author(s)
      S.Nagashima, M.Nihei, T.Yamada, M.Murata, M.Kurihara, H.Nishihara
    • Journal Title

      Macromol.Symp. 204

      Pages: 93-101

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Novel Intramolecular Electron-transfer Equilibrium in a Spatially Interacting Binary System of a Metal-free Porphyrin and a Ruthenium Trichloro Terpyridyl Complex2003

    • Author(s)
      K.Mizuno, M.Kurihara, S.Takagi, H.Nishihara
    • Journal Title

      Chem.Lett. 32(9)

      Pages: 788-789

    • NAID

      10012818942

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Core size effects on electrodeposition of gold nanoparticles attached with biferrocene derivative2003

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Eur.Phys.J.D 24

      Pages: 257-260

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Azo- and quinone-conjugated redox complexes - photo- and proton-coupled intramolecular reactions based on d-π interaction2002

    • Author(s)
      M.Kurihara, H.Nishihara
    • Journal Title

      Coord.Chem.Rev. 226

      Pages: 125-135

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photo- and Protonation-Induced Changes in Structures and Physical Properties of Azo-Conjugated Metal Complex Systems2002

    • Author(s)
      H.Nishihara, M.Nihei, A.Hirooka, M.Kurihara
    • Journal Title

      Macromol.Symp. 186

      Pages: 93-98

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Redox-conjugated Reversible Isomerization of Ferrocenylazobenzene with a Single Green Light2002

    • Author(s)
      M.Kurihara, A.Hirooka, S.Kume, M.Sugimoto, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc. 124

      Pages: 8800-8801

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] A Large Trans/cis Conversion Ratio in Redox-conjugated Single-light Reversible Isomerization of a Cobalt Complex with meta-Bipyridylazobenzene Ligands2002

    • Author(s)
      S.Kume, M.Kurihara, H.Nishihara
    • Journal Title

      J.Korean Electrochem.Soc. 5

      Pages: 189-191

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine Complexes by Trans-Cis Photoisomerization2002

    • Author(s)
      T.Yutaka, I.Mori, M.Kurihara, J.Mizutani, N.Tamai, T.Kawai, M.Irie, H.Nishihara
    • Journal Title

      Inorg.Chem. 41

      Pages: 7143-7150

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] フォトクロミック金属錯体2002

    • Author(s)
      西原 寛, 村田昌樹
    • Journal Title

      触媒 44(5)

      Pages: 328-333

    • NAID

      10009489641

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Redox Chemistry and Functionalities of Conjugated Ferrocene Systems2002

    • Author(s)
      H.Nishihara
    • Journal Title

      Adv.Inorg.Chem 53

      Pages: 41-86

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Electrochemical construction of an alternating multi-layered structure of palladium and gold nanoparticles attached with biferrocene moieties2002

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Chem.Commun.

      Pages: 2578-2579

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Azo-and quinone-conjugated redox complexes-photo-and proton-coupled intramolecular reactions based on d-π interaction2002

    • Author(s)
      M Kurihara, H.Nishihara
    • Journal Title

      Coord.Chem.Rev. 226

      Pages: 125-135

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photo-and Protonation-Induced Changes in Structures and Physical Properties of Azo-Conjugated Metal Complex Systems2002

    • Author(s)
      H.Nishihara, M.Nihei, A.Hirooka, M.Kurihara
    • Journal Title

      Macromol.Symp 186

      Pages: 93-98

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Redox-conjugated Reversible Isomerization of Ferrocenylazobenzene with a Single Green Light2002

    • Author(s)
      M.Kurihara, A.Hirooka, S.Kume, M.Sugimoto, H.Nishihara
    • Journal Title

      J.Am.Chem.Soc. 124(30)

      Pages: 8800-8801

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] A Large Trans/cis Conversion Ratio in Redox-conjugated Single-light Reversible Isomerizati on of a Cobalt Complex with meta-Bipyridylazobenzene Ligands2002

