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Behavior analysis for separation of heavy metalcompounds in exhaust gas in waste heat treatment process

Research Project

Project/Area Number 14380267
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 環境保全
Research InstitutionKanazawa University

Principal Investigator

HATA Mitsuhiko (2004)  Kanazawa University, Graduate School of Natural Science and Technology, Research associate, 自然科学研究科, 助手 (00334756)

金岡 千嘉男 (2002-2003)  金沢大学, 自然科学研究科, 教授 (00019770)

Co-Investigator(Kenkyū-buntansha) FURUUCHI Masami  Kanazawa University, Division of Environmental Science and Engineering, Associate professor, 自然科学研究科, 助教授 (70165463)
増井 芽  (株)アクトリー, 技術開発・営業室, 室長代行(研究職)
畑 光彦  金沢大学, 工学部, 助手 (00334756)
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥15,300,000 (Direct Cost: ¥15,300,000)
Fiscal Year 2004: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2003: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2002: ¥11,700,000 (Direct Cost: ¥11,700,000)
KeywordsHeat treatment of waste / Heavy metal compounds / Gas treatment / Consistent separation / Particle generation / Residence time / Reaction rate / High temperature gas cleaning / 有機脱水汚泥 / 廃棄物 / 重金属化合物 / 熱力学平衡計算 / ダスト / 溶融 / 存在形態 / 下水脱水汚泥 / 平衡計算 / セラミックフィルタ
Research Abstract

To analyze behavior of heavy metal compounds in exhaust gas from waste heat treatment process, single straight tube type simulator has been developed. The simulator is capable of simulating status change of exhaust gas components such as heavy metals and toxic gases as SO_2 and HCl. Calculated and experimental states of exhaust gas through the simulator by controlled temperature and flow rate have been compared. To discuss possibility of heavy metal compounds separation technology from industrial waste, following items have been discussed.
1)Experimental investigation of heavy metals behavior in waste heat treatment process simulator
Waste heat treatment process simulator which consists of waste heat treatment exhaust gas generator and state-controlled sampler has been developed. The exhaust gas can treat wastes up to 1100℃ and provide exhaust gas up to 10L/min to the state-controlled sampler. For particulate and gas sampling from exhaust gas at various temperatures, the state-controlled … More sampler has three stage quartz filter thimbles at independently-controlled temperature from 800 to 200℃ through a straight sampling tube. Behavior of heavy metals has been investigated by temperature and residence time which has been controlled by flow-rate and quartz filter thimbles' position. From the results, particle generation ratio difference by temperature and residence time has been observed.
2)State estimation of exhaust gas include heavy metals by thermodynamic equilibrium simulation
Exhaust gas state through the state-controlled sampler has been simulated by thermodynamic equilibrium calculation. From the result, heavy metals compounds state has been changed by sampling temperature and gas composition. Therefore, possibility of heavy metals separation technology has been indicated.
3)State change estimation of heavy metals in exhaust gas by reaction kinetics theory
Lead compounds particle generation rate in exhaust gas by temperature has been investigated by reaction kinetics calculation. From the results, particle generation mechanism has been suggested to be rather phase change such as condensation than chemical reaction.
4)Investigation of effective method of heavy metals separation
From the all discussions above, most effective condition settings for heavy metals separation such as sampling temperature and residence time have been discussed. Less

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (21 results)

All 2005 2004 Other

All Journal Article (13 results) Book (1 results) Publications (7 results)

  • [Journal Article] The influence of humidity on dry separation of granular particles based on geometrical characteristics2005

    • Author(s)
      M.Furuuchi, K.Gotoh, C.Kanaoka
    • Journal Title

      Powder Technology (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Characterization and Modeling Filtration in a Granular Coke Bed2004

    • Author(s)
      M.Furuuchi, M.Hata, C.Kanaoka, R.Takahashi, J.Yagi, R.Takehama, Y.Kawaminami
    • Journal Title

      Characterization & Control of Interfaces for High Quality Advanced Materials 146

      Pages: 365-373

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] A Mechanistic Model for Mercury Capture with In-Situ Generated Titania Particles : Role of Water Vapor2004

    • Author(s)
      S.Rodriguez, C.Almquist, T.G.Lee, M.Furuuchi, E.Hedrick, P.Biswas
    • Journal Title

      J.Air and Waste Management Association 54

      Pages: 149-156

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Separation Characteristics of a Supersonic Virtual Impactor2004

    • Author(s)
      M.Furuuchi, C.Kanaoka, Y.Shimizu
    • Journal Title

      Proc. Asian Pacific Confederation of Chemical Engineering 2004 (APCChE2004) (CD-ROM)

