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PROPOSAL OF NOVEL FACILITATED TRANSPORT MEMBRANE FOR GAS SEPARATION AND ITS APPLICATION FOR PROTECTION OF GLOBAL ENVIROMENT

Research Project

Project/Area Number 14350417
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 反応・分離工学
Research InstitutionKYOTO INSUTITUTE OF TECHNOLOGY

Principal Investigator

TERAMOTO Masaaki  KYOTO INSTITUTE OF TECHNOLOGY, FACULTY OF ENGINEERING AND DESIGN, PROFESSOR, 工芸学部, 教授 (60026086)

Co-Investigator(Kenkyū-buntansha) MATSUMIYA Norifumi  SUMITOMO ELECTRIC INDUSTRIES, LTD., POLYMER PHOTONIC COMPONENTS PROJECT, ASSISTANT MANEGER, エレクトロニクス材料研究所, 主席
MATSUYAMA Hideto  KYOTO INSTITUTE OF TECHNOLOGY, FACULTY OF ENGINEERING AND DESIGN, ASSOCIAITE PROFESSOR, 工芸学部, 助教授 (50181798)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 2003: ¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2002: ¥10,300,000 (Direct Cost: ¥10,300,000)
Keywordsfacilitated transport membrane / hollow fiber membrane module / gas separation / carbon dioxide / global warming / amice / ethylene / silver nitrate / 中空糸膜モジュール / 阻外濾過膜 / 熱誘起相分離法
Research Abstract

A novel hollow fiber or capillary-type facilitated transport membrane module was developed for gas separation, in which both the feed gas and the carrier solution are supplied to the lumen of the module (feed side, high-pressure side) and the solution containing dissolved gas permeates the membrane to the permeate side (shell side, low-pressure side) maintained at a reduced pressure. There, the dissolved gas is stripped from the solution and recovered as an enriched gas. The carrier solution is recycled to the lumen of the module by a pump. This novel membrane system was applied to CO_2 separation from model flue gases, and also ethylene/ethane separation, which is one of the most energy intensive separations in chemical processes. The following promising results were obtained.
1. The proposed membrane system was found to have very high efficiency (>80%) by the experiments on the CO_2/N_2 separation using a physical solvent, water as an absorbent for the case where the feed side pressur … More e was atmospheric and the permeate side pressure was about 10kPa and also for the case where the feed side pressure was 200 to 500kPa and the permeate side pressure was atmospheric.
2. In the separation of CO_2 from model flue gases using various amines as carriers of CO_2, CO_2 in N_2 could be enriched from 1.5-15% to 98.5-99.8% by a one stage membrane separation. The typical results obtained at 10% CO_2 in the feed gas were as follows. CO_2 permeance: 1200GPU, CO_2/N_2 selectivity: 80% at the mean residence time of gas in module=0.28_s. The energy consumption was much lower than those of conventional separation methods. Furthermore, by using hollow fiber ultrafiltration membranes with a larger inside diameter, which was fabricated by the thermally induced phase separation (TIPS) technique, the energy consumption was remarkably reduced. It was found that the present membrane separation method was the most energy saving method for the CO_2 recovery from flue gases.
3. In the ethylene/ethane separation using a 4M A_gNO3 solution, where the feed side pressure was from 200 to 500 kPa and the permeate side was atmospheric pressure, ethylene was enriched from 80% to 99.8%. The ethylene/ethane selectivity was 300, and the ethylene permeance was 300GPU.
4. The membrane modules were stable during a discontinuous several-month testing period without the decreases in permeance and selectivity. Less

