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Interaction between the transition metals and organic molecules in the framework structure of zeolite.

Research Project

Project/Area Number 14340161
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionThe University of Tokyo

Principal Investigator

SUGIYAMA Kazumasa  The University of Tokyo, Graduate School of Science, Research Associate Professor, 大学院・理学系研究科, 助教授 (40196762)

Co-Investigator(Kenkyū-buntansha) TANAKA Masahiko  Institute of Materials Structure Science, High Energy Accelerator research Organization, Research Associate, 物質構造科学研究所, 助手 (60249901)
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥14,300,000 (Direct Cost: ¥14,300,000)
Fiscal Year 2004: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2003: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2002: ¥10,900,000 (Direct Cost: ¥10,900,000)
Keywordszeolite / crystal structure / x-ray diffraction / anomalous scattering / laumontite / Zn-Al-P-O system / Co-Al-P-O system / SHG発振 / laumonitite / ZN-Al-P-O系 / 非線形光学効果 / Zn-Al-P-O系化合物 / 単結晶構造解析 / セオライト / 水熱合成 / 異常散乱 / 放射光
Research Abstract

The purpose of this study is to characterize the interaction between transition metals and organic molecules in zeolites with the porous framework structure. For this purpose a special experimental facility which allows us to perform the single crystal anomalous X-ray scattering measurement was newly built at the Photon Factory at the Institute of Materials Structure Research. Anomalous x-ray scattering method is powerful technique and the environmental structure around a specific element can be obtained from the analysis of the energy dependence of the scattering data. This relatively new method was applied to the analysis of Se@mordenite and the chain like Se molecule in the mordenite channel was quantitatively obtained by suggesting the electron transfer from Se molecules. The solvo-thermal technique in the Zn-Al-P-O and Co-Al-P-O system allowed us to serve the laumontite framework structure. Laumontite in the Zn(Co)-Al-P-O system indicates the ordering of transition metals and incorporated organic molecule and 1,2-aminoethypiperazine@laumontite, in particular, showed the non-centered space group symmetry of Cc. The measurement of the SHG signal for this new material supported the attractive performance and further application of such materials for the optic-electrical will be realized in near future.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (22 results)

All 2004 2003 Other

All Journal Article (17 results) Book (1 results) Publications (4 results)

  • [Journal Article] Crystal Structure of a 2/1 Cubic Approximant in an Al-Rh-Si Alloy.2004

    • Author(s)
      K.Sugiyama, W.Sun, K.Hiraga
    • Journal Title

      Journal of Non-Crystalline Solids 344&345

      Pages: 156-160

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Di(2-methylimidazolium) aluminum diphosphorous hydroxyloxide2004

    • Author(s)
      J.Takashima, K.Sugiyama, T.Tagai, O.Terasaki, J.Yu
    • Journal Title

      Acta Crystallogr. C60

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Anomalous X-ray Scattering Study for Determining Cation Distribution in ZnFe_2O_4 and NiFe_2O_4.2004

    • Author(s)
      K.Sugiyama, T.Okamoto, Y.Waseda
    • Journal Title

      High Temperature Materials Processing 23・5&6

      Pages: 357-369

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Crystal Structure of a 2/1 Cubic Approximant in an Al-Rh-Si Alloy.2004

    • Author(s)
      K.Sugiyama, W.Sun, K.Hiraga
    • Journal Title

      J.Non-Crystalline Solids 344&345

      Pages: 156-160

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Di-(2-methylimidazolium) aluminum diphosphorous Hydroxioxide.2004

    • Author(s)
      J.Takashima, K.Sugiyama, T.Tagai, O.Terasaki, J.Yu
    • Journal Title

      Acta Crystallogr. C60

      Pages: 333-334

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Anomalous X-ray Scattering Study for Determining Cation Distribution in ZnFe_2O_4 and NiFe_2O_4.2004

    • Author(s)
      K.Sugiyama, T.Okamoto, Y.Waseda
    • Journal Title

      High Temp.Mater.Processings 23(5-6)

