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CONTROL OF CARBON NANOTUBE GROWTH USING SELF-ORGANIZED CATALYST NANOCLUSTERS AND ITS APPLICATION TO NANODEVICES

Research Project

Project/Area Number 14205010
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 表面界面物性
Research InstitutionOSAKA UNIVERSITY

Principal Investigator

OURA Kenjiro  OSAKA UNIVERSITY, GRADUATE SCHOOL OF ENGINEERING, PROFESSOR, 大学院・工学研究科, 教授 (60029288)

Co-Investigator(Kenkyū-buntansha) HIDEAKI Okado  OSAKA UNIVERSITY, RESEARCH CENTER FOR ULTRA-HIGH VOLTAGE ELECTRON MICROSCOPY, RESEARCH ASSOCIATE, 超高圧電子顕微鏡センター, 助手 (20324816)
HONDA Shin-ichi  OSAKA UNIVERSITY, GRADUATE SCHOOL OF ENGINEERINGGRADUATE SCHOOL OF ENGINEERING, RESEARCH ASSOCIATE, 大学院・工学研究科, 助手 (90324821)
KATAYAMA Mitsuhiro  OSAKA UNIVERSITY, GRADUATE SCHOOL OF ENGINEERING, ASSOCIATE PROFESSOR, 大学院・工学研究科, 助教授 (70185817)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥54,990,000 (Direct Cost: ¥42,300,000、Indirect Cost: ¥12,690,000)
Fiscal Year 2003: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2002: ¥44,850,000 (Direct Cost: ¥34,500,000、Indirect Cost: ¥10,350,000)
Keywordscarbon nanotube / carbon nanotube bridging between electrodes / thermal chemical vapor deposition / dispersing carbon nanotube / thermal annealing / electron transport properties / contact resistance / field effect transistor / CNT / 自己組織化プロセス / 触媒金属ナノクラスター / 熱CVD / 横配向 / 電極間架橋 / 固有抵抗
Research Abstract

Electrical conductance of carbon nanotubes (CNTs) was measured by a newly developed probe system. The CNTs were bridged between the electrodes by using thermal CVD with self-organized catalyst nanoclusters or dispersing commercial CNTs on the patterned electrodes. Furthermore, Ti electrodes were deposited over both ends of the CNT bridges in order to reduce the contact resistance between CNTs and electrodes. A test device of field effect transistor (FET) with a channel of CNTs was fabricated.
After annealing the CNTs bridging between the electrodes in a vacuum, the contact resistance was reduced, indicating the Ti carbide could form at the interface of the electrodes. Furthermore, Ti electrodes were deposited over both ends of the CNTs using photolithography and lift-off technique, resulting in reduction of the contact resistance. The conductance was found to be proportional to A/L as well as B/L, where A, B, and L is the cross section, circumference, and length of CNTs. This means that diffusive transport occurs in our CNTs.
We have fabricated an FET test device using CNTs. The drain current was measured with changing gate voltages. The drain current was modulated by the gate voltages. The value of transconductance per unit channel width of the FET test devices was found to be comparable to that of conventional p-type MOSFET. The performance of the FET test devices could be improved by changing the channel length or the structure of the electrodes.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (26 results)

All Other

All Publications (26 results)

