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Supramolecular Film of Low Molecular Mass Molecule As Leucine-Zipped a-Sheet Assemblage

Research Project

Project/Area Number 14550831
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionChiba University

Principal Investigator

YAMADA Norihiro  Chiba University, Faculty of education, Associate Professor, 教育学部, 助教授 (40182547)

Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥4,200,000 (Direct Cost: ¥4,200,000)
Fiscal Year 2003: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2002: ¥3,100,000 (Direct Cost: ¥3,100,000)
KeywordsSupramolecular Film / Leucine Fastener / Hydrogen Bonding / β-sheet / Molding Press / Oligo-leucine / Peptide-containing Amphiphile / Flexible Film / 塑性加工 / 加圧成形 / ペプチド / 平行β-シート構浩 / ロイシンジッパー / フィルム形成 / FT-IRスペクトル / 両親媒性化合物 / 多重水素結合
Research Abstract

This work is the first report for the formation of a self-supporting elastic film without the use of macromolecular materials. We prepared the film using a peptide-containing amphiphile that possesses three or four consecutive leucinate residues. The amphiphile initially formed a b-sheet structure, which stacked by a fastener-like action between the side chains of leucine within the different β-sheets.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] 長谷川健: "Cartesian-structure Analysis in Cast Films by Advanced Infrared Multiple-angle Incidence Resolution Spectroscopy"Anal.Chem.. (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 山田哲弘: "Self-Supporting Elastic Film without Covalent Linkages As a Hierarchically Integrated β-Sheet Assemblage"Angew.Chem.Int.Ed.Engl.. 42. 5496-5499 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 中嶋直敏: "超分子科学"化学同人. 496 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Takeshi Hasegawa: "Cartesian-Structure Analysis in Cast Films by Advanced Infrared Multiple-Angle Incidence Resolution Spectroscopy"Anal.Chem.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Norihiro Yamada: "Self-supporting Elastic Film without Covalent Linkages As a Hierarchically Integrated β-Sheet Assemblage"Angew.Chem.Int.Ed.Engl.. 42,(No.44). 5496-5499 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 長谷川健: "A Novel Approach of Cartesian-Structure Analysis in Cast Films by Advanced Infrared Multiple-Angle Incidence Resolution Spectroscopy"Anal.Chem.. (印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 山田哲弘: "Self-supporting Elastic Film without Covalent Linkages As a Hierarchically Integrated β-Sheet Assemblage"Angew.Chem.Int.Ed.Engl.. 42(44). 5496-5499 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 中嶋直敏: "超分子科学"化学同人. 496 (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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