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有機強誘電体/シリコン系希薄磁性半導体へテロ接合における電界効果スピン制御

Research Project

Project/Area Number 14J11716
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Structural/Functional materials
Research InstitutionOsaka Prefecture University

Principal Investigator

宮田 祐輔  大阪府立大学, 工学研究科, 特別研究員(DC1)

Project Period (FY) 2014-04-25 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2016: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2015: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2014: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywords希薄磁性半導体 / シリコン / 希土類元素 / 分子線エピタキシ法 / 電界効果トランジスタ / 有機強誘電体 / 磁気伝導特性 / 磁性半導体素子 / ドーピング
Outline of Annual Research Achievements

本研究では、Ceを添加したSiエピタキシャル(Si:Ce)薄膜における磁気物性の発現に注目している。これまで、低温分子線エピタキシ成長によって、数%ものCeを含むSi:Ce薄膜の作製に成功し、Ceの固溶状態と相関のある特異な磁気伝導特性を示すことを明らかにしてきた。本年度は、Bの共添加法や電界効果によるキャリア制御を試み、スピン-キャリア相互作用を起源とする負の磁気抵抗効果(MR)や異常Hall効果の発現および制御を目指した。
Si:Ce薄膜は低温成長に伴うドナー性欠陥によりn型の伝導特性を示すため、キャリア制御を目的としたBの共添加及び、電界効果素子の作製を行った。半導体的な伝導特性を示すp型のSi:0.6at.%Ce,Bにおいて、20K以下の低温で3.0%程度の負のMRを明瞭に観測した。フィッティングによる解析や光電子分光法を用いたCeの価数評価の結果から、4f軌道に1つの孤立電子スピンを有するCe3+の局在磁気モーメントが、外部磁場によって秩序することで系の抵抗率を下げることを見出した。また本試料は明瞭な異常Hall効果も発現している。伝導キャリアが及ぼすMRや異常Hall効果の影響を明らかにするために、3倍周期の再構成表面を有するSi:0.6at.%Ceをチャネル層に用いた電界効果素子を作製した。ゲート電圧印加によって負のMR、異常Hall効果を制御することに成功した。蓄積・空乏・反転層の形成を示唆するドレイン電流や静電容量の増減を観測していることから、強誘電体の分極操作によってSi:Ceのキャリア密度が変化し、負のMRや異常Hall効果の発現に影響を及ぼしているものと考えられる。
上記のような、希土類元素を添加したSi薄膜におけるMRや異常Hall効果の電界制御に関する報告はこれまでに無く、半導体スピントロニクス分野における極めて重要な成果と考えられる。

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (23 results)

All 2017 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (19 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Cerium ion doping into self-assembled Ge using three-dimensional dot structure2017

    • Author(s)
      Yusuke Miyata, Kazuya Ueno, Takeshi Yoshimura, Atsushi Ashida and Norifumi Fujimura
    • Journal Title

      Journal of Crystal Growth

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Large enhancement of positive magnetoresistance by Ce doping in Si epitaxial thin films2016

    • Author(s)
      Yusuke Miyata, Kazuya Ueno, Yoshihiko Togawa, Takeshi Yoshimura, Atsushi Ashida and Norifumi Fujimura
    • Journal Title

      Applied Physics Letters

      Volume: 109 Pages: 112101-112101

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-voltage operation of Si-based ferroelectric field effect transistors using organic ferroelectrics, poly(vinylidene fluoride-trifluoroethylene), as a gate dielectric2015

    • Author(s)
      Yusuke Miyata, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 425

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of the electronic states in highly Ce doped Si films grown by low temperature molecular beam epitaxy system2015

    • Author(s)
      Yusuke Miyata, Yukinori Nose, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura
    • Journal Title

      Journal of Crystal Growth

      Volume: 印刷中 Pages: 158-161

    • DOI

      10.1016/j.jcrysgro.2015.03.013

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Field effect control of magneto-transport in Si epitaxial films doped with Ce by novel doping method using surface reconstruction2017

    • Author(s)
      Yusuke Miyata, Hayato Nonami, Daisuke Kiriya, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Spin-related magneto-transport in semiconducting Ce doped p-type Si epitaxial films2016

    • Author(s)
      Yusuke Miyata, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Rare earth ion doping in Ge deposited by molecular beam epitaxy2016

    • Author(s)
      Yusuke Miyata, Kazuya Ueno, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carrier control in Ce doped Si thin films using organic ferroelectric-gate field effect transistors2016

