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Study on the Formation Processes of Polycyclic Aromatic Hydrocarbon in a Fuel Spray Flame via Excitation Emission Matrix spectroscopy

Research Project

Project/Area Number 14350103
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

KOSAKA Hidenori  Tokyo Institute of Technology, Graduate School of Science and Engineering, Associate Professor, 大学院・理工学研究科, 助教授 (50225413)

Co-Investigator(Kenkyū-buntansha) AIZAWA Tetsuya  Tokyo Institute of Technology, Graduate School of Science and Engineering, Research Associate, 大学院・理工学研究科, 助手 (60323797)
MATSUI Yukio  Tokyo Institute of Technology, Graduate School of Science and Engineering, Professor, 大学院・理工学研究科, 教授 (50301172)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥13,000,000)
Fiscal Year 2003: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2002: ¥10,100,000 (Direct Cost: ¥10,100,000)
KeywordsFuel Spray Flame / Soot Formation Processes / Polycyclic Aromatic Hydrocarbons(PAHs) / Soot Precursors / Excitation Emission Matrix(EEM) / Shock Tube / High Temp.and High Pres.Conditions / Multiwavelenghts Laser / すす前駆物 / 多色レーザー
Research Abstract

In order to investigate the formation processes of the polycyclic aromatic hydrocarbons (PAHs) which are considered as soot precursors in a spray flame, Excitation Emission Matrix (EEM) spectroscopy which can be applied to the transient fuel spray at high temperature and high pressure was developed. The latter half of this study, the laser-induced fluorescence spectroscopy and 2-S imaging were applied to the spray flame in a rapid compression machine. The summary of the obtained results are followings
(1)The stronger emission was observed in the incident side of the spray flame in the case of excitation by 226 nm wavelength than that in the case of 355 nm excitation. This indicates that the more kinds of species are excited and emit the fluorescence in the case of 266 nm excitation than that of 355 nm excitation.
(2)In the case of 335 nm excitation, the LIF from formaldehyde formed in the low temperature oxidation process of fuel was detected before the hot ignition, this LIF from formaldehyde disappears rapidly and the LIF from PAHs are appears immediately after the hot ignition. In the case of 266 nm excitation, the LIF from formaldehyde was not detected before the hot ignition, but the LIF from impurities in fuel was observed. After the hot ignition, the strong LIF from PAHs appears which has the same spectrum as the case of 355 nm excitation.
(3)In the both cases of 266 nm and 355 excitations, the LIF from PAHs can be observed in the central region of a spray flame between 35 mm and 45 mm from the nozzle orifice after the hot ignition. At the 55 mm from the nozzle orifice, the LII from soot particles is overlapped to the LIF from PAHs.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Aizawa, T., Kosaka, H., Matsui, Y.: "2-D Imaging of Soot Formation Process in a Transient Spray Flame by Laser-Induced Fluorescence and Incandescence Techniques"SAE Technical paper. 2002-01-2669. 1-9 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Aizawa, T., Imaichi, K., Kosaka, H., Matsui, Y.: "Measurement of Excitation-Emission Matrix of Shock Heated PAHs using a Multi-Wavelength Laser Source"SAE Technical paper. 2003-01-1785. 1-10 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 相澤哲哉, 小酒英範, 松井幸雄: "レーザー誘起蛍光・赤熱法による非定常噴霧火炎内すす生成過程の2次元可視化"日本機械学会論文集(B編). 69・680. 981-987 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 相澤哲哉, 小酒英範, 松井幸雄: "多波長レーザ光源を用いた火炎内多環芳香族炭化水素の励起発光マトリクス(EEM)の測定"日本機械学会論文集(B編). 70・690. 496-502 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Aizawa, T., Kosaka, H., Matsui, Y.: "2-D Imaging of Soot Formation Process in a Transient Spray Flame by Laser-Induced Fluorescence and Incandescence Techniques"SAE Technical paper. No.2002-01-2669. 1-9 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Aizawa, T., Imaichi, Kosaka, H., Matsui, Y.: "Measurement of Excitation-Emission Matrix of Shock Heated PAHs using a Multi-Wavelength Laser Source"SAE Technical paper. No.2003-01-1785. 1-10 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Aizawa, T., Kosaka, H., Matsui, Y.: "2-D Imaging of Soot Formation Process in a Transient Spray Flame by Laser-Induced Fluorescence and Incandescence Techniques"SAE Technical paper. 2002-01-2669. 1-9 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] Aizawa, T., Imaichi, K., Kosaka, H., Matsui, Y.: "Measurement of Excitation-Emission Matrix of Shock Heated PAHs using a Multi-Wavelength Laser Source"SAE Technical paper. 2003-01-1785. 1-10 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 相澤哲哉, 小酒英範, 松井幸雄: "レーザー誘起蛍光・赤熱法による非定常噴霧火炎内すす生成過程の2次元可視化"日本機械学会論文集(B編). 69・680. 981-987 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 相澤哲哉, 小酒英範, 松井幸雄: "多波長レーザ光源を用いた火炎内多環芳香族炭化水素の励起発光マトリクス(EEM)の測定"日本機械学会論文集(B編). 70・690. 496-502 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Aizawa, T., Kosaka, H., Matsui, Y.: "2-D Imaging of Soot Formation Process in a Transient Spray Flame by Laser-Induced Fluorescence and Incandescence Techniques"SAE Technical paper. 2002-01-2669. 1-9 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Aizawa, T., Imaichi, K., Kosaka, H., Matsui, Y.: "Measurement of Excitation-Emission Matrix of Shock Heated PAHs using a Multi-Wavelength Laser Source"SAE Technical paper. 2003-01-1785. 1-10 (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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