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Construction and Characterization of Nano-structure based on acethylene macrocycles consisting of the fluorene units.

Research Project

Project/Area Number 14550827
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

TSUGE Akihiko  Kyushu Institute Of Technology, Department of Chemistry, Professor, 工学部, 教授 (80179986)

Co-Investigator(Kenkyū-buntansha) MORIGUCHI Tetsuji  Kyushu Institute Of Technology, Department of Chemistry, Research Associate, 工学研究科, 助手 (40243985)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 2003: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2002: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsFluorene / Macrocyclic compound / Host molecule / Nano-Structure
Research Abstract

Supramolecular chemistry which could produce novel functions by, combining small molecules using non-covalent bondings has always attracted a major interest. Macrocyclic compounds consisting of the acethylene units has the inner : cavity. Assembling these macrocyclic compounds, supramolecular structures such as a tube-like structure could be formed, which can be applied for host-guest chemistry and so forth. In this research we proposed the preparation of acethylene-type macrocyclic compounds based on the fluorene units instead of the benzene units and the examination of their aggregation behavior in order to explore the applications. We found out that some functional groups can be introduced into the 1-and 8-positions of the fluorene unit for the first time. Using 3,6-di-tert-butyl fluorene, chloromethylation was carried out under various conditions to give the 1,8-bis(chloromethyl)fluorene from which : the acethylene-type flourene was obtained in several steps. We have investigated various methods to prepare the desired acethylene-type macrocyclic compounds from the fluorene derivatives. As the result we could synthesize the acethylene-type macrocyclic compounds based on the fluorene units as the mixture which contains some analogous compound. We also introduce a long alkyl chain into the outer positions of the fluorene unit. Aggregation behavior of these macrocyclic compounds was investigated in terms of π-π. interaction, hydrogen-bondings and electrostatic interaction. The macrocyclic compounds having a long alkyl chain shows some phases in the solid state. Detail examination is now under way to clarify the liquid crystal properties of these compounds.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] A.Tsuge et al.: "Preparation and Molecular Arrangement of Novel Pyrenophanes"Chem.Lett.. 384-385 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Sakata et al.: "Synthesis and Reaction of Novel(Tetraaza[14]annulene)nicked(II) Complexes With Amino Groups in their Side Chains"J.Coord.Chem. 55. 225-239 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Tsuge et al.: "Preparation, Spectroscopic Properties and Characterization of Oxovanadium (IV) complexes with c Bis-crown Ether"J.Coord.Chem. 55. 1283-1291 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Sakata et al.: "Synthesis and Spectral Properties of Inn(II),Copper(I),Silver(I) and Palladium (II) Complexes of a Bidetate Diisonitriu"Synth.React.Inorg.Met.-Org.Chem.. 33. 11-22 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Tsuge et al.: "Preparation and Structural Properties of Novel Fluorenophanes"Chem.Lett.. 32. 776-777 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Tsuge: "Cyclophane Chemistry for the 21st Centry"Research Signport. 12-32 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Tsuge, A., Tanba, Y., Moriguchi, T., Sakata, K.: "Preparation and Molecular Arrangement of Novel Pyrenophanes."Chem.Lett.. 384-385 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Sakata, K., Shibata, H., Hashimoto, M., Tsuge, A.: "Synthesis and Reaction of Novel(teraaza-[14]annulene)nickel(II) Complexes with Amine Groups in their Side Chains."J.Coord.Chem.. 55. 225-239 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Tsuge, A.: "Weak interactions in cyclophane systems."Cyclophane Chemistry for the 21st Centry. 12-32 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Sakata, K., Miyamoto, Y., Hashimoto, M., Tsuge, A.: "Preparation, Spectroscopic Properties and Characterization of Oxovanadium(IV), Isothiocyanatomanganese(III), Cyano-cobalt(II) and Cobalt(II) Complexes with a Bis-crown Ether Tetraaza[14]annulene."J.Coord.Chem.. 55. 1283-1291 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Sakata, K., Urabe, K., Hashimoto, M., Yanagi, Y., Tsuge, A., Angelici, R.J.: "Synthesis and Spectral Properties of Iron(II), Copper(I), Silver(I), and Palladium(II) Complexes of a Bidentate Diisonitril."Synth.React.Inorg.Met.-Org.Chem.. 33. 11-22 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Tsuge, A., Nishimoto, H., Moriguchi, T., Sakata,.K.: "Preparation and Structural Properties of Novel Fluorenophanes."Chem.Lett.. 32. 776-777 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Tsuge, et al.: "Preparation and Molecular Arrangement of Novel Pyrenophanes"Chem.Lett.. 384-385 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Sakata, et al.: "Synthesis and Reaction of Novel (Tetraaza[14]annulen)nickel(II) complexes with Amino Groups in their Sids Chains"J.Coord.Chem.. 55. 225-239 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Tsuge, et al.: "The preparation, Spectroscopic properties and characterization of Oxovanadium(IV) complexes with a Bis-crown Ether"J.Coord.Chem.. 55. 1283-1291 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Sakata, et al.: "Synthesis and Spectral Properties of Iron(II), Copper(I), Silver(I), and Palladium(II) Complexes of a Bidentate Diisonitrile"Synth.React.Inorg.Met-Org.Chem.. 33. 11-22 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Tsuge, et al.: "Preparation and Structural Properties of Nord Fluorenophanes"Chem.Lett.. 32. 776-777 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Tsuge: "Cyclophane Chemistry for the 21st Century"Research Signpost. 12-32 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Tsuge, et al.: "Preparation and Molecular Arrangement of Novel Pyrenophanes"Chem. Lett.. 384-385 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Sakata, et al.: "Synthesis and Reaction of Novel (Tetraaza[14]annulene) nickel(II) Complexes with Amine Groups in their Side Chains"J. Coord. Chem.. 55. 225-239 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Tsuge, et al.: "Preparation, Spectrosapic Boperties and Characterization of Oxoranadium (IV) complexes with a Bis-crown Ether"J. Coord. Chem.. 55. 1283-1291 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Tsuge: "Cyclophane Chemistry for the 21st Centry"Research Signpost. 12-32 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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