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Studies on shape resonance dynamics by photoelectron angular distribution measurements from oriented molecules

Research Project

Project/Area Number 14340126
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 物理学一般
Research InstitutionHigh Energy Accelerator Research Organization (2004)
The High Energy Accelerator Research Organization (2002-2003)

Principal Investigator

YAGISHITA Akira  High energy accelerator research organization, Institute of materials structure science, Prof., 物質構造科学研究所, 教授 (80157966)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Masahiko  Tohoku Univ, Institute of Multidisciplinary Research for Advanced Materials, Associate Prof., 多元物質科学研究所, 助教授 (80241579)
ADACHI Jun-ichi  High energy accelerator research organization, Institute of materials structure science, Res. Associate, 物質構造科学研究所, 助手 (10322629)
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥14,700,000 (Direct Cost: ¥14,700,000)
Fiscal Year 2004: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 2003: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2002: ¥11,400,000 (Direct Cost: ¥11,400,000)
Keywordsvelocity imaging / angular correlation / inversion symmetry / dissociation channel / triple coincidence / core-hole / 反転対称性 / 分子の構造変形 / 配向したCO_2分子 / 光電子の角度分布パターン / CO_2分子の対称性 / 運動量画像イメージング / 光電子・光イオン同時計測 / 振動準位を分離 / Franck-Condon原理の破れ / 形状共鳴 / スピン多重度を分離 / 光電離ダイナミックス / 電子・解離イオン同時計測実験装置 / 二次元検出器 / 円二色性 / 電気双極子遷移行列要素 / fσ_uチャンネル
Research Abstract

We have successfully designed and constructed a new apparatus of coincidence velocity imaging spectrometer for the study of angular correlations between photoelectrons and photofragments.
Using this apparatus, we have measured momentum correlation patterns between O1s photoelectrons and photofragments of CO^+ and O^+ at the photon energy above the ionization threshold of O1s of CO_2 molecules. And we have found that the O1s photoelectron angular distribution pattern violate the inversion symmetry.
We have also succeeded in measuring the C1s photoelectron angular distribution patterns of C_2H_2 molecules for each dissociation channel by the triple coincidence. For asymmetric dissociation channels, the C 1s photoelectron angular distribution patterns violate the inversion symmetry. This implies that the core-hole memory is preserved in the photofragments.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (35 results)

All 2005 2004 2003 2002 Other

All Journal Article (29 results) Publications (6 results)

  • [Journal Article] Inner-shell photoelectron angular distributions from fixed-in-space OCS molecules2005

    • Author(s)
      A.V.Golovin
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 38

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Photoelectron angular distributions from fixed-in-space molecules2005

    • Author(s)
      A.Yagishita
    • Journal Title

      Journal of Electron Spectroscopy and Relat.Phenom. 142

      Pages: 295-312

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Symmetry-resolved soft x-ray absorption spectroscopy ; its application to simple molecules2005

    • Author(s)
      J.Adachi
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 38(in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Inner-shell photoelectron angular distributions from fixed-in-space OCS molecules2005

    • Author(s)
      A.V.Golovin, J.Adachi, S.Motoki, M.Takahashi, A.Yagishita
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys 38

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoelectron angular distributions from fixed-in-space molecules2005

    • Author(s)
      A.Yagishita, H.Hosaka, J.Adachi
    • Journal Title

      Journal of Electron Spectroscopy and Relat. Phenom. 142

      Pages: 295-312

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoelectron angular distributions from fixed-in-space molecules.2005

    • Author(s)
      A.Yagishita
    • Journal Title

      Journal of Electron Spectroscopy & Relat.Phenom. 142

      Pages: 295-312

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Multiplet-specific N 1s photoelectron angular distributions from the fixed-in-space NO molecules2004

    • Author(s)
      K.Hosaka
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 37

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Angular distributions of vibrationally-resolved C 1s photoelectrons from fixed-in-space CO molecules : vibrational effect in the shape-resonant C 1s photoionization of CO2004

    • Author(s)
      J.Adachi
    • Journal Title

      Journal of Electron Spectroscopy and Relat.Phenom. 137

      Pages: 243-248

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Multiple photoionization following 3d_<5/2>-shell threshold ionization of Xe2004

    • Author(s)
      T.Matsui
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 37

      Pages: 3745-3752

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] O K-shell photoemission of the CO molecule : comparison between theory and experiment2004

    • Author(s)
      N.A.Cherepkov
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 37

      Pages: 4803-4815

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Multiplet-specific N 1s photoelectron angular distributions from the fixed-in-space NO molecules2004

    • Author(s)
      K.Hosaka, J.Adachi, M.Takahashi, A.Yagishita, P.Lin, R.R.Lucchese
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 37

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Angular distributions of vibrationally-resolved C 1s photoelectrons from fixed-in-space CO molecules : vibrational effect in the shape-resonant C 1s photoionization of CO2004

    • Author(s)
      J.Adachi, K.Hosaka, S.Furuya, K.Soejima, M.Takahashi, A.Yagishita, S.K.Semenov, N.A.Cherepkov
    • Journal Title

      Journal of Electron Spectroscopy and Relat. Phenom. 137

      Pages: 243-248

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Multiple photoionization following 3d_<5/2>-shell threshold ionization of Xe.2004

    • Author(s)
      T.Matsui, H.Yoshiki, K.Tsukamoto, S.Kawakita, E.Murakami, J.Adachi, A.Yagishita, Y.Morioka, T.Hayaishi
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 37

      Pages: 3745-3752

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] O K-shell photoemission of the CO molecule : comparison between theory and experiment2004