      Pages: 357-369

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Crystal structure of a rhombohedral λ-AlFeSi.2004

    • Author(s)
      K.Sugiyama, N.Kaji, K.Hiraga
    • Journal Title

      J.Alloy.Comp. 368

      Pages: 251-255

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Di(2-methylimidazolium) aluminium dihosphrous hydroxloxide2004

    • Author(s)
      J.Takashima, K.Sugiyama, T.Tagai, O.Terasaki, J.Yu
    • Journal Title

      Acta Cryst.C C60

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Influence of intermartensitic transitions on transport propertiese of Ni_<2.16>Mn_<0.84>Ga alloy.2004

    • Author(s)
      V.V.Khovailo, K.Oikawa, C.Wedel, T.Takagi, T.Abe, K.Sugiyama
    • Journal Title

      J.Phys, : Condens.Matter 16

      Pages: 1951-1961

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Anomalous X-ray Scattering Study for Determining Cation Distribution in ZnFe_2O_4 and NiFe_2O_42004

    • Author(s)
      K.Sugiyama, T.Okamoto, Y.Waseda
    • Journal Title

      High Temp.Mater Processing 23(5-6)

      Pages: 357-366

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural Characterization of Non-Crystalline Oxides by the Anomalous X-ray Scattering2003

    • Author(s)
      Y.Waseda, K.Sugiyama
    • Journal Title

      High Temperature Materials Processing 22・2

      Pages: 103-122

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Energy Dispersive X-ray Diffraction Method for Structural Characterization of Non-Crystalline Oxides.2003

    • Author(s)
      Y.Waseda, K.Sugiyama
    • Journal Title

      High Temperature Materials Processing 22・3&4

      Pages: 211-219

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] チャバサイト型骨格構造を持つAl-P-O系物質の合成と結晶構造2003

    • Author(s)
      高島淳矢, 杉山和正, 田賀井篤平
    • Journal Title

      ゼオライト 20・4

      Pages: 156-162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural Characterization of Non-Crystalline Oxides by the Anomalous X-ray Scattering.2003

    • Author(s)
      Y, Waseda, K.Sugiyama
    • Journal Title

      High Temp.Mater.Processing 22(2)

      Pages: 103-122

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Energy Dispersive X-ray Diffraction Method for Structural Characterization of Non-Crystalline Oxides.2003

    • Author(s)
      Y, Waseda, K.Sugiyama
    • Journal Title

      High Temp.Mater.Processing 22(3-4)

      Pages: 211-219

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis and Crystal structure of AIPO-34 with the chabazite structure.2003

    • Author(s)
      J.Takashima, K, Sugiyanma, T.Tagai
    • Journal Title

      ZEORAITO 20(4)

      Pages: 156-162

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Small-angle X-ray Scattering to Characterization of Condensed Mater.2003

    • Author(s)
      Y.Waseda, K.Sugiyama, A.H.Shinohara
    • Journal Title

      Advances in Material Research (Springer-Verlag)

      Pages: 63-91

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] Small-angle X-ray Scattering to Characterization of Condensed Matter2003

    • Author(s)
      Y.Waseda, K.Sugiyama, A.H.Shinohara
    • Publisher
      Advances in Material Research, Springer-Verlag
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] Y.Waseda, K.Sugiyama: "Structural Characterization of Non-Crystalline Oxides by the Anomalous X-ray Scattering."High Temeprature Materials Processing. 22・2. 103-122 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Waseda, K.Sugiyama: "Energy Dispersive X-ray Diffraction Method for Structural Characterization of Non-Crystalline Oxides."High Temperature Materials Processing. 22・3&4. 211-219 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Sugiyama, W.Sun, K.Hiraga: "Crystal Structure of a 2/1 Cubic Approximant in an Al-Rh-SiAlloy."Journal of Non-Crystalline Solids. 344&345. 156-160 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 高島淳矢, 杉山和正, 田賀井篤平: "チャバサイト型骨格構造を持つAl-P-O系物質の合成と結晶構造"ゼオライト. 20・4. 156-162 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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