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Synthesis and Applications of Organotin Clusters with Multi-Layered Structure

Research Project

Project/Area Number 14205129
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionOKAYAMA UNIVERSITY OF SCIENCE

Principal Investigator

OTERA Junzo  Okayama University of Science, Department of Applied Chemistry, Professor, 工学部, 教授 (20131617)

Co-Investigator(Kenkyū-buntansha) ORITA Akihiro  Okayama University of Science, Department of Applied Chemistry, Associate Professor, 工学部, 助教授 (30262033)
Project Period (FY) 2002 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥54,080,000 (Direct Cost: ¥41,600,000、Indirect Cost: ¥12,480,000)
Fiscal Year 2005: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2004: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2003: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2002: ¥22,100,000 (Direct Cost: ¥17,000,000、Indirect Cost: ¥5,100,000)
KeywordsCatalyst / Organotin / Ester / Carboxylic acid / Alcohol / Fluorous biphase technology / Green Chemistry / Distannoxan
Research Abstract

Novel fluorodistannoxanes [XR^F_2SnOSnR^F_2Y]_2(R^F=C_6F_<13>C_2H_4;C_4F_9C_2H_4,X,Y=Cl,Br,NCS) were synthesized. As expected, these compounds were highly fluorophilic and thus exhibited high partition coefficients for the fluorous solvents when dissolved in a binary flurous/organic solvent mixture. The fluorous biphasic (trans)esterification by use of these catalysts enabled quantitative recovery of the catalysts, hence allowing the recycled use more than 20 times. More importantly, the reaction proceeded in 100% conversion and yield even by use of reactants in a strict 1:1 ratio. This means that the fluorous biphasic technology enabled the perfect conversion of the equilibrium reactions, which had be been realized before.
Next, the chlorine atoms in the above compounds were replaced by C_8F_<17>SO_3 and (C_8F_<17>SO_2)_2N with the hope to further increase the fluorophilicity. The desired compounds were obtained as hydrates, but they were not completely insoluble in fluorous solvents in contrary to our expectation. On the hand, they were soluble in polar organic solvents and, to our surprise, they preferentially dissolved in fluorous solvents when exposed to a binary mixture of fluorous and polar organic solvents. This anomaly was explained by replacement of hydrated water with polar organic solvents. Based on this character, fluorous distannoxanes proved to work as fluorous surfactants.

Report

(5 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (70 results)

All 2006 2005 2004 2003 2002 Other

All Journal Article (52 results) Book (6 results) Publications (12 results)

  • [Journal Article] Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts. Synthesis, Characterization, and Catalysis2006

    • Author(s)
      D.L.An, Z.Peng, A.Orita, A.Kurita, S.Man-e, K.Ohkubo, X.Li, S.Fukuzumi, J.Otera
    • Journal Title

      Chem. Eur. J. 12

      Pages: 1642-1647

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts. Synthesis, Characterization, and Catalysis2006

    • Author(s)
      D.L.An, Z.Peng, A.Orita, A.Kurita, S.Man-e, K.Ohkubo, X.Li, S.Fukuzumi, J.Otera
    • Journal Title

      Chem.Eur.J. 12

      Pages: 1642-1647

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Synthesis and Properties of 1,6,7,12,13,18,19,24-octamethl-dibenzo[def,par]tetraphenylene2005

    • Author(s)
      E.L.Elliott, A.Orita, D.Hasegawa, P.Gantzel, J.Otera, J.S.Seigel
    • Journal Title

      Org. Biomol. Chem. 3

      Pages: 581-583

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fluorous distannoxane-catalyzed acetylation of alcohols in heterogeneous single fluorous solvent system2005

    • Author(s)
      Z.Peng, A.Orta, D.L.An, J.Otera
    • Journal Title

      Tetrahedron Lett. 46

      Pages: 3187-3189

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] A cationic distannoxane catalyst, Synthesis and applications to carbon-cargon bond froming reactions2005

