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Positron Annihilation Study of Cu pecipitation Induced by Irradiation and Deformation

Research Project

Project/Area Number 14550655
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionKyushu University

Principal Investigator

KURAMOTO Ejichi  Kyushu University, Research Institute for Applied Mechanics, Professor, 応用力学研究所, 教授 (30013519)

Co-Investigator(Kenkyū-buntansha) OHSAWA Kazuhito  Kyushu University, Research Institute for Applied Mechanics, Research Associate, 応用力学研究所, 助手 (90253541)
ABE Hironobu  Kyushu University, Research Institute for Applied Mechanics, Research Associate, 応用力学研究所, 助手 (90038555)
TSUKUDA Nonoru  Kyushu University, Research Institute for Applied Mechanics, Associate Professor, 応用力学研究所, 助教授 (90038563)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2003: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2002: ¥3,000,000 (Direct Cost: ¥3,000,000)
KeywordsPressure Vessel Steel / Irradiation Embrittlement / Cu Precipitation in Fe / Positron Annihilation Measurement / Coincidence Doppler Measurement / Electrical Resistivity Measurement / Cu Migration due to SIA / 鉄中の銅析出過程 / 軽水炉圧力容器の脆化 / 照射欠陥 / 塑性変形
Research Abstract

It has been clarified that the irradiation embrittlement plays a main role in the determination of the lifetime of the neutron reactor, and the basic process which causes the irradiation embrittlement is the irradiation enhanced Cu precipitation in Fe matrix. In the present study the atomistic feature of this process has been made clear by using the positron annihilation technique and electrical resistivity measurement which were applied for model Fe-Cu alloys irradiated by electrons at low temperature and also deformed at room temperatue. Low temperature irradiation induced vacancies and interstitial atoms into the model alloys and during the isochronal annealing process Cu atoms distributed randomly in the matrix started to form micro-precipitates by the aid of irradiation induced defects. Positrons are trapped not only vacancy type defects but also Cu precipitates because of its high positron affinity. The coincidence Doppler broadening measurement was made for low temperature irradiated or deformed Fe-Cu alloys and from the isochronal annealing measurement, the so-called W-S plot was obtained. This result clearly shows that positrons are trapped and annihilated at Cu-precipitates even at low temperature below stage III (220K). This suggests that self-interstitial atoms contribute to the formation of Cu precipitates. At higher temperatures vacancies also contribute to the formation of Cu precipitates. This new contribution from interstitial atoms is confirmed from the electrical resistivity measurement for the Fe-Cu model alloys irradiated at low temperatures. It is reasonably considered that Cu atoms migrate by the aid of self-interstitial atoms through the so-called mixed dumbbell mechanism. The recent calculation of the atomic size of Cu in Fe matrix shows that Cu is almost the same or slightly larger than Fe, which does not contradict to the mixed dumbbell mechanism.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Deformation-Enhanced Cu Precipetation in Fe-Cu Alloy Studied by Positron Annihilation Spectroscopy"Phys.Rev.B. 65. 012204-1-012204-4 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Irradiation-Enhanced Cu-Precipitation in Fe-Cu Alloys Studied by Positron Annihilation Spectroscopy and Electrical Resistivity Measurement"Mat.Sci.Forum. 455-456. 168-170 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Chiba, E.Kuramoto et al.: "Electronic Structure of Nanosized bcc Cu Precipitates in Fe-Cu Alloys Studied by Positron 2D-ACAR"Mat.Sci.Forum. 455-456. 380-384 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] E.Kuramoto: "Analysis of Stress Degradation of Metals by Positron Annihilation"Proc.Int.Conf.On Mat.Chem.In Nucl.Environment. MO-02. 71-76 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] E.Kuramoto, K.Ohsawa et al.: "Bias Mechanism and Its Effects for Fundamental Process of Irradiation Damage"Mat.Trans.JIM. 45. 34-39 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Deformation-Enhanced Cu Precipitation in Fe-Cu Alloy Studied by Positron Annihilation Spectroscopy"Phys. Rev. B. Vol.65. 012201-1-012204-4 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Irradiation-Enhanced Cu-Precipitation in Fe-Cu Alloys Studied by Positron Annihilation Spectroscopy and Electrical Resistivity Measurement"Mat. Sci. Forum. Vol.455-456. 168-170 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Chiba, E.Kuramoto et al.: "Electronic Structure of Nanosized bcc Cu Precipitates in Fe-Cu Alloys Studied by Positron 2D-ACAR"Mat. Sci. Forum. Vol.455-456. 380-384 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] E.Kuramoto: "Analysis of Stress Degradation of Metals by Positron Annihilation"Proc. Int. Conf. On Mat. Chem. In Nucl. Environment. MO-02. 71-76 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] E.Kuramoto, K.Ohsawa et al.: "Bias Mechanism and Its Effects for Fundamental Process of Irradiation Damage"Mat. Trans. JIM. 45. 34-39 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Deformation-Enhanced Cu Precipitation in Fe-Cu Alloy Studied by Positron Annihilation Spectroscopy"Phys.Rev.B. 65. 012204-1-012204-4 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Onitsuka, E.Kuramoto et al.: "Irradiation-Enhanced Cu-Precipitation in Fe-Cu Alloys Studied by Positron Annihilation Spectroscopy and Electrical Resistivity Measurement"Mat.Sci.Forum. 455-456. 168-170 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Chiba, E.Kuramoto et al.: "Electronic Structure of Nanosized bcc Cu Precipitates in Fe-Cu Alloys Studied by Positron 2D-ACAR"Mat.Sci.Forum. 455-456. 380-384 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] E.Kuramoto: "Analysis of Stress Degradation of Metals by Positron Annihilation"Proc.Int.Conf.On Mat.Chem.In Nucl.Environment. MO-02. 71-76 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] E.Kuramoto, K.Ohsawa et al.: "Bias Mechanism and Its Effects for Fundamental Process of Irradiation Damage"Mat.Trans.JIM. 45. 34-39 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 蔵元英一: "結晶中の照射欠陥の基礎的挙動とバイアス効果"日本物理学会誌. 58. 158-165 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Onitsuka, E.Kuramoto etc: "Deformation-Enhanced Cu Precipitation in Fe-Cu Alloy Studied by Positron Annihilation Spectroscopy"Phys.Rev.B. 65. 012204-1-012204-4 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] E.Kuramoto, K.Ohsawa, T.Tsutumi: "Computer Simulation of Fundamental Behaviors of Point Defects, Clusters and Interaction with Dislocations in Fe and Ni"Comp.Mod.Eng.Sci.. 3. 193-200 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] E Kuramoto, K.Ohsawa, T.Tsutsumi: "Study of Fundamental Features of Bias Effect in Metals under Irradiation"J.Nucl.Mat.. 307-311. 982-987 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Sato, T.Yoshiie, Y.Satoh, Q.Xu, E.Kuramoto, M.Kiritani: "Point Defect Production under High Internal Stress without Dislocations in Ni and Cu"Rad.Eff.Def.Sol.. 157. 171-178 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 蔵元英一: "結晶中の照射欠陥の基礎過程とバイアス効果"日本物理学会誌. 58. 158-165 (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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