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Control of X-ray induced defects in chalcogenide glasses : Large area X-ray sensor for medical use

Research Project

Project/Area Number 14550297
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionGifu University

Principal Investigator

SHIMAKAWA Koichi  Gifu University, Faculty of Engineering, Professor, 工学部, 教授 (60021614)

Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 2003: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2002: ¥3,200,000 (Direct Cost: ¥3,200,000)
Keywordschalcogenide glasses / X-ray digital detector / carrier diffusion / X-ray induced defect / photo-induced defect / image degradation / flat panel / electronic space charge / X-ray digital detector for Medical use / X-ray detector / photoinduced defect / photoinduced structural changes
Research Abstract

To obtain X-ray images directly for medical use, a new system without using X-ray films has been proposed (direct conversion from X-ray into free electrons and holes using chalcogenide glasses). A large area and real-time observations should be required in the new system. The following big problems should be overcome : (1) A signal intensity (sensitivity) decreases with X-ray exposures, and (2) The real time observations are limited owing to a response time.
In the present research project, the principal object is to understand the problem (1). It is well known that microscopic defects increase with visible light exposure in chalcogenide glasses. These light-induced defects lead to the decrease in sensitivity of optical devices. If the number of defect increases with X-ray exposure, sensitivity of X-ray images decreases, which is attributed to a decrease in collective efficiency of free electrons and holes induced by X-ray. Therefore, firstly, we should understand a correlation between defect creation arid sensitivity of X-ray images.
The following results have been obtained in amorphous selenium which is one of chalcogenide glasses: (1) Carrier collective efficiency decreases with X-ray exposure time. Time dependence of the decreases in sensitivity is empirically described by a stretched exponential function. (2) The photoconductivity is unchanged by X-ray-exposure. (3) Photoluminescence (PL) intensity is unchanged by X-ray exposure. The above results suggest that new defects are not induced by X-ray exposure.
Probably, trapping of electrons and holes induced by X-ray in deep localized states may affect carrier collection efficiency. These are also studied theoretically. Photo-structural changes have been also studied to understand these phenomena.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] K.Shimakawa: "Dynamics of Photo-induced Metastability in Amorphous Chalcogenides"Dynamics of Photo-induced Metastability in Amorphous Semiconductors (Book ed. by A.V.Kolobov) (Wiley-VCH). 58-68 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa: "Influence of potential fluctuations on photoconductivity in a-Si : H"J.Material Science : Materials in Electronics. 14. 685-688 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa et al.: "Quantum efficiency of light-induced defect creation in hydrogenated amorphous silicon and amorphous As2Se3"Philosophical Magazine B. 84. 81-89 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa et al.: "Acceralation of photodarkening under d.c. electric field in amorphous As2Se3"J.Non-Cryst.Solids. (印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Ikeda, K.Shimakawa: "Real-time in-situ measurements of photoinduced volume changes in amorphous chalcogenides"J.Non-Cryst.Solids. (印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Jai Singh, Koichi Shimakawa: "Advances in Amorphous Semiconductors"Taylor & Francis. 328 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa: "Dynamics of Photo-induced Metastability in Amorphous Chalcogenides"Dynamics of Photo-induced Metastability in Amorphous Semiconductors (Book ed.by A.V.Kolobov) (Wiley-VCH). 58-68 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa: "Influence of potential fluctuation on photoconductivity in a-Si:H"J.Material Sciences : Materials in. vol.14. 685-688 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa et al.: "Quantum efficiency of Light-induced defect creation in hydrogenated Amorphous silicon and amorphous As2Se3"Philosophical Magazine B. vol.84. 81-89 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa et al.: "Acceleration of photodarkening under d.c.electric field in Amorphous As2Se3"J.Non-Cryst.Solids. (in print). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Ikeda, K.Shimakawa: "Real-time in-situ measurements of Photoinduced volume changes in amorphous Chalcogenides"J.Non-Cryst.Solids. (in print). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Jai Smgh, Koichi Shimakawa: "Advances in Amorphous Semiconductors"Taylor & Francis (London and New York). 328 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Shimakawa: "Dynamics of Photo-induced Metastability in Amorphous Chalcogenides"Dynamics of Photo-induced Metastability in Amorphous Semiconductors (Book edited by A.V.Kolobov) (Wiley-VCH). 58-68 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Shimakawa: "Influence of potential fluctuations on photoconductivity in a-Si:H"J.Material Science : Materials in Electronics. 14. 685-688 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Shimakawa et al.: "Quantum efficiency of light-induced defect creation in hydrogenated Amorhous silicon and amorphous As2Se3"Philosophical magazine B. 84. 81-89 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Shimakawa et al.: "Acceleration of photodarkening under d.c.electric field in amorphous As2Se3"J.Non-Cryst.Solids. (In print). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Shimakawa et al.: "Photoconductivity of a-Si:H and a-Ge:H : Influence of potential fluctuations"J.Non-Cryst.Solids. (In print). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Ikeda, K.Shimakawa: "Real-time in-situ measurements of photoinduced volume changes in Amorphous chalcogenides"J.Non-Cryst.Solids. (In print). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Jai Singh, Koichi Shimakawa: "Advances in Amorphous Semiconductors"Taylor & Francis. 328 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Shimakawa: "Photoconductivity of hydrogenated amorphous silicon : Influence of Potential fluctuations"Philosophical Magazine Letter. 82. 635-640 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Ganjoo, K.Shimakawa: "Dynamics of photodarkening in amorphous chalcogenides"J. Optoelectronics and Advanced Materials. 4. 595-604 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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