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] M.Teramoto, T.Takeuchi, T.Maki, H.Matsuyama: "Facilitated Transport of CO_2 through liquid membrane accompanied by permeation of carrier solution"Separation and Purification Technology. 27,1. 25-31 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Takeuchi, T.Maki, H.Matsuyama: "Ethylene/ethane separation by facilitated transport membrane accompanied by permeation of aqueous silver nitrate solution"Separation and Purification Technology. 28,2. 117-124 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Ohnishi, N.Takeuchi, S.Kitada, H.Matsuyama, N.Matsumiya, H.Mano: "Separation and enrichment of CO_2 by capillary membrane module with permeation of carrier solution"Separation and Purification Technology. 30,3. 215-227 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, S.Kitada, N.Ohnishi, H.Matsuyama, N.Matsumiya: "Separation and concentration of CO_2 by capillary-type facilitated transport membrane with permeation of carrier solution"Journal of Membrane Science. 234,1-2. 83-94 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Takeuchi, N.Ohnishi, H.Matsuyama: "Removal of CO_2 by novel facilitated transport membrane using capillary membrane module with permeation of carrier solution"Abstract of Sixth international Conference on Green house Gas Control Technologies. 122-122 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, S.Kitada, N.Ohnishi, H.Matsuyama, N.Matsumiya: "Simultaneous separation and enrichment of CO_2 by novel capillary membrane module with permeation of carrier solution"Proc.PERMEA 2003. 162-162 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Takeuchi, T.Maki, H.Matsuyama: "Facilitated transport of CO_2 through liquid membrane accompanied by permeation of carrier solution"Separation and Purification Technology. 27,1. 25-31 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Takeuchi, T.Maki, H.matsuyama: "Ethylene/ethane separation by facilitated transport membrane accompanied by permeation of aqueous silver nitrate solution"Separation and Purification Technology. 28,2. 117-124 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Ohnishi, N.Takeuchi, S.KItada, H.Matsuyama, N.Matsumiya, H.Mano: "Separation and enrichment of carbon dioxide by capillary membrane module with permeation of carrier solution"Separation and Purification Technology. 30,3. 215-227 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.teramoto, N.S.kitada, N.Ohnishi, H.Matsuyama, N.matsuyama: "Separation and concentration of CO_2 by capillary-type facilitated transport membrane module with permeation of carrier solution"J.Membrane Sci.. 234. 83-94 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, N.Takeuchi, N.Ohnishi, H.Matsuyama: "Removal of CO_2 by novel facilitated transport membrane using capillary module with permeation of carrier solution"Abstract of Sixth International Conference on Greenhouse Gas Control Technology. 122-122 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Teramoto, S.KItada, N.Ohnishi, H.Matsumiya: "Simultaneous separation and enrichment of CO_2 by novel capillary membrane module with permeation of carrier solution"Proc. Permea 2003(Slovakia). 162-162 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Masaaki Teramoto: "Separation and enrichment of carbon dioxide by capillary membrane module with permeation of carrier solution"Separation and Purification Technology. 30巻3号. 215-227 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaaki Teramoto: "Separation and concentration of CO_2 by capillary-type facilitated transport membrane module with permeation of carrier solution"Journal of membrane Science. (in press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaaki Teramoto: "Simultaneous separation and enrichment of CO_2 by novel capillary membrane module with permeation of carrier solution"Proc.PERMEA2003. 162-162 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 寺本正明: "キャリヤー溶液の透過を伴う中空糸促進輸送膜によるガス分離"膜シンポジウム2003 講演要旨集. No.15. 5-8 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Masaaki Teramoto: "Separation and enrichment of carbon dioxide by capillary membrane module with permeation of carrier solution"Separation and Purification Technology. 30巻・3号. 215-227 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 尚 孟弦: "熱誘起相分離法によるポリエチレン/ビニルアルコール共重合体中空糸膜の作製と膜特性評価"化学工学会第68年会講演要旨集. 講演番号R301. (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Masaaki Teramoto: "Removal of carbon dioxide by novel tubular-type gas absorber"Proc. CHISA 2002(15th International Congress of Chemical and Process Engineering). Summary 2. 60-61 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Masaaki Teramoto: "Ethylene/ethane separation by facilitated transport membrane accompanied by permeation of aqueous silver nitrate solution"Separation and Purification Technology. 28巻・2号. 117-124 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Masaaki Teramoto: "Facilitated transport of CO_2 through liquid membrane accompanied by permeation of carrier solution"Separation and Purification Technology. 27巻・1号. 25-31 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Masaaki Teramoto: "Removal and enrichment of CO_2 by novel facilitated transport membrane using capillary membrane module with permeation of carrier solution"Proceedings of Sixth International Conference on Greenhouse Gas Control Technologies (GHGT-6). (Elsevier Scienceから3月に刊行予定). (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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