    • Author(s)
      S.Kume, M.Kurihara, H.Nishihara
    • Journal Title

      J.Korean Electrochem.Soc. 5(4)

      Pages: 189-191

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine Complexes by Trans-Cis Photoisomerization2002

    • Author(s)
      T.Yutaka, I.Mori, M.Kurihara, J.Mizutani, N.Tamai, T.Kawai, M.Irie, H.Nishihara
    • Journal Title

      Inorg.Chem. 41(26)

      Pages: 7143-7150

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photochromic Metal Complexes2002

    • Author(s)
      H.Nishihara, M.Murata
    • Journal Title

      Shokubai 44(5)

      Pages: 328-333

    • NAID

      10009489641

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Redox Chemistry and Functionalities of Conjugated Ferrocene Systems2002

    • Author(s)
      H.Nishihara
    • Journal Title

      Adv.Inorg.Chem. 53

      Pages: 41-86

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Combination of redox-and photo-chemistry of azo-conjugated metal complexes

    • Author(s)
      H.Nishihara
    • Journal Title

      Coord.Chem.Rev. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Large Solvent and Potential Effects on the Collective Surface Plasmon Band of Gold Nanoparticle Films

    • Author(s)
      M.Yamada, H.Nishihara
    • Journal Title

      Chem Phys Chem. 2004(4)

      Pages: 555-559

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] 金属元素が拓く21世紀の新しい化学の世界(錯体から分子デバイスへ)2004

    • Author(s)
      西原 寛
    • Publisher
      クバプロ
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] 集積型金属錯体の科学(光やプロトンに応答するレドックス錯体)2004

    • Author(s)
      西原 寛
    • Publisher
      化学同人
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] Protonation-Induced Intramolecular Electron Transfer in the Ferrocene-Quinone Conjugated Systems," H.Nishihara, in Macromolecular Nanostructured Materials, in Macromolecular Nanostructured Materials2004

    • Author(s)
      H.Nishihara
    • Publisher
      Kodansha (Tokyo), Springer (New York)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] "Protonation-Induced Intramolecular Electron Transfer in the Ferrocene-Quinone Conjugated Systems," H.Nishihara, in Macromolecular Nanostructured Materials、in Macromolecular Nanostructured Materials2004

    • Author(s)
      H.Nishihara
    • Publisher
      Kodansha (Tokyo), Springer (New York)
    • Related Report
      2004 Annual Research Report
  • [Publications] S.Kume, M.Kurihara, H.Nishihara: "Coordination-Syncronized Trans/cis Photoisomerization of Bipyridylazobenzene Driven by a Cu(II)/Cu(I) Redox Change"Inorg.Chem.. 42(7). 2194-2196 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Yutaka, I.Mori, M.Kurihara, N.Tamai, H.Nishihara: "Photochemical Behavior of Azobenzene-Conjugated Co(II), Co(III) and Fe(II) Bis(terpyridine) Complexes"Inorg.Chem.. 42(20). 6306-6313 (2003)

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      2003 Annual Research Report
  • [Publications] S.Nagashima, M.Nihei, T.Yamada, M.Murata, M.Kurihara, H.Nishihara: "Synthesis of Azo-conjugated Catecholate Complexes and their Photon- and Proton-responses"Macromol.Symp.. 204. 93-101 (2003)

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      2003 Annual Research Report
  • [Publications] H.Nishihara: "Multi-mode Molecular Switching Properties and Functions of Azo-conjugated Metal Complexes"Bull.Chem.Soc.Jpn.. 77(3)(In press). (2004)

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      2003 Annual Research Report
  • [Publications] M.Yamada, T.Tadera, K.Kubo, H.Nishihara: "Electrochemical Deposition of Biferrocene Derivative-Attached Gold Nanoparticles and The Morphology of the Formed Film"J.Phys.Chem.B. 107. 3703-3711 (2003)

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      2003 Annual Research Report
  • [Publications] K.Mizuno, M.Kurihara, S.Takagi, H.Nishihara: "Novel Intramolecular Electron-transfer Equilibrium in a Spatially Interacting Binary System of a Metal-free Porphyrin and a Ruthenium Trichloro Terpyridyl"Chem.Lett.. 32(9). 788-789 (2003)

