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液晶性有機半導体を用いた高効率有機薄膜太陽電池の開発

Research Project

Project/Area Number 14F04051
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Research Field Electronic materials/Electric materials
Research InstitutionOsaka University

Principal Investigator

尾崎 雅則  大阪大学, 工学(系)研究科(研究院), 教授 (50204186)

Co-Investigator(Kenkyū-buntansha) DAO QUANG-DUY  大阪大学, 工学(系)研究科(研究院), 外国人特別研究員
DAO Quang-Duy  大阪大学, 工学(系)研究科(研究院), 外国人特別研究員
Project Period (FY) 2014-04-25 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2015: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2014: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsPhthalocyanine / Organic solar cell / Tandem solar cell / Liquid crystal / Organic semiconductor / Organic Solar cell / Processing additive
Outline of Annual Research Achievements

1. Effects of thermal-annealing and processing-additive treatment in organic solar cells (OSCs): Effects of thermal-annealing and processing-additive treatment on crystallization-induced phase separation and photovoltaic performance in bulk heterojunction (BHJ) OSCs utilizing non-peripherally substituted octapentyl tetrabenzotriazaporphyrin (C5TBTAPH2) mixed in 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)C71 (PCBM) were reported. By using either thermal-annealing or processing-additive treatment, the C5TBTAPH2-crystallite sizes in the BHJ films were enlarged and the power conversion efficiencies (PCEs) were increased due to improvement of the crystallization-induced phase separation. However, the optimum PCE of the processing-additive treated devices was higher than those PCE of devices treated by thermal annealing. These results were discussed by taking the thermal properties and molecular aggregation of PCBM into consideration.
2. All-solution processalbe tandem cell using mesogenic phthalocyanine: The photovoltaic performance of BHJ OSCs using C6TBTAPH2 limits due to the weak absorption at around 500 nm. I have fabricated the tandem solar cell with all-solution processed multilayer structure utilizing a conventional structure composed of C6TBTAPH2 and poly(3-hexylthiophene) (P3HT). The P3HT single cell give a maximum the external quantum efficiency at 500 nm, and the C6TBTAPH2 single cell has two predominant peaks at 720 and 350 nm. The tandem solar cells with stacking of the two composite thin films cover the all visible spectral range and the PCE of 3.2% was achieved.

Research Progress Status

27年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

27年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (13 results)

All 2016 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Fabrication of tandem solar cells with all-solution processed multilayer structure using non-peripherally substituted octahexyl tetrabenzotriazaporphyrins2016

    • Author(s)
      Quang Duy Dao
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 3S2 Pages: 03DB01-03DB01

    • DOI

      10.7567/jjap.55.03db01

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of thermal-annealing and processing-additive treatment on crystallization-induced phase separation in organic solar cells utilizing octapentyl tetrabenzotriazaporphyrins2015

    • Author(s)
      Quang Duy Dao
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 48 Issue: 38 Pages: 385103-385103

    • DOI

      10.1088/0022-3727/48/38/385103

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Liquid crystalline and charge transport properties of novel non-peripherally octasubstituted perfluoroalkylated phthalocyanines2015

    • Author(s)
      Lydia Sosa-Vargas, Fabien Nekelson, Daiju Okuda, Minokazu Takahashi, Yukimasa Matsuda, Quang-Duy Dao, Yoshida Hiroyuki, Akihiko Fujii, Masanori Ozaki and Yo Shimizu.
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 8 Pages: 1757-1765

    • DOI

      10.1039/c4tc02557a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficiency enhancement in solution processed small-molecule based organic solar cells utilizing various phthalocyanine-tetrabenzoporphyrin hybrid macrocycles2015

    • Author(s)
      Quang-Duy Dao, Lydia Sosa-Vargas, Takuya Higashi, Masashi Ohmori, Hiromichi Itani, Akihiko Fujii, Yo Shimizu, and Masanori Ozaki
    • Journal Title

      Organic Electronic

      Volume: 23 Pages: 44-52

    • DOI

      10.1016/j.orgel.2015.04.009

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Octahexyltetrabenzotriazaporphyrin: A Discotic Liquid Crystalline Donor for High-performance Small-molecule Solar Cells2014

    • Author(s)
      Quang-Duy Dao, Koichi Watanabe, Hiromichi Itani, Lydia Sosa-Vargas, Akihiko Fujii, Yo Shimizu and Masanori Ozaki
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 11 Pages: 1761-1763

    • DOI

      10.1246/cl.140685

    • NAID

      130004703959

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Effects of thermal-annealing and processing-additive treatment on crystallization-induced phase separation in organic solar cells utilizing octapentyl tetrabenzotriazaporphyrins2015

    • Author(s)
      Q.-D. Dao, T. Uno, M. Ohmori, K. Watanabe, Hiromichi Itani, Akihiko Fujii, Yo Shimizu, and Masanori Ozaki
    • Organizer
      (第76回)応用物理学会秋季学術講演会
    • Place of Presentation
      Nagoya Congress center, Japan
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] A study on high-efficiency organic solar cells using hybrid phthalocyanine-tetrabenzoporphyrin macrocycles2015

    • Author(s)
      Quang-Duy Dao, Akihiko Fujii, Yo Shimizu, and Masanori Ozaki
    • Organizer
      The Seventh East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2015-09-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Efficiency enhancement of phthalocyanine based solution processable organic solar cell by controlling numbers of aza links at meso-position2015

    • Author(s)
      Quang-Duy Dao, Koichi Watanabe, Masashi Ohmori, Hiromichi Itani, Lydia Sosa-Vargas, Akihiko Fujii, Yo Shimizu, and Masanori Ozaki
    • Organizer
      12th International Symposium on Functional π- electron Systems
    • Place of Presentation
      Seattle, USA
    • Year and Date
      2015-07-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Small molecule tandem solar cell using all-solution process2015

    • Author(s)
      Quang-Duy Dao, Akihiko Fujii, Yo Shimizu, and Masanori Ozaki
    • Organizer
      8th international conference on molecular electronics and bioelectronics
    • Place of Presentation
      Tower Hall Funabori, Tokyo, Japan
    • Year and Date
      2015-06-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-efficiency bulk heterojunction organic solar cell utilizing various hybrid phthalocyanine-tetrabenzopophyrin macrocycles2014

    • Author(s)
      Quang-Duy Dao, Koichi Watanabe, Masashi Ohmori, Hiromichi Itani, Lydia Sosa-Vargas, Akihiko Fujii, Masanori Ozaki and Yo Shimizu.
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, Massachusetts, US
    • Year and Date
      2014-12-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Optical, electronic, and photovoltaic properties of octahexyl tetrabenzotriazaporphyrin2014

    • Author(s)
      Quang-Duy Dao, Koichi Watanabe, Hiromichi Itani, Lydia Sosa-Vargas, Akihiko Fujii, Masanori Ozaki and Yo Shimizu.
    • Organizer
      (第75回)応用物理学会秋季学術講演会
    • Place of Presentation
      Hokaido, Japan
    • Year and Date
      2014-09-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] A study on high-efficiency octahexylphthlocyanine-based organic solar cells using processing additives2014

    • Author(s)
      Quang-Duy Dao, Akihiko Fujii, Yo Shimizu and Masanori Ozaki
    • Organizer
      ICSM 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-07-01
    • Related Report
      2014 Annual Research Report
  • [Remarks] 大阪大学大学院工学研究科電気電子情報工学専攻尾崎研究室

    • URL

      http://opal.eei.eng.osaka-u.ac.jp/httpdocs/

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-01-22   Modified: 2024-03-26  

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