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Three-Dimensional Molecular Alignment by the Use of Selective Adsorption on Solids

Research Project

Project/Area Number 14550008
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionShizuoka University (2004)
Kyoto Institute of Technology (2002-2003)

Principal Investigator

KUBONO Atsushi  Shizuoka University, Faculty of Engineering, Associate Prof., 工学部, 助教授 (70234507)

Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2004: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2003: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2002: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsQuartz Crystal Microbalance / Liquid Crystals / Crystal Growth / Molecular Orientation / Adsorption / Anisotropy / Substrate Temperature / Visco-elasticity / 強誘電性 / 残留分極
Research Abstract

Organic thin films with high performance require three-dimensional (3D) regulation of the position and the orientation of molecules in organic thin films. The 3D regulation appears to be feasible by combination of one-dimensional out-of-plane regulation and two-dimensional in-plane alignment. The out-of-plane regulation involves the molecular layer epitaxy method firstly demonstrated by the author, and the out-of-plane alignment can be controlled by the interfacial anisotropy induced by the external electric field, the substrate crystal structure and the rubbing of the substrate surface. The electric and optical properties of these films are investigated. The mechanism of the specific structure formation is discussed from the quartz crystal microbalance study on the basis of a novel theoretical model.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (7 results)

All 2003 Other

All Journal Article (5 results) Publications (2 results)

  • [Journal Article] Remanent Polarization of Evaporated Films of Vinylidene Fluoride Oligomers2003

    • Author(s)
      K.Noda, K.Ishida, A.Kubono, T.Horiuchi, H.Yamada, K.Matsushige
    • Journal Title

      J.Appl.Phys. 93

      Pages: 2866-2870

    • NAID

      120000910517

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Visco-elastic Analysis in the Formation of Organic Thin Films

    • Author(s)
      A.Kubono, R.Akiyama
    • Journal Title

      Mol.Cryst.Liq.Cryst. (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Visco-elastic Analysis in the Formation of Organic Thin Films

    • Author(s)
      A.Kubono, R.Akiyama
    • Journal Title

      Mol.Cryst.Liq.Cryst. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Visco-elastic Analysis in the Formation of Organic Thin Films

    • Author(s)
      A.Kubono, R.Akiyama
    • Journal Title

      Mol.Cryst.Liq.Cryst. (in press)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Thermodynamic Model of Molecular Orientation in Vapor-deposite Organic Thin Films

    • Author(s)
      A.Kubono.R.Akiyama
    • Journal Title

      J.Appl.Phys. (in press)

    • Related Report
      2004 Annual Research Report
  • [Publications] A.Kubono, T.Sato, K.Takemoto, R.Akiyama, K.Tanaka: "Striped Pattern Formation in Polymer-Dispersed Liquid Crystal Films"Liq.Cryst.. 30. 1181-1187 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Noda, K.Ishida, A.Kubono, T.Horiuchi, H.Yamada, K.Matsushige: "Remanent Polarization Observed for Evaporated Films of Vinylidene Fluoride Oligomer"J.Appl.Phys.. 93. 2866-2870 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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