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SYNTHESES OF PHOTOCHROMIC METAL COMPLEXES WITH LIGHT-TRIGGERED INCLUSION FUNCTION OF GUEST MOLECULES.

Research Project

Project/Area Number 14340211
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionKinki University

Principal Investigator

MUNAKATA Megumu  KINKI UNIVERSITY, DEPARTMENT OF SCIENCE, PROFESSOR, 理工学部, 教授 (80090942)

Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥16,000,000 (Direct Cost: ¥16,000,000)
Fiscal Year 2003: ¥5,800,000 (Direct Cost: ¥5,800,000)
Fiscal Year 2002: ¥10,200,000 (Direct Cost: ¥10,200,000)
Keywordsmultifunction / photochromism / porous metal complex / guest molecule / adsorption / desorption / diaiylethene / solid state / crystal structure / フォトクロミック錯体 / ゲスト分子の取り込み / 多孔性金属錯体 / 光応答金属錯体 / 複合機能錯体 / 光メモリー / 反応点間距離 / 銀錯体
Research Abstract

The purpose of this study is to synthesize multifunctional complexes with diarylethene, i,e., porous photochromic complexes which reversibly incoorpolate guest molecules in the cavity, using the structural change between ring ring-open and ring-closed forms of photochromic diarylethene.
(1)Reversible incoorpolation of guest molecules in porous photochromic complexes. We succeeded in synthesizing porous photochromic metal complexes with 2,3-bis(2,4,5-trimethyl-3-thienyl)maleimide(bttm), [Ag(bttm)(CF_3COO)] (1) h [Ag(closed-bttm)(CF_3COO)] (2),which have channels of 7.0×7.9Å and 7.5×7.6Åsizes, respectively. Reversible incoorpolation and elimination of guest molecules in the porous complexes was studied by means of TG, X-ray powder pattern and ^1H NMR spectrum. Complex 1 takes in 0.4 molar pentane and about 75% of this pentane is desorbed by heating at 120℃. On the other hand, complex 2 takes in 1.9 molar pentane which is completely desorbed by the light irradiation as well as by heating at 130℃, indicating the possibility of light-triggered inclusion of guest molecules.
(2)Synthesis of novel photochromic and porous complexes. Diarylethene derivatives with pyridine rings which is easily coordinated to metal ions, 1,2-bis(2'-methyl-5'-(4''-pyridyl)-3'-thienyl)perfluorocyclopentene(BM-4-PTP), 1, 2-bis(3-methyl-5'-(2''-pyridyl)-2'-thienyl)perfluorocyclopentene(BM-2-PTP) and their photochromic copper(II)complex,[Cu(BM-4-PTP)_2(CF_3COO)_2]・2H_2O・2THF and [Ag_2(BM-2-PTP)(CF_3COO_2](C_6H_6), were synthesized in order to construct novel complexes with light-triggered inclusion function of guest molecules.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (35 results)

All Other

All Publications (35 results)

