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Preparation of all-solid-state thin film secondary batteries by pulsed laser deposition method

Research Project

Project/Area Number 14350157
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionTohoku University

Principal Investigator

KAWAMURA Junichi  TOHOKU UNIVERSITY, Institute of Multidisciplinary Research for Advanced Materials, Professor, 多元物質科学研究所, 教授 (50142683)

Co-Investigator(Kenkyū-buntansha) KAMISHIMA Osamu  TOHOKU UNIVERSITY, Institute of Multidisciplinary Research for Advanced Materials, Research Associate, 多元物質科学研究所, 助手 (90321984)
HATTORI Takeshi  Science University of Tokyo, Department of Physics, Professor, 理学部, 教授 (20029234)
佐多 教子  東北大学, 大学院・工学研究科, 助教授 (20271984)
入山 次郎  日本電気(株), NECラボラトリーズ, 研究員
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥14,800,000 (Direct Cost: ¥14,800,000)
Fiscal Year 2004: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 2003: ¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 2002: ¥5,800,000 (Direct Cost: ¥5,800,000)
Keywordsthin film battery / secondary battery / lithium battery / laser abration / solid state ionics / superionic conductor / ionic conductor glass / lithium cobalt oxide / 固体電解質
Research Abstract

Recent developments of the electronic devices strongly demand very small energy sources with high power density. A thin-film lithium-ion battery is one of the candidates for satisfying these demands. In this project we have tried and succeeded in preparation of all-solid-state thin film batteries by using a pulsed laser deposition (PLD) method.
First, we have investigated the condition for preparing amorphous lithium ion conductor films by thermal evaparation and PLD method. A good quality amorphous thin film was obtained for the Li4SiO4-Li3VO4 by PLD, which can be used as the solid electrolyte for batteries. The film was characterized through X-ray, FT -IR, Raman, a field emission scanning electron microscope (FE-SEM), an atomic force microscope (AFM) and an inducting coupled plasma (ICP). The ionic conductivity of the film was 10-7S/cm at room temperature.
Second, we have prepared cathode and anode thin films also by PLD method. Then, we found the good preparation condition for LiCoO2 as a cathode and SnO as an anode.
Thirdly, based on these results, we have demonstrated to prepare some all-solid-stete thin film secondary lithium ion batteries only by PLD method. The battery consisted of LiCoO2/LVSO/SnO exhibited a good performance of of an open circuit voltage of about 2.7 V, and a good reversibility on charge-discharge cyclings over 100 cycles between 0 and 3.3 V. The thin-film battery can be handled in open atmosphere before charging.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (28 results)

All 2005 2004 2003 Other

All Journal Article (16 results) Book (1 results) Patent(Industrial Property Rights) (1 results) Publications (10 results)

  • [Journal Article] Thin film batteries in "Solid State Ionics for Batteries"2005

    • Author(s)
      J.Kawamura
    • Journal Title

      Solid State Ionics for Batteries(ed.T.Minami)(Springer-Verlag, Tokyo)

      Pages: 64-72

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Preparation of amorphous lithium ion conductor thin-films by laser deposition2004

    • Author(s)
      J.Kawamura 他
    • Journal Title

      Solid Sate Ionics 175,1-4

      Pages: 273-276

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Non-Arrhenius ionic conductivity in a-AgI stabilized composites and rapid quenched glasses2004

    • Author(s)
      N.Kuwata 他
    • Journal Title

      Solid State Ionics 175,1-4

      Pages: 679-682

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Thin-film lithium ion batteries with Li-V-Si-O amorphous solid electrolyte fabricated by pulsed laser deposition2004

    • Author(s)
      Kuwata, N 他
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion

      Pages: 637-644

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural and Impedance spectroscopic analysis of LiBiVO42004

    • Author(s)
      Bhuvaneswari, M.S 他
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion

      Pages: 519-524

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Thin-film lithium-ion battery with amorphous solid electrolyte fabricated by pulsed laser deposition2004

    • Author(s)
      N.Kuwata 他
    • Journal Title

      Electrochem.Commun 6

      Pages: 417-421

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Preparation of amorphous lithium ion conductor thin-films by laser deposition2004

    • Author(s)
      J.Kawamura et al.
    • Journal Title

      Solid Sate Ionics 175(1-4)

