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非食性バイオマスからの化成品生産に向けた固体触媒グリーンエンジニアリングの構築

Research Project

Project/Area Number 14J12396
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Catalyst/Resource chemical process
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

CHOUDHARY HEMANT (2015)  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)

CHOUDHARY Hemant (2014)  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)

Project Period (FY) 2014-04-25 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2015: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2014: ¥1,000,000 (Direct Cost: ¥1,000,000)
KeywordsBiomass / Metal Organic Framework / Heterogeneous Catalyst / Organic transformation / Acid Catalyst / Proton Conductivity / Organic Transformation
Outline of Annual Research Achievements

In the event of engineering greener methodologies for converting inedible-biomass into commodity chemicals over heterogeneous catalysts, various heterogeneous catalysts were developed. The preparation of metal-organic framework (MOF) based acid catalyst were successfully achieved through post-synthetic modification methodology. The prepared catalyst possessed acidic properties and catalytic activity for esterification and hydrolysis reaction comparable to the commercially known acid catalysts such as Amberlyst-15 and Nafions. In addition to the catalysis, the prepared acidic materials had potential for applications in fuel cells with high proton conductivity.
The research also proposed the functionalization of MOFs to afford not only acid catalysts but also to immobilize metals like palladium (Pd) through amine functionalization. The successful incorporation of amine functionality was achieved through ligand design methodology and Pd was grafted on such material to afford a potent heterogeneous catalyst. Such catalyst demonstrated remarkable stability and catalytic performances for Mizoroki-Heck reaction. Surfactant-treated and/or stabilized monometallic and bimetallic nanoparticle based catalysts were also developed for various selective transformations including hydrogenation of olefins, oxidation of diols and cross-coupling reaction of aryl chloride.

Research Progress Status

27年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

27年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (15 results)

All 2016 2015 2014

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (8 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Hydrotalcite-supported PdPt-catalyzed aerobic oxidation of 5-hydroxymethylfurfural to 2,5- furandicarboxylic acid in water2016

    • Author(s)
      Hemant Choudhary, Kohki Ebitani
    • Journal Title

      Chemistry Letters

      Volume: in press Issue: 6 Pages: 613-615

    • DOI

      10.1246/cl.160178

    • NAID

      130005155030

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A convenient surfactant-mediated hydrothermal approach to control supported copper oxide species for catalytic upgrading of glucose to lactic acid2015

    • Author(s)
      Hemant Choudhary, Kohki Ebitani
    • Journal Title

      ChemNanoMat

      Volume: 1 Issue: 7 Pages: 511-516

    • DOI

      10.1002/cnma.201500131

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal preparation of a robust boehmite-supported N,N-dimethyldodecylamine N-oxide-capped cobalt and palladium catalyst for the facile utilization of formic acid as a hydrogen source2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Journal Title

      ChemCatChem

      Volume: 7 Issue: 15 Pages: 2361-2369

    • DOI

      10.1002/cctc.201500161

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Formic Acid from Monosaccharides using Calcined Mg-Al Hydrotalcite as Reusable Catalyst in the Presence of Aqueous Hydrogen Peroxide2015

    • Author(s)
      Ryo Sato, Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Journal Title

      Organic Process Research & Development

      Volume: 19 Issue: 3 Pages: 449-453

    • DOI

      10.1021/op5004083

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of high-value organic acids from sugars promoted by hydrothermally loaded Cu oxide species on magnesia2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 162 Pages: 1-10

    • DOI

      10.1016/j.apcatb.2014.05.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Tailored design of palladium species grafted on an amino functionalized organozinc coordination polymer as a highly pertinent heterogeneous catalyst2014

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Issue: 43 Pages: 18687-18696

    • DOI

      10.1039/c4ta03889d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Sustainable catalytic conversions: Production of organic acids from inedible-biomass resources over heterogeneous catalysts2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, Hawaii, United States of America
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis, characterization and catalytic applications of functionalized porous coordination polymers2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, Hawaii, United States of America
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Capped Co-promoted Pd/AlOOH catalyst in dehydrogenation of formic acid for hydrogenation of maleic anhydride2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      XII European Congress on Catalysis (EuropaCat-XII)
    • Place of Presentation
      Korston Hotel, Kazan, Russia
    • Year and Date
      2015-08-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] A robust palladium species grafted on amino-functionalized organozinc coordination polymer for efficient Suzuki-Miyaura coupling reaction in open air2015

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      7th International Conference on Green and Sustainable Chemistry and 4th JACI/GSC Symposium
    • Place of Presentation
      Hitotsubashi Hall, Tokyo, Japan
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Highly efficient and reusable heterogeneous copper catalyst for the synthesis of value-added organic acids from inedible biomass2014

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      4th International Solvothermal and Hydrothermal Association Conference (ISHA2014)
    • Place of Presentation
      ENSEIRB Talence, Bordeaux, France
    • Year and Date
      2014-10-26 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Highly-active porous coordination polymer-supported palladium catalyst2014

    • Author(s)
      Shun Nishimura, Hemant Choudhary, Kohki Ebitani
    • Organizer
      The 44th Petroleum-Petrochemical Symposium of JPI
    • Place of Presentation
      Asahikawa Grand Hotel, Asahikawa, Hokkaido, Japan
    • Year and Date
      2014-10-16 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Catalytic synthesis of organic acids for energy and plastics with biomass resources2014

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      JAIST Japan-India Symposium on Automotive Technologies (Energy, Fuel and Plastics)
    • Place of Presentation
      JAIST (Japan Advanced Institute of Science and Technology), Nomi, Ishikawa, Japan
    • Year and Date
      2014-08-04 – 2014-08-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Palladium-decorated amino-functionalized organozinc composites as stable and highly-active heterogeneous catalyst for Suzuki-Miyaura coupling2014

    • Author(s)
      Hemant Choudhary, Shun Nishimura, Kohki Ebitani
    • Organizer
      The Seventh Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT7)
    • Place of Presentation
      Kyoto TERRSA, Kyoto, Japan
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] Metal-supported porous coordination polymer catalyst2015

    • Inventor(s)
      Nishimura, Ebitani, Choudhary
    • Industrial Property Rights Holder
      JAIST
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-05-01
    • Related Report
      2015 Annual Research Report
    • Overseas

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Published: 2015-01-22   Modified: 2024-03-26  

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