    • NAID

      130005052397

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Transformation of Mineral and Emission of Particulate Matters during Co-combustion of Coal with Sewage Sludge2004

    • Author(s)
      Y.Ninomiya, L.Zhang, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel 83(6)

      Pages: 751-764

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Combustibility of Dried Sewage Sludge and its Mineral Transformation at Different Oxygen Content in Drop Tube Furnace2004

    • Author(s)
      L.Zhang, M.Ito, A.Sato, Y.Ninomiya, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel Processing Technology 85(8-10)

      Pages: 983-1011

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Characterization and Modeling Filtration in a Granular Coke Bed2004

    • Author(s)
      M.Furuuchi, M.Hata, C.Kanaoka, R.Takahashi, J.Yagi, R.Takehama, Y.Kawaminami
    • Journal Title

      Characterization & Control of Interfaces for High Quality Advanced Materials

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Transformation of Mineral and Emission of Particulate Matters during Co-combustion of Coal with Sewage Sludge2004

    • Author(s)
      Y.Ninomiya, L.Zhang, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel 83

      Pages: 6-6

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Combustibility of Dried Sewage Sludge and its Mineral Transformation at Different Oxygen Content in Drop Tube Furnace2004

    • Author(s)
      L.Zhang, M.Ito, A.Sato, Y.Ninomiya, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel Processing Technology 85

      Pages: 8-10

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Separation Characteristics of a Supersonic Virtual Impactor2004

    • Author(s)
      M.Furuuchi, C.Kanaoka, Y Shimizu
    • Journal Title

      Proc.Asian Pacific Confederation of Chemical Engineering 2004 (APCChE2004)

    • NAID

      130005052397

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Separation Characteristics of a Supersonic Virtual Impactor2004

    • Author(s)
      M.Furuuchi, C.Kanaoka, Y.Shimizu
    • Journal Title

      Proc.Asian Pacific Confederation of Chemical Engineering 2004(APCChE2004) (CD-ROM)

    • NAID

      130005052397

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Transformation of Mineral and Emission of Particulate Matters during Co-combustion of Coal with Sewage Sludge2004

    • Author(s)
      Y.Ninomiya, L.Zhang, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel 83,6

      Pages: 751-764

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Combustibility of Dried Sewage Sludge and its Mineral Transformation at Different Oxygen Content in Drop Tube Furnace2004

    • Author(s)
      L.Zhang, M.Ito, A.Sato, Y.Ninomiya, T.Sakano, C.Kanaoka, M.Masui
    • Journal Title

      Fuel Processing Technology 85,8-10

      Pages: 983-1011

    • Related Report
      2004 Annual Research Report
  • [Book] まちづくりのための気候学入門2005

    • Author(s)
      古内正美他21名
    • Total Pages
      150
    • Publisher
      建築学会(予定)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Publications] Y.Ninomiya, L.Zhang, T.Sakano, C.Kanaoka, M.Masui: "Transformation of Mineral and Emission of Particulate Matters during Co-combustion of Coal with Sewage Sludge"Fuel. 83・6. 751-764 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] L.Zhang, Y.Ninomiya, T.Sakano, C.Kanaoka, M.Masui: "Combustibility of Sewage Sludge and the Mineral Transformation at Different Oxygen Content in Drop Tube Furnace"Fuel Processing Technology. (Submitted).

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Ninomiya, H.Cui, M.Masui, T.Sakano, C.Kanaoka: "Combustibility of Dehydrated Sewage Sludge under Oxygen Enrichment Condition"Journal of Material and Waste Management. (Submitted).

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Hata, M.Furuuchi, C.Kanaoka, R.Kurose, H.Makino: "Observation of Dust Release Behavior from Ceramic Filter Element"Journal of Advanced Powder Technology. 14・6. 719-734 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] R.Kurose, H.Makino, M.Hata, C.Kanaoka: "Numerical Analysis of a Flow Passing through a Ceramic Candle Filter on Pulse Jet Cleaning"Journal of Advanced Powder Technology. 14・6. 735-748 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Sakano, C.Kanaoka, M.Furuuchi K.Yang, M.Hata: "Separation Characteristics of Heavy Metal Compounds by Hot Gas Cleaning System"Gas Cleaning at High Temperature III. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Hata, C.Kanaoka, M.Furauchi, T.Inagaki: "Analysis of Pulse-jet Cleaning of Dust Cake from Ceramic Filter Element"Gas Cleaning at High Temperature III. (in press).

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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