  • [Publications] 宗像 惠, 他5名: "Conversion of Phellyl-Subsituted Cyclopentadiene to Pyrylium Cations."J.Org.Chem.. 69・4. 1432-1424 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他7名: "Syntheses, Structures and Properties of Intercalation Compounds of Siiver(I) Complex with [2.2] Paracyclophane."Inorg.Chem.. 43・2. 633-641 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他6名: "Synthesis, Crystal Structure and Magnetic Properties of Novel Mn_<12>Single-Molecule Magnets with Thiophenylcarboxyiate"Polyhedron. 22. 1795-1801 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他6名: "Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular π-π Interactions."Inorg.Chem.. 42・8. 2553-2558 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他5名: "Syntheses and Structures of Photochromic Silver(I) Coordination Polymers withcis-1,2-Dicyano-1,2-Bis(2,4,5-trimethyl-3-thienyl)ethen"Inorg.Chem.. 42・6. 1928-1934 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他5名: "Prcparation, Crystal Structure and Spectroscopic Properties of Vanadium(III)Complexes with [V-O-V]^<4+> Cores"J.Chem.Soc., Dalton Trans.. 11. 2390-2398 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 分担執筆: "集積型金属錯体の科学"化学同人. 273(17) (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] G.L.Ning, X.C.Li, M.Munakata et al.: "Conversion of Phenyl-Subsituted Cyclopentadiene to Pyrylium Cations."J.Org.Chem.. 69, No.4. 1432-1434 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Munakata et al.: "Syntheses, Structures and Properties of Intercalation Compounds of Silver(I) Complex with [2.2]Paracyclophane."Inorg.Chem.. 43, No.2. 633-641 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Munakata et al.: "Syntheses and Crystal Structures of the First Indium Complexes with m-and p-terphenyl."Inorg.Chim.Acta. 357. 331-338 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Munakata et al.: "Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular π-π-Interactions"Inorg.Chem.. 42, No.8. 2553-2558 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Konaka, L.Wu, M.Munakata et al.: "Syntheses and Structures of Photochromic Silver(I) Coordination Polymers with cis-1,2-Dicyano-1,2-Bis(2,4,5-trimethyl-3-thienyl)ethene"Inorg.Chem.. 42, No.6. 1928-1934 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Suenaga, S.Konaka, M.Munakata et al.: "Crystal Structure and photo-induced propertity of Two-dimensional Siver(I) Complex with 1,3,5-Tris(benzylsulfanyl)benzene"Inorg.Chim.Commun. 6. 389-393 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Maekawa, N.Hashimoto, M.Munakata et al.: "Syntheses and Structural Characterization of [2,2]Paracyclophane Complexes of Rhodium and Iridium Supported By Diene Ligands"Inorg.Chim.Acta. 344. 143-157 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] J.C.Zhong, M.Munakata et al.: "Syntheses and Structural Studies on Silver(I) Coordination Polymers with Trans, trans-1,4-dipenyl-1,3-butadiene"Inorg.Chim.Acta. 342. 202-208 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Wen, M.Munakata et al.: "Porous Silver(I) Organometallic Coordination Polymer of Triptycene, and The Guest Desorption and Absorption"Inorg.Chim.Acta. 340. 8-14 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Wen, M.Maekawa, M.Munakata et al.: "Dinuclear Silver(I) Complexes of Dibenzo-crown ethers and the Mononuclear Complex of Aminobenzo-crown ether"Inorg.Chim.Acta. 338. 111-118 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] G.Q.Bian, J.Dai, M.Munakata et al.: "Benzenthiolate Bridged Binuclear Group 12 Metal Complexes with TTF Fused Dithiolate Ligand, A New Synthetic Approach using Cluster-Cracking Reaction."Bull.Chem.Soc.Jpn.. 73. 561-655 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kuroda-Sowa, S.Fukuda, M.Munakata et al.: "A Chemical Modification of a Mn_<12> Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions"Chemistry Letters. No.7. 682-683 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kumagai, S.Kitagawa, M.Munakata et al.: "Preparation, Crystal Structure and Spectroscopic Properties of Vanadium(III) Complexes with [V-O-V]^<4+> Cores."J.Chem.Soc.(Dalton Trans.). No.11. 2390-2398 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Wen, M.Munakata et al.: "Silver(I) Complexes of Dibenzo-18-crown-6-ether having Cation-π andπ-π Interactions"Inorg.Chim.Acta. 332. 18-24 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Suenaga, M.Munakata et al.: "A Zigzag Chain Coordination Polymer Consisting of Silver(I) Ion having Square Planar Geometry."Inorg.Chim.Acta. 328. 105-110 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 宗像 惠, 他5名: "Conversion of Pheynyl-Subsituted Cyclopentadiene to Pyrylium Cations."J.Org.Chem.. 69・4. 1432-1424 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他7名: "Syntheses, Structures and Properties of Intercalation Compounds of Silver(I) Complex with [2.2]Paracyclophane."Inorg.Chem.. 43・2. 633-641 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他6名: "Synthesis, Crystal Structure and Magnetic Properties of Novel Mn_<12>Single-Molecule Magnets with Thiophenylcarboxylate, [Mn_<12>O_<12>(O_2CC_4H_3S)_<16>(H_2O)_4], and Tetraphenylphosphonium Salt."Polyhedron. 22. 1795-1801 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他6名: "Construction of the Multidecker Anthracene-Silver(I) System by Intramoleular π-π Interactions."Inorg.Chem.. 42・8. 2553-2558 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他5名: "Synthesis and Structures of Photochromic Silver(I) Coordination Polymers with cis-1,2-Dicyano-1,2-Bis(2,4,5-trimethyl-3-thienyl)ethene."Inorg.Chem.. 42・6. 1928-1934 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他5名: "Crystal Structure and Photo-Induced Propertity of Two-dimensional Siver(I) Complex with 1,3,5-Tris(benzylsulfanyl)benzene."Inorg.Chim.Commun.. 6. 389-393 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠 分担執筆: "集積型金属錯体の科学"化学同人. 273(17) (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 宗像 惠, 他4名: "Porous Silver(I) Organometallic Coordination Polymer of Triptycene, and The Guest Desorption and Absorption"Inorg. Chim. Acta.. 340. 8-14 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 宗像 惠, 他4名: "Dinuclear Silver(I) complexes of dibenzo-crown ethers and the mononuclear complex of aminobenzo-crown ether"Inorg. Chim. Acta.. 338. 111-118 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 宗像 惠, 他5名: "Benzenthiolate Bridged Binuclear Group 12 Metal Complexes with TTF Fused Dithiolate Ligand, A New Synthetic Approach using Cluster-Cracking Reaction"Chem. Commun.. 14. 1474-1475 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 宗像 惠, 他5名: "Preparetion Crystal Structure and Spectroscopic Properties of Vanadium(III) Complexes with [V-O-V]^<4+> Cores"J. Chem. Soc., Dalton Trans.. 11. 22390-2398 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 宗像 惠, 他4名: "Silver(I) Complexes of Dibenzo-18-crown-6-ether having Cation-π and π-π interactions"Inorg. Chim. Acta.. 332. 18-24 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 宗像 惠, 他4名: "A Zigzag Chain Coordination Polymer Consisting of Silver(I) Ion having Square Planar Geometry"Inorg. Chim. Acta.. 328. 105-110 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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