    • Author(s)
      X.Li, A.Kurita, S.Man-e, A.Orita, J.Otera
    • Journal Title

      Organometallics 24

      Pages: 2567-2569

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for synthesis of arylene ethynylenes containing heteroaromatic rings2005

    • Author(s)
      A.Orita, F.Ye, G.Babu, T.Ikemoto, J.Otera
    • Journal Title

      Can. J. Chem. 83

      Pages: 716-727

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel synthesis of 2-aryland 2,3-disubstituted indoles by modified double elimination protocol2005

    • Author(s)
      G.Babu, A.Orita, J.Otera
    • Journal Title

      Org. Lett. 7

      Pages: 4641-4643

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis and properties of 1,6,7,12,13,18,19,24-octamethyl-dibenzo[def,par]tetraphenylene2005

    • Author(s)
      E.L.Elliott, A.Orita, D.Hasegawa P.Gantzel, J.Otera, J.S.Siegel
    • Journal Title

      Org.Biomol.Chem. 3

      Pages: 581-583

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A cationic distannoxane catalyst. Synthesis and applications to carbon-carbon bond fromin reactions2005

    • Author(s)
      X.Li, A, Kurita, S.Man-e, A.Orita, J.Otera
    • Journal Title

      Organometallics 24

      Pages: 2567-2568

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for synthesis of arylene ethynylenes containing heteroaromatic rings2005

    • Author(s)
      A.Orita, F.Ye, G.Babu, T.Ikemoto, J.Otera
    • Journal Title

      Can.J.Chem. 83

      Pages: 716-727

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Novel synthesis of 2-aryl and 2,3-disubstituted indoles by modified double elimination protocol2005

    • Author(s)
      G.Babu, A.Orita, J.Otera
    • Journal Title

      Org.Lett. 7

      Pages: 4641-4643

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis and properties of 1,6,7,12,13,18,19,24-octamethyl-dibenzo[def,par]tetraphenylene2005

    • Author(s)
      E.L.Elliott, A.Orita, D.Hasegawa, P.Gantzel, J.Otera, J.S.Siegel
    • Journal Title

      Org.Biomol.Chem. 3

      Pages: 581-583

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A cationic distannoxane catalyst. Synthesis and applications to carbon-carbon bond froming reactions2005

    • Author(s)
      X.Li, A, Kurita, S.Man-e, A.Orita, J.Otera
    • Journal Title

      Organometallics 24

      Pages: 2567-2569

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Novel synthesis of 2-aryl and 2,3-disubstituted indoles by modified double elimination protocol2005

    • Author(s)
      G.Babu, A.Orita, J.Otera
    • Journal Title

      Org.Left. 7

      Pages: 4641-4643

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Toward Ideal(Trans) Esterification by Use of Fluorous Distannoxane Catalysts2004

    • Author(s)
      J.Otera
    • Journal Title

      Acc. Chem. Res. 37

      Pages: 288-296

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Bis(1H,1H,2H,2H-perfluorooctyl) Tin Oxide and 1,3-Dichloroterao(1H,1H,2H,2H-perfluoroocatyl) distannoxane. Synthesis and Applications of Fluorous Distannoxanes2004

    • Author(s)
      J.Otera
    • Journal Title

      In Hand book of Fluorous Chemistry, Gladysz, J.A.;cuma, D.P.;Horvathe,I.T.Eds,Wiley-VCH, Weinheim

      Pages: 412-414

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Intermittent molecular shuttle as a binary switch2004

    • Author(s)
      L.Jiang, J.Okano, A.Orita, J.Otera
    • Journal Title

      Angew. Chem. Int. Ed. 43

      Pages: 2121-2124

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Rate acceleration of the reaction between solid reactants by premixing in solution : application to the efficient synthesis of a [2] rotaxane2004