      Pages: 273-276

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Non-Arrhenius ionic conductivity in a-AgI stabilized composites and rapid quenched glasses2004

    • Author(s)
      N.Kuwata et al.
    • Journal Title

      Solid State Ionics 175,(1-4)

      Pages: 679-682

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Thin-film lithium ion batteries with Li-V-Si-O amorphous solid electrolyte fabricated by pulsed laser deposition2004

    • Author(s)
      N.Kuwata, et al.
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion

      Pages: 637-644

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Structural and Impedance spectroscopic analysis of LiBiVO42004

    • Author(s)
      M.S.Bhuvaneswari, et al.
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion

      Pages: 519-524

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Thin-film lithium-ion battery with amorphous solid electrolyte fabricated by pulsed laser deposition2004

    • Author(s)
      N.Kuwata et al.
    • Journal Title

      Electrochem.Commun. 6

      Pages: 417-421

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Non-Arrhenius ionic conductivity in a-Agl stabilized composites and rapid quenched glasses2004

    • Author(s)
      N.Kuwata 他
    • Journal Title

      Solid Sate Ionics 175,1-4

      Pages: 679-682

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Thin-film lithium ion batteries with Li-V-Si-O amorphous solid electrolyte fabricated by pulsed laser deposition2004

    • Author(s)
      Kuwata, N.他
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion (B.V.R.Chowdari et al., ed., World Sci.Publ.Co., Singapor)

      Pages: 637-644

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural and Impedance spectroscopic analysis of LiBiVO42004

    • Author(s)
      Bhuvaneswari, M.S.他
    • Journal Title

      Solid State Ionics : The Science and Technology of Ions in Motion (B.V.R.Chowdari et al., ed., World Sci.Publ.Co., Singapor)

      Pages: 519-524

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Cation dynamics of stabilized alpha-AgI in AgI-Ag2O-MoO3 glasses, studied by Ag-109 NMR2003

    • Author(s)
      N.Kuwata 他
    • Journal Title

      J.Non-Cryst.Solids 324

      Pages: 79-91

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Cation dynamics of stabilized alpha-Agl in AgI-Ag2O-MoO3 glasses, studied by Ag-109 NMR2003

    • Author(s)
      N.Kuwata et al.
    • Journal Title

      J.Non-Cryst.Solids 324

      Pages: 79-91

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] Solid State Ionics for Batteries (ed.T.Minami)2005

    • Author(s)
      J.Kawamura
    • Publisher
      Springer-Verlag, Tokyo
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 酸化物エピタキシャル薄膜およびその作製方法2003

    • Inventor(s)
      佐多 教子他
    • Industrial Property Rights Holder
      東北大学
    • Filing Date
      2003-08-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Publications] J.Kawamura他(5名): "Preparation of amorphous lithium ion conductor thin-films by laser deposition"Solid Sate Ionics. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kuwata他(4名): "Thin-film lithium-ion battery with amorphous solid electrolyte fabricated by pulsed laser deposition"Electrochem.Commun.. 6. 417-421 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kuwata他(4名): "cation dynamics of stabilized alpha-Agl in Agl-Ag20-Mo03 glasses, studied by Ag-109 NMR"J.Non-Cryst.Solids. 324. 79-91 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kuwata他(4名): "Non-Arrhenius ionic conductivity in a-Agl stabilized composites and rapid quenched glasses"Solid State Ionics. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 河村純一: "実験化学講座第5版7電気物性,磁気物性(固体のイオン伝導体)"日本化学会編 丸善. 12 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kuwata 他2名: "New organic-inorganic hybrid superionic conductor glasses consisting of silver iodide and alkylbis-trimethylammonium diiodides"Solid State Commun.. 124. 221-226 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Waki 他3名: "Optical and electrical properties of Tl-S glasses"J. Non-Cryst. Solids. 297. 26-30 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.Kawamura 他3名: "Ag-109 NMR of AgI based superionic conductor glasses"Proceedings of 8th Asian Conference on Solid State Ionics. 751-762 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J Kawamura 他4名: "Evidence of multi-site exchange in AgI-AgPO3 glasses : 109Ag NMR hole-burnign spectra"Solid State Ionics. 154-155. 183-188 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Aniya 他1名: "Medium range structure and activation energy of ion transport in glasses"Solid State Ionics. 154-155. 343-348 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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