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      2003 Annual Research Report
  • [Publications] M.Yamada, H.Nishihara: "Core size effects on electrodeposition of gold nanoparticles attached with biferrocene derivatives"Eur.Phys.J.D.. 24. 257-260 (2003)

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      2003 Annual Research Report
  • [Publications] M.Yamada, H.Nishihara: "Electrodeposition of Biferrocene Derivative-Attached Gold Nanoparticles : Solvent Effects and Lithographic Assembly"Langmuir. 19(19). 8050-8056 (2003)

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      2003 Annual Research Report
  • [Publications] M.Yamada, H.Nishihara: "Electrochemical Deposition of Metal Nanoparticles Functionalized with Multiple Redox Molecules"Compt.Rend.Chim.. 6. 919-934 (2003)

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      2003 Annual Research Report
  • [Publications] 西原 寛: "金属元素が拓く21世紀の新しい化学の世界 (錯体から分子デバイスへ)"クバプロ. 215(190-198) (2004)

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      2003 Annual Research Report
  • [Publications] 西原 寛: "集積型金属錯体の科学 (光やプロトンに応答するレドックス錯体)"化学同人. 268(51-57) (2004)

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      2003 Annual Research Report
  • [Publications] M.Kurihara, H.Nishihara: "Azo-and quinone-conjugated redox complexes-photo-and proton-coupled intramolecular reactions based on d-π interaction"Coord.Chem.Rev.. 226. 125-135 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Nishihara, M.Nihei, A.Hirooka, M.Kurihara: "Photo-and Protonation-Induced Changes in Structures and Physical Properties of Azo-Conjugated Metal Complex Systems"Macromol.Symp.. 186. 93-98 (2002)

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      2002 Annual Research Report
  • [Publications] M.Kurihara, A.Hirooka, S.Kume, M.Sugimoto, H.Nishihara: "Redox-conjugated Reversible Isomerization of Ferrocenylazobenzene with a Single Green Ligh"J.Am.Chem.Soc.. 124. 8800-8801 (2002)

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      2002 Annual Research Report
  • [Publications] S.Kume, M.Kurihara, H.Nishihara: "A Large Trans/cis Conversion Ratio in Redox-conjugated Single-light Reversible Isomerization of a Cobalt Complex with meta-Bipyridylazobenzene Ligands"J.Korean Electrochem.Soc.. 5. 189-191 (2002)

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      2002 Annual Research Report
  • [Publications] T.Yutaka, I.Mori, M.Kurihara, J.Mizutani, N.Tamai, T.Kawai, M.: "Photoluminescence switching of Azobenzene-Conjugated Pt(II)Terpyridine Complexes by Trans-Cis Photoisomerization"Inorg.Chem.. 41. 7143-7150 (2002)

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      2002 Annual Research Report
  • [Publications] M.Nihei, M.Kurihara, J.Mizutani, H.Nishihara: "Synthesis of Azo-Conjugated Metalladithiolenes and Their Photo-and Proton-Responsive Isomerization Reactions"J.Am.Chem.Soc.. 125. 2964-2973 (2003)

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      2002 Annual Research Report
  • [Publications] S.Kume, M.Kurihara, H.Nishihara: "Coordination-Syncronized Trans/cis Photoisomerization of Bipyridylazobenzene Driven by a Cu(II)/Cu(I) Redox Change"Inorg. Chem.. 42. ASAP (2003)

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      2002 Annual Research Report
  • [Publications] 西原 寛, 村田 昌樹: "フォトクロミック金属錯体"触媒. 44(5). 328-333 (2002)

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      2002 Annual Research Report
  • [Publications] M.Yamada, H.Nishihara: "Electrochemical construction of an alternating multi-layered structure of palladium and gold nanoparticles attached with biferrocene moieties"Chem.Commun.. 2578-2579 (2002)

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      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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