    • Author(s)
      L.Jiang, J.Okano, A.Orita, J.Otera
    • Journal Title

      Angew. Chem. Int. Ed. 43

      Pages: 3724-3728

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Metal-assisted assembly of pyridine-containing arylene ethynylene strands to enantiopure double helicates2004

    • Author(s)
      A.Orita, T.Nakano, D.L.An, K.Tanikawa, K.Wakamatsu, J.Otera
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 10389-10396

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] High birefringent bisdiynes and hexatriynes based on double elimination of b-substituted sulfones2004

    • Author(s)
      F.Ye, A.Orita, J.Yaruva, T.Hamada, J.Otera
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 528-529

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Toward Ideal (Trans)Esterification b Use of Fluorous Distannoxane Catalysts2004

    • Author(s)
      J.Otera
    • Journal Title

      Acc.Chem.Res. 37

      Pages: 288-296

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Bis(1H,1H,2H,2H-perfluorooctyl) Tin Oxide and 1,3-Dichloroterao(1H,1H,2H,2H-perfluoroocatyl)distannoxane. Synthesis and Applications of Fluorous Distannoxanes2004

    • Author(s)
      J.Otera
    • Journal Title

      Hand book of Fluorous Chemistry(Gladysz, J.A., Currna, D.P., Horvathe, I.T Eds.)(Wile-VCH, Weinheim) 2004

      Pages: 412-414

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Intermittent molecular shuttle as a binary switch2004

    • Author(s)
      L.Jiang, J.Okano, A.Orita, J.Otera
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 2121-2124

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Rate acceleration of the reaction between solid reactants by premixing in solution : application to the efficient synthesis of a [2]rotaxane2004

    • Author(s)
      L.Jiang, J.Okano, A.Orita, J.Otera
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 3724-3728

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Metal-assisted assembly of pyridine-containing arylene ethynylene strands to enantiopure double helicates2004

    • Author(s)
      A.Orita, T.Nakano, D.L.An, K.Tanikawa, K.Wakamatsu J.Otera
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 10389-10396

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] High birefringent bisdiynes and hexatriynes based on double elimination of b-substituted sulfones2004

    • Author(s)
      F.Ye, A.Orita, J.Yaruva, T.Hamada, J.Otera
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 528-529

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Toward Ideal (Trans)Esterification by Use of Fluorous Distannoxane Catalysts2004

    • Author(s)
      J.Otera
    • Journal Title

      Acc.Chem.Res. 37

      Pages: 288-296

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Bis(1H,1H,2H,2H-perfluorooctyl) Tin Oxide and 1,3-Dichloroterao(1H,1H,2H,2H-perfluoroocatyl)distannoxane. Synthesis and Applications of Fluorous Distannoxanes2004

    • Author(s)
      J.Otera
    • Journal Title

      In Hand book of Fluorous Chemistry (Gladysz, J.A.; Currna, D.P.; Horvathe, I.T.Eds.)(Wiley-VCH, Weinheim)

      Pages: 412-414

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Rate acceleration of the reaction between solid reactants by premixing in solution : application to the efficient synthesis of a [2]rotaxane2004

    • Author(s)
      A.Orita, J.Okano, Y.Tawa, L.Jiang, J.Otera
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 3724-3728

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Metal-assisted assembly of pyridine-containing arylene ethynylene strands to enantiopure double helicates2004

    • Author(s)
      A.Orita, T.Nakano, D.L.An, K.Tanikawa, K.Wakamatsu, J.Otera
    • Journal Title

      J.Am.Chem.Soc. 126

      Pages: 10389-10396

    • Related Report
      2004 Annual Research Report
  • [Journal Article] High birefringent bisdiynes and hexatriynes based on double elimination of β-substituted sulfones2004

    • Author(s)
      F.Ye, A.Orita, J.Yaruva, T.Hamada, J.Otera
    • Journal Title

      Chem.Lett. 33

      Pages: 528-529

    • NAID

      10012943382

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Unusual Carbonyl Differentiation in the Lewis Acid-Catalyzed Allylation of Aldehydes with Tertaallyltin. Applications to Parallel Recognition and Shotgun Process2003

