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Measurements of reduction cross sections of metal-oxides by atomic hydrogen

Research Project

Project/Area Number 14580529
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear fusion studies
Research InstitutionNational Institute for Fusion Science

Principal Investigator

SAGARA Akio  National Institute for Fusion Science, LHD project, Associate Professor, 大型ヘリカル研究部, 助教授 (20187058)

Co-Investigator(Kenkyū-buntansha) SUZUKI Akihiro  The University of Tokyo, Faculty of Engineering, Associate Professor, 工学部, 助教授 (80332188)
SUZUKI Hajime  Chubu University, College of Engineering, Associate Professor, 工学部, 助教授 (20260044)
KUBOTA Yusuke  National Institute for Fusion Science, LHD project, Associate Professor, 大型ヘリカル研究部, 助教授 (50023726)
Project Period (FY) 2002 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2003: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2002: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordsatomic hydrogen / reduction reaction / plasma-wall interaction / electron cyclotron resonance / dissociated hydrogen / micro-wave / discharge cleaning / chromium oxide
Research Abstract

The purpose of this research is to measure the reduction cross sections of metal oxides due to irradiation of atomic hydrogen. The results obtained in this study contribute to quantitative prediction and control of behaviors of oxygen impurities due to plasma-wall interactions.
This research has been accomplished with two steps. The first step is to develop a small size atomic-hydrogen source using electron-cyclotron resonance (ECR) plasma. The point in this stage is to newly develop a localized magnetic field for ECR, because the Auger surface analyzer (AES) used in this study is very sensitive to magnetization of the AES material itself. For this purpose, instead of large solenoid coils, a small-size permanent-magnet system has been newly developed, in which many requirements such as UHV and cooling are also optimized.
The second step is to evaluate the flux φ_H of atomic hydrogen by measuring plasma temperature and density. Then, using this atomic hydrogen flux, the time constant τ_d of metal-oxide reduction is measured with AES. From this time constant, the reduction cross section is evaluated as σ_d = 1/(τ_d φ_H).
Experimental results have shown that, in case of Ni, adsorbed oxygen is clearly reduced under the irradiation of atomic hydrogen. The reduction cross section σ_d is evaluated to be about 7x10^<-18> cm^2, which is in good agreement with the values so far estimated in discharge cleaning experiments for plasma-wall conditioning. On the other hand, in case of Cr, no clear reduction of oxygen has been observed. This result is not so different as expected from chemical equilibrium of chromium-oxide against atomic hydrogen. Increase of the flux φ_H is the technical main issue to be developed in future. These results have been mainly presented in plasma research conferences.

Report

(3 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] A.Sagara, et al.: "Helical divertor operation and erosion/deposition at target surfaces in LHD"Journal of Nuclear Materials. 313-316. 1-10 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hino et al.: "Analysis for surface probes of third experimental campaign in the large helical device"Journal of Nuclear Materials. 313-316. 169-173 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kubota et al.: "Investigation of the trapped helium and hydrogen ions in plasma facing materials for LHD using thermal desorption spectrometer and alternating glow discharge cleanings"Journal of Nuclear Materials. 313-316. 241-246 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Suzuki et al.: "Behavior of helium gas in the LHD vacuum chamber"Journal of Nuclear Materials. 313-316. 297-301 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Ohya, A.Sagara: "Dynamic Simulation of Erosion and Redeposition Patterns and Impurity Depth Profile of an LHD Divertor Plate"Journal of Plasma and Fusion Research. 78. 840-841 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hino et al.: "Material probe analysis for plasma facing surface in the Large Helical Device"Nuclear Fusion. 44. 496-502 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Sagara, et al.: "Helical divertor operation and erosion/deposition at target surfaces in LHD"Journal of Nuclear Materials. Vol.313-316. 1-10 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hino et al.: "Analysis for surface probes of third experimental campaign in the large helical device"Journal of Nuclear Materials. Vol.313-316. 169-173 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Kubota et al.: "Investigation of the trapped helium and hydrogen ions in plasma facing materials for LHD using thermal desorption spectrometer and alternating glow discharge cleanings"Journal of Nuclear Materials. Vol.313-316. 241-246 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Suzuki et al.: "Behavior of helium gas in the LHD vacuum chamber"Journal of Nuclear Materials. Vol.313-316. 297-301 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Ohya, A.Sagara: "Dynamic Simulation of Erosion and Redeposition Patterns and Impurity Depth Profile of an LHD Divertor Plate"Journal of Plasma and Fusion Research. Vol.78. 840-841 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T, Hino et al.: "Material probe analysis for plasma facing surface in the Large Helical Device"Nuclear Fusion. Vol.44. 496-502 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hino et al.: "Material probe analysis for plasma facing surface in the large helical device"Nuclear Fusion. Vol.44,No.4. 496-502 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Nishimura et al.: "Effects of Boronization in LHD"Journal of Plasma and Fusion Research. Vol.79,No.12. 1216-1217 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A Sagara, et al.: "Helical divertor operation and erosion/ deposition at target surfaces in LHD"Journal of Nuclear Materials. 313-316. 1-10 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Kubota et al.: "Investigation of the trapped helium and hydrogen ions in plasma facing materials for LHD using thermal desorption spectrometer and alternating glow discharge cleanings"Journal of Nuclear Materials. 313-316. 241-246 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Hino et al.: "Analysis for surface probes of third experimental campaign in the large helical device"Journal of Nuclear Materials. 313-316. 169-173 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Ohya, A.SagaTa: "Dynamic simulation of erosion and redeposition patterns and impurity depth profile of an LHD divertor plate"Journal of Plasma Fusion Research. Vol.78, No.9. 840-841 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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