    • Author(s)
      N.A.Cherepkov, S.K.Semenov, A.V.Golovin, J.Adachi, A.Yagishita
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 37

      Pages: 4803-4815

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Angular distributions of vibrationally-resolved C1s photoelectrons from fixed-in-space CO molecules : vibrational effect in the shape-resonant C1s photoionization of CO.2004

    • Author(s)
      J.Adachi
    • Journal Title

      Journal of Electron Spectroscopy & Relat.Phenom. 137

      Pages: 243-248

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Shape-Resonance-Enhanced Vibrational Effects in the Angular Distributions of C 1s Photoelectrons from Fixed-in-Space CO Molecules2003

    • Author(s)
      J.Adachi
    • Journal Title

      Phys.Rev.Lett. 91

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] N 1s photoionization cross sections of nitric oxide molecules in the shape resonance region2003

    • Author(s)
      K.Hosaka
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. 36

      Pages: 4617-4629

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Shape-Resonance-Enhanced Vibrational Effects in the Angular Distributions of C 1s Photoelectrons from Fixed-in-Space CO Molecules2003

    • Author(s)
      J.Adachi, K.Hosaka, S.Furuya, K.Soejima, M.Takahashi, A.Yagishita, S.K.Semenov, N.A.Cherepkov
    • Journal Title

      Phys. Rev. Lett. 91

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] N 1s photoionization cross sections of nitric oxide molecules in the shape resonance region2003

    • Author(s)
      K.Hosaka, J.Adachi, M.Takahashi, A.Yagishita
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 36

      Pages: 4617-4629

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Double photoionization of helium at an excess energy of 60 eV using left-and right-elliptically-polarized light2002

    • Author(s)
      S.A.Collins
    • Journal Title

      Phys.Rev.A 65

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Cascade processes after 3p-shell threshold photoionization of Kr2002

    • Author(s)
      T.Matsui
    • Journal Title

      J.Phys.B : At.Mol.Opt.Phys. 35

      Pages: 3069-3075

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Complete photoionization experiment in the region of the 2□_g□ □_u shape resonance of the N_2 molecule2002

    • Author(s)
      S.Motoki
    • Journal Title

      J.Phys.B : At.Mol.Opt.Phys. 35

      Pages: 3801-3819

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Characterization of □_u shape resonance in the C 1s ionization continuum of CO_2 molecules.2002

    • Author(s)
      J.Adachi
    • Journal Title

      J.Phys.B : At.Mol.Opt.Phys. 35

      Pages: 5023-5033

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Double photoionization of helium at an excess energy of 60 eV using left-and right-elliptically-polarized light2002

    • Author(s)
      S.A.Collins, S.Cvejanovic, C.Dawson, T.J.Reddish, D.P.Seccombe, A.Huetz, L.Malegat, P.Selles, A.K.Kazansky, A.Danjo, K.Soejima, K.Okuno, A.Yagishita
    • Journal Title

      Phys. Rev. A 65

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Cascade processes after 3p-shell threshold photoionization of Kr.2002

    • Author(s)
      T.Matsui, H.Yoshii, A.Higurashi, E.Murakami, T.Aoto, T.Onuma, Y.Morioka, A.Yagishita, T.Hayaishi
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 35

      Pages: 3069-3075

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Complete photoionization experiment in the region of the 2□_g□ □_u shape resonance of the N_2 molecule2002

    • Author(s)
      S.Motoki, J.Adachi, K, Ito, K.Ishii, K.Soejima, A.Yagishita, S.K.Semenov, N.A.Cherepkov
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 35

      Pages: 3801-3819

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Characterization of of □_u shape resonance in the C 1s ionization continuum of CO_2 molecules2002

    • Author(s)
      J.Adachi, S.Motoki, N.A.Cherepkov, A.Yagishita
    • Journal Title

      J. Phys. B ; At. Mol. Opt. Phys. 35

      Pages: 5023-5033

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Symmetry-resolved soft x-ray absorption spectroscopy ; its application to simple molecules

    • Author(s)
      J.Adachi, N.Kosugi, A.Yagishita
    • Journal Title

      J. Phys. B; At. Mol. Opt. Phys (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Symmetry-resolved soft x-ray absorption spectroscopy : its application to simple molecules.

    • Author(s)
      J.Adachi
    • Journal Title

      J.Phys.B ; At.Mol.Opt.Phys. (accepted)

    • Related Report
      2004 Annual Research Report
  • [Publications] J.Adachi: "Shape-Resonance-Enhanced Vibrational Effects in the Angular Distributions of C 1s Photoelectrons from Fixed-in-Space CO Molecules"Phys.Rev.Lett.. 91・16. 163001-1-163001-4 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Hosaka: "N 1s photoionization cross sections of nitric oxide molecules in the shape resonance region"J.Phys.B : At.Mol.Opt.Phys.. 36・23. 4617-4629 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Hosaka: "Multiplet-specific N 1s photoelectron angular distributions from the fixed-in-space NO molecules"J.Phys.B : At.Mol.Opt.Phys.. 37・3. L49-L55 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Adachi: "Angular distributions of vibrationally-resolved C 1s photoelectrons from fixed-in-space CO molecules : vibrational effect in the shape resonant C 1s photoionization"J.Electron Spectrosc.Relat.Phenom.. (in press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Motoki: "Complete photoionization experiment in the region of the 2σ_g→σ_u shape resonance of the N_2 molecule"J.Phys.B : At.Mol.Opt.Phys.. 35・18. 3801-3819 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Jun-ichi Adachi: "Characterization of σ_u shape resonance in the C ls ionization continuum of CO_2 molecules"J.Phys.B : At.Mol.Opt.Phys.. 35・24. 5023-5033 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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