| Project/Area Number |
14J00061
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 国内 |
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| Research Field |
Composite materials/Surface and interface engineering
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| Research Institution | Hokkaido University |
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Principal Investigator |
李 俊燮 北海道大学, 総合化学院, 特別研究員(DC2)
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|---|
| Project Period (FY) |
2014-04-25 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2015: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2014: ¥900,000 (Direct Cost: ¥900,000)
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| Keywords | hydrogen sulfide / stainless steel / sulfide / microelectrode / electrochemistry / sulfidation |
|---|
| Outline of Annual Research Achievements |
The effect of hydrogen sulfide ions (HS－) on the passivity of type 316L stainless steel was investigated in pH 8.4 boric acid-borate buffer solution. Galvanostatic polarization of a silver microelectrode covered with Ag2S generated both OH－ and HS－ above the stainless steel surface. During potentiostatic polarization of the stainless steel, the passivity-maintaining current density increased with increase in the concentration of HS－ in the vicinity of the surface. The impedance of the stainless steel at a constant frequency decreased during polarization in the presence of HS－, while it was sustained after dilution of HS－. Electrochemical impedance spectroscopy (EIS), Mott-Schottky (M-S) analysis and scanning electrochemical microscopy (SECM) showed that a defective and n-type semiconductive passive film was formed in the solution containing HS－. Auger electron spectroscopy (AES) revealed that metal cations and oxygen vacancies in the passive film on the stainless steel increased when it was formed in a HS－-containing solution. The series of changes in passive film properties is thought to be due to adsorption of HS－ on the film surface during the polarization.
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| Research Progress Status |
27年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
27年度が最終年度であるため、記入しない。
|
