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Device Process for Integrated Systems Composed of Dislocation-Free III-V-N Alloys and Silicon

Research Project

Project/Area Number 15002007
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Engineering
Research InstitutionToyohashi University of Technology

Principal Investigator

YONEZU Hiroo  Toyohashi University of Technology, Dept. of Electrical and Electronic Engineering, Professor, 工学部, 教授 (90191668)

Co-Investigator(Kenkyū-buntansha) WAKAHARA Akihiro  Toyohashi University of Technology, Dept. of Electrical and Electronic Engineering, Professor, 工学部, 教授 (00230912)
FURUKAWA Yuzo  Toyohashi University of Technology, Dept. of Electrical and Electronic Engineering, Research Associate, 工学部, 助手 (20324486)
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥313,300,000 (Direct Cost: ¥241,000,000、Indirect Cost: ¥72,300,000)
Fiscal Year 2005: ¥45,500,000 (Direct Cost: ¥35,000,000、Indirect Cost: ¥10,500,000)
Fiscal Year 2004: ¥128,700,000 (Direct Cost: ¥99,000,000、Indirect Cost: ¥29,700,000)
Fiscal Year 2003: ¥139,100,000 (Direct Cost: ¥107,000,000、Indirect Cost: ¥32,100,000)
KeywordsIII-V-N alloy / point defect / InGaPN / electric conductivity control / device process / MOS FET / light emitting diode / optoelectronic integrated system / III-V-N混晶 / GaPN / 格子整合 / 発光効率 / 格子間原子 / GaPNダブルヘテロ構造LED / 光-電子融合シスデム / 光学定数 / 伝導度制御 / Si-III-V-N融合システム / Si-GaPN / GaP LED / 超並列集積回路
Research Abstract

Basic process technologies have been developed for realizing novel optoelectronic integrated systems in a single chip, in which optical devices and electronic circuits were combined. These technologies were based on the dislocation-free heteroepitaxy of Si and III-V-N alloys.
We have investigated point defects originated in N atoms in the III-V-N alloys and optical and electronic properties related to the defects. The defects were decreased by rapid thermal annealing and by suppressing the irradiation of N ions generated in an rf-plasma source. The effects led to the increase in photoluminescence intensity and the reduction of Ga interstitials. In addition, InGaPN layers with direct transition were successfully grown. It was clarified that the defects cause poor electronic conductivity. N-and p-type electronic conductivities were controlled by S and Mg doping, respectively.
Si and III-V-N alloys were mutually impurities. Contamination during epitaxy was suppressed by applying a two-chamber molecular beam epitaxy system which was developed in this project. Process conditions for both devices of a Si MOS FET and a III-V-N alloy light emitting diode (LED) were optimized. Mutual diffusion between the Si and III-V-N alloy layers was suppressed by decreasing the growth temperature of a gate oxide. As a result, it became apparent that the novel optoelectronic integrated systems could be fabricated by applying a process flow followed to that of MOS integrated circuits.
The composite layer of Si/III-V-N alloy double heterostructure (DH) layers was grown on a Si substrate. Elemental devices for the integrated systems, MOS FETs and LEDs, were fabricated in the topmost Si layer and the III-V-N alloy DH layer, respectively by applying the process flow for the first time. The optical output of the LED was controlled by the MOS FET. These results mean that the basic device process technologies were developed for the novel integrated systems such as ultra-parallel networks and others.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (40 results)

All 2006 2005 2004 2001 Other

All Journal Article (30 results) Book (3 results) Patent(Industrial Property Rights) (1 results) Publications (6 results)

  • [Journal Article] Electrical Properties of n-type GaPN Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      Y.Furukawa, H.Yonezu, A.Wakahara, Y.Yoshizumi, Y.Morita, A.Sato
    • Journal Title

      Applied Physics Letters Vol. 88,No. 14

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Nitrogen Ion Bombardment on Defect Formation and Luminescence Efficiency of GaNP Epilayers Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      D.Dagnelund, I.A.Buyanova, T.Mchedlidze, W.M.Chen, A.Utsumi, Y.Furukawa, A.Wakahara, H.Yonezu
    • Journal Title

      Applied Physics Letters Vol. 88,No. 10

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electrical Properties of n-type GaPN Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      Y.Furukawa, H.Yonezu, A.Wakahara, Y.Yoshizumi, Y.Morita, A.Sato
    • Journal Title

      Applied Physics Letters Vol. 88, No. 14

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Nitrogen Ion Bombardment on Defect Formation and Luminescence Efficiency of GaNP Epilayers Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      D.Dagnelund, I.A.Buyanova