  • [Publications] 尾浦憲治郎 他7名: "プラズマ化学気相成長法による電界電子エミッター用ナノ構造薄膜の作製と評価"真空. 46. 302-305 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 片山光浩 他8名: "触媒金属微粒子制御による垂直配向カーボンナノチューブ薄膜の作製"真空. 46. 542-545 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Kenjiro Oura 他6名: "Formation of Graphite Layers during Carbon Nanotubes Growth"Jpn.J.Appl.Phys.. 42. 579-581 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Mitsuhiro Katayama 他7名: "Low Temperature Synthesis of Aligned Carbon Nanotubes by Inductively Coupled Plasma Chemical Vapor Deposition Using Pure Methane"Jpn.J.Appl.Phys.. 42. L441-L443 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 尾浦憲治郎 他5名: "熱化学気相成長法によるカーボンナノチューブ-金属微粒子間架橋構造の形成"真空. 46. 497-500 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Mitsuhiro Katayama 他9名: "Large Field Emission from Carbon Nanotubes Grown on Patterned Catalyst Thin Film by Thermal Chemical Vapor Deposition"Physica B. 323. 171-173 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Kenjiro Oura 他10名: "Doping of Magic Nanoclusters in the Submonolayer In/Si(100) System"Phys.Rev.Lett.. 91. 026104-1-026104-4 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kuzuoka, K.Y.-G Baek, T.Ikuno, S.Ohkura, S.Honda, M.Katayama, T.Hirao, K.Oura: "Synthesis and Characterization of Nanostructured Thin Films for Field Emitter by Plasma Enhanced Chemical Vapor Deposition"J. Vac. Soc. Jpn. 46, No.3. 302-305 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] N.Hayashi, K.-Y.Lee, T.Ikuno, K.Tsuji, S.Ohkura, S.Honda, M.Katayama, T.Hirao, K.Oura: "Vertically Aligned Carbon Nanotube Growth Using Density-Controlled Catalyst Nanoparticles"J. Vac. Soc. Jpn.. 46, No.7. 542-545 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.-G.Baek, S.Honda, T.Ikuno, S.Ohkura, M.Katayama, T.Hirao, K.Oura: "Formation of Graphite Layers during Carbon Nanotubes Growth"Jpn. J. Appl. Phys.. 42. 579-581 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Honda, M.Katayama, K.-Y.Lee, T.Ikuno, S.Ohkura, K.Oura, H.Furuta, T.Hirao: "Low Temperature Synthesis of Aligned Carbon Nanotubes by Inductively Coupled Plasma Chemical Vapor Deposition Using Pure Methane"Jpn. J. Appl. Phys.. 42. L441-L443 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] N.Yamauchi, T.Ikuno, S.Ohkura, S.Honda, M.Katayama, K.Oura: "Carbon Nanotube Bridges between Metal Nanoparticles Synthesized by Thermal Chemical Vapor Deposition"J Vac. Soc. Jpn.. 46, No.6. 497-500 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Ikuno, T.Yamamoto, M.Kamizono, S.Takahashi, H.Furuta, S.Honda, S.Ohkura, M.Katayama, T.Hirao, K.Oura: "Large Field Emission from Carbon Nanotubes Grown on Patterned Catalyst Thin Film by Thermal Chemical Vapor Deposition"Physica B. 323. 171-172 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] V.G.Kotlyar, A.V.Zotov, A.A.Saranin, E.N.Chunkurov, T.V.Kasyanova, M.A.Cherevik, I.V.Pisarenko, H.Okado, M.Katayama, K.Oura, V.G.Lifshits: "Doping of Magic Nanoclusters in the Submonolayer In/Si(100) System"Phys. Rev. Lett.. 91. 026104-026104 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 尾浦憲治郎 他7名: "プラズマ化学気相成長法による電界電子エミッター用ナノ構造薄膜の作製と評価"真空. Vol.46, No.3. 168-171 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 片山光浩 他8名: "触媒金属微粒子制御による垂直配向カーボンナノチューブ薄膜の作製"真空. Vol.46, No.7. 4-7 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kenjiro Oura 他6名: "Formation of Graphite Layers during Carbon Nanotubes Growth"Jpn.J.Appl.Phys. 42. 579-581 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Mitsuhiro Katayama 他7名: "Low Temperature Synthesis of Aligned Carbon Nanotubes by Inductively Coupled Plasma Chemical Vapor Deposition Using Pure Methane"Jpn.J.Appl.Phys. 42. L441-L443 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 尾浦憲治郎他5名: "熱化学気相成長法によるカーボンナノチューブ-金属微粒子間架橋構造の形成"真空. Vol.46, No.6. 7-10 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Mitsuhiro Katayama 他9名: "Large field emission from carbon nanotubes grown on patterned catalyst thin film by thermal chemical vapor deposition"Physica B. 323. 171-173 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] Kenjiro Oura 他10名: "Doping of Magic Nanoclusters in the Submonolayer in/Si (100) System"Physical Review Letters. Vol.91, No.2. 026104-1-026104-4 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Oura 他5名: "Ni-based Catalytic Growth of Vertically Aligned Multi-Walled Carbon Nanotubes by Dual-RF Plasma CVD Method and their Field Emission Properties"Physica B. 323. 299-302 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Katayama 他9名: "Large Field Emission from Carbon Nanotubes Grown on Patterned Catalyst Thin Film by Thermal Chemical Vapor Deposition"Physica B. 323. 171-173 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Oura 他8名: "Method for Aligned Bamboo-like Carbon Nanotube Growth using RF Magnetron Sputtering"Jpn. J. Appl. Phys.. 42. 713-715 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Katayama 他6名: "Formation of Graphite Layers during Carbon Nanotubes Growth"Jpn. J. Appl. Phys.. 42. 579-581 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Oura 他9名: "High Aligned Carbon Nano tube Arrays Fabricated by Bias Sputtering"Appl. Surf. Sei. (印刷中). (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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