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Pages: 2175-2182

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts2003

    • Author(s)
      Y.Imakura, S.Nishiguchi, A.Orita, J.Otera
    • Journal Title

      Appl. Organometal. Chem. 17

      Pages: 795-799

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for access to unsymmetrically substituted aromatic polyynes starting from sulfones and aldehydes2003

    • Author(s)
      F.Ye, A.Orita, A.Doumoto, J.Otera
    • Journal Title

      Tetrahedron 59

      Pages: 5635-5643

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Diversification of shotgun process2003

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Tetrahedron 59

      Pages: 5569-5578

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] High atom efficiency in Sc(OTf)_3-catalyzed allylation of aldehydes with tetraallyltin2003

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Adv. Synth. Cat. 345

      Pages: 643-646

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for access to unsymmetricaldi(phenylethnyl) benzenes2003

    • Author(s)
      A.Orita, F.Ye, A.Doumoto, J.Otera
    • Journal Title

      Chem. Lett. 32

      Pages: 104-105

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Unusual Carbonyl Differentiation in the Lewis Acid-Catalyzed Allylation of Aldehdes with Tetraallyltin. Applications to Parallel Recognition and Shotgun Process2003

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Bull.Chem.Soc.Jpn.

      Pages: 2175-2182

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Assessment of fluoroalkytin compounds as fluorous Lewis acid catalysts2003

    • Author(s)
      Y.Imakura, S.Nishiguchi, A.Orita, J.Otera
    • Journal Title

      Appl.Organometal.Chem. 17

      Pages: 795-799

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for access to unsymmetrically substituted aromatic of polyynes starting from sulfones and aldehydes2003

    • Author(s)
      F.Ye, A.Orita, A.Doumoto, J.Otera
    • Journal Title

      Tetrahedron 59

      Pages: 5635-5643

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] High atom efficiency in Sc(OTf)_3-catalyzed allylation of aldehydes With tetraallyltin2003

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Adv.Synth.Cat. 345

      Pages: 643-646

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Double elimination protocol for access tounsymmetricaldi(phenylethynyl)benzenes2003

    • Author(s)
      A.Orita, F.Ye, A.Doumoto, J.Otera
    • Journal Title

      Chem. Lett. 32

      Pages: 104-105

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fluorous biphasic esterification directed towards ultimate atom efficiency2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      Angew. Chem. Int. Ed. 42

      Pages: 4117-4119

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Combined Lewis acid catalyst in shotgun process : a convenient synthesis of the female sex pheromone of the red-bollworm moth2002

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Tetrahedron 58

      Pages: 8211-8218

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Solventless reaction dramatically accelerates supramolecular self-assembly2002

    • Author(s)
      A.Orita, L.Jian, T.Nakano, N.Ma, J.Otera
    • Journal Title

      J. Chem. Soc. Chem. Commun.

      Pages: 1362-1363

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fluoroalkyldistannoxane catalysts for transesterification in Fluorous Biphasic Technology2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      Adv. Synth. Cat. 344

      Pages: 84-90

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis and characterization of fluoroalkyldistannoxanes2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      J. Organomet. Chem. 648

      Pages: 264-250

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fluorous biphasic esterification directed towards ultimate atom efficiency2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      Angew.Chem.Int.Ed. 42

      Pages: 4117-4119

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Combined Lewis acid catalyst in shotgun process : a convenient synthesis of thefemale sex pheromone of the red-bollworm moth2002

    • Author(s)
      Y.Nagano, A.Orita, J.Otera
    • Journal Title

      Tetrahedron 58

      Pages: 8211-8218

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Solventless reaction dramatically accelerates supramolecular self-assembly2002

    • Author(s)
      A.Orita, L.Jiang, T.Nakano, N.Ma, J.Oterta
    • Journal Title

      J.Chem.Soc., Chem.Commun.

      Pages: 1362-1363

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fluoroalkyldistannoxane catalysts for transesterification in Fluorous Biphasic Technology2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      Adv.Synth.Cat. 344

      Pages: 84-90

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Synthesis and characterization of fluoroalkyldisannoxanes2002

    • Author(s)
      J.Xiang, A.Orita, J.Otera
    • Journal Title

      J.Organomet.Chem. 648

      Pages: 246-250

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] フルオラスケミストリー2005

    • Author(s)
      大寺 純蔵 監修
    • Total Pages
      277
    • Publisher
      シーエムシー出版
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Book] Florous Chemistry2005

    • Author(s)
      Junzo, Otera
    • Total Pages
      277
    • Publisher
      CMC publishing CO., Ltd
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Main Group Metals in Organic Synthesis Chapter 12, p621-7202004

    • Author(s)
      A.Orita, J.Otera
    • Total Pages
      1000
    • Publisher
      Wiley-VCH, Weinheim(H. Yamamoto, K. Oshima, Eds.)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Main Group Metals in Organic Synthesis Chapter 12(H.Yamamoto, K.Oshima, Eds.)2004

    • Author(s)
      A.Orita, J.Otera
    • Publisher
      Wile-VCH, Weinheim
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] Main Group Metals in Organic Synthesis Chapter 12(H.Yamamoto, K.Oshima, Eds.)2004

    • Author(s)
      A.Orita, J.Otera
    • Publisher
      Wiley-VCH, Weinheim
    • Related Report
      2004 Annual Research Report
  • [Book] Esterification2003

    • Author(s)
      J.Otera
    • Total Pages
      303
    • Publisher
      Wiley-VCH
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Publications] Y.Nagano, A.Orita, J.Otera: "Unusual Carbonyl Differentiation in the Lewis Acid-Catalyzed Allylation of Aldehydes with Tetraallyltin. Applications to Parallel Recognition and Shotgun Process"Bull.Chem.Soc.Jpn.. 2175-2182 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Imakura, S.Nishiguchi, A.Orita, Otera J.: "Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts"Appl.Organometal.Chem.. 17. 795-799 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] F.Ye, A.Orita, A.Doumoto, J.Otera, J.: "Double elimination protocol for access to unsymmetrically substituted aromatic polyynes starting from sulfones and aldehydes"Tetrahedron. 59. 5635-5643 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nagano, A.Orita, J.Otera: "Diversification of shotgun process"Tetrahedron. 59. 5569-5578 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nagano, A.Orita, J.Otera: "High atom efficiency in Sc(OTf)_3-catalyzed allylation of aldehydes with tetraallyltin"Adv.Synth.Catal.. 345. 643-646 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Otera: "Esterification"Wiley-VCH. 303 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Orita, A., Ye, F., Doumoto, A., Otera, J.: "Double elimination protocol for access to unsymmetricaldi(phenylethynyl)benzenes"Chem. Lett.. 32. 104 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Xiang, J., Orita, A., Otera, J.: "Fluorous biphasic esterification directed towards ultimate atom efficiency"Angew. Chem. Int. Ed.. 42. 4117-4119 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Nagano, Y., Orita, A., Otera, J.: "Combined Lewis acid catalyst in shotgun process: a convenient synthesis of the female sex pheromone of the red-bollworm moth"Tetrahedron. 58. 8211-8218 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Orita, A., Jiang, L., Nakano, T., Ma, N., Oterta, J.: "Solventless reaction dramatically accelerates supramolecular self-assembly"J. Chem. Soc., Chem. Commun.. 1362-1363 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Xiang, J., Orita, A., Otera, J.: "Fluoroalkyldistannoxane catalysts for transesterification Fluorous Biphasic Technology"Adv. Synth. Cat.. 344. 84-90 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Xiang, J., Orita, A., Otera, J.: "Synthesis and characterization of fluoroalkyldistannoxanes"J. Organomet. Chem.. 648. 246-250 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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