| Project/Area Number |
14350498
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
高分子構造・物性(含繊維)
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| Research Institution | Kobe University |
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Principal Investigator |
YANAGI Hisao Kobe University, Faculty of Engineering, Research Associate, 工学部, 助手 (00220179)
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| Co-Investigator(Kenkyū-buntansha) |
TANIGUCHI Yoshio Shinshu University, Faculty of Textile Science and Technology, Professor, 繊維学部, 教授 (00283242)
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| Project Period (FY) |
2002 – 2003
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| Project Status |
Completed (Fiscal Year 2003)
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| Budget Amount *help |
¥8,300,000 (Direct Cost: ¥8,300,000)
Fiscal Year 2003: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2002: ¥6,400,000 (Direct Cost: ¥6,400,000)
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| Keywords | Self-organization / π-Conjugated oligomer / Low-dimensional crystals / Organic semiconductor laser / Organic electroluminescence / Field effect transistor / 電界効果型トランジスタ |
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| Research Abstract |
This study was carried out to realize organic semiconductor lasers using self-organized low-dimensional crystals of π-conjugated oligomers based on their confinement effects of excitons and light. The results are summarized as follows.
(1) Development of laser dye molecules
We found that π-conjugated linear oligomers of distyrylbenzene derivatives, thiophene and p-phenylene are promising as stable lasing materials with good emission efficiency under high current injection.
(2) Fabrication of self-organized low-dimensional crystals
The self-organized low-dimensional crystals were successfully prepared by vapor-deposition of the above oligomers onto the (100) surface of a KCl single-crystal substrate. The oligomer of the distyrylbenzene derivative was self-olganized in dotlike morphology of 1-10 μm in diameter. The tiophene/phenylene co-oligomers grew in epitaxially oriented rodlike crystals.
(3) Optically pumped light amplification phenomena of self-organized low-dimensional crystals
The self
… More
-organized microdots and epitaxially oriented rodlike crystals were optically pumped by a pulsed excition laser and their photoluminescence spectra were observed. The emitted light was confined in these low-dimensional crystals and gain-narrowed by their microcavity and self-waveguiding effects resulting in the amplified spontaneous emisson (ASE) with a band width of several nanometers. Furthermore,by changing the excitation wavelengths, unusually narrowed emission (band width < 0.5 nm) related to the Raman scattering process was obtained. It was assigned as the stimulated resonance Raman scattering that was indicative of polaritonic interaction between the emitted light and the excitons localized at a specific molecular vibration mode.
(4) Current injection characteristics of FET devices fabricated with self-organized low-dimensional crystals
Carrier injection and transport properties of field effect transistors fabricated with the self-organized low-dimensional crystals were measured. The highest hole mobility, 0.015 cm2V-1s-1, was obtained from the epitaxially oriented crystals of the thiophene/phenylene co-oligomer. It suggests that the crystal orientation with respect to the channel direction is important to improve the carrier transport efficiency. Less
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