    • Author(s)
      Hayato Nonami, Yusuke Miyata, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      35th Electronic Materials Symposium
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Rare earth ion doping in Ge deposited by molecular beam epitaxy2016

    • Author(s)
      Yusuke Miyata, Hayato Nonami, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      35th Electronic Materials Symposium
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effect of carrier on magneto-transport characteristics of Ce doped Si films2016

    • Author(s)
      Yusuke Miyata, Hayato Nonami, Takeshi Yoshimura, Atsushi. Ashida and Norifumi Fujimura
    • Organizer
      35th Electronic Materials Symposium
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electronic states of Ce and magneto-transport characteristics in Ce doped Si films2016

    • Author(s)
      Yusuke Miyata, Kazuya Ueno, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura
    • Organizer
      2016年<第63回>応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Anomalous Magnetoresistance in Rare Earth, Ce, Doped Single Crystalline Si Epitaxial Films2015

    • Author(s)
      M. Yusuke, K. Ueno, A. Ashida, Y. Togawa, N. Fujimura
    • Organizer
      31st North American Molecular Beam Epitaxy Conference
    • Place of Presentation
      The IBEROSTAR Paraíso Beach Hotel, Mayan Riviera Mexico
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Si-based Nonvolatile Field Effect Transistor using Low Temperature Process2015

    • Author(s)
      Y. Miyata, A. Ashida, T. Yoshimura and N. Fujimura
    • Organizer
      The 2015 International Conference on Solid State Device and Materials
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of hole density in acceptor co-doped Si:Ce films2015

    • Author(s)
      Yusuke Miyata, Kazuya Ueno, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura
    • Organizer
      2015年<第76回>応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Novel rare earth doping using surface re-construction of Ce doped Si films2015

    • Author(s)
      Y. Miyata, K. ueno, T. Yoshimura, A. Ashida and N. Fujimura
    • Organizer
      34st Electronic Materials Symposium
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2015-07-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Transport characteristics of B co-doped Si:Ce films2015

    • Author(s)
      Y. Miyata, K. ueno, T. Yoshimura, A. Ashida and N. Fujimura
    • Organizer
      34st Electronic Materials Symposium
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2015-07-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] The effect of B doping on the surface morphology and transport characteristics of Si:Ce films2015

    • Author(s)
      Yusuke Miyata, Ueno Kazuya, Takeshi Yoshimura, Atsushi Ashida, Norifumi Fujimura
    • Organizer
      2015年第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県平塚市
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Si-based non-volatile FET using Organic Ferroelectrics2015

    • Author(s)
      宮田 祐輔、藤村 紀文
    • Organizer
      応用物理学会 界面ナノ電子化学研究会 第1回ポスター発表展
    • Place of Presentation
      神奈川県厚木市
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機強誘電体P(VDF-TrFE)を用いたCe添加Si薄膜の伝導制御2014

    • Author(s)
      宮田 祐輔、植野 和也、吉村 武、芦田 淳、藤村 紀文
    • Organizer
      2014年 第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Transport Properties of Highly Ce Doped Si Films Grown by Low-temperature Molecular Beam Epitaxy2014

    • Author(s)
      Y. Miyata, N. Fujimura
    • Organizer
      18th International Conference on Molecular Beam Epitaxy
    • Place of Presentation
      Flagstaff, Arizona, USA
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrical Characteristics of Non-volatile Silicon Thin Film Transistors Using Organic Ferroelectrics2014

    • Author(s)
      Yusuke Miyata, Takeshi Yoshimura, Atsushi Ashida and Norifumi Fujimura
    • Organizer
      The 10th Japan-Korea Conference on Ferroelectrics
    • Place of Presentation
      広島県広島市
    • Year and Date
      2014-08-17 – 2014-08-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 再構成表面を利用した新規な希土類元素ドーピング2014

    • Author(s)
      宮田 祐輔、植野 和也、藤村 紀文
    • Organizer
      平成26年度第2回半導体エレクトロニクス部門委員会第1回研究会
    • Place of Presentation
      大阪府吹田市
    • Year and Date
      2014-07-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Transport properties of highly Ce doped Si films grown by low-temperature molecular beam epitaxy2014

    • Author(s)
      Yusuke Miyata and Norifumi Fujimura
    • Organizer
      33rd Electronic Materials Symposium
    • Place of Presentation
      静岡県伊豆市
    • Year and Date
      2014-07-09 – 2014-07-11
    • Related Report
      2014 Annual Research Report

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Published: 2015-01-22   Modified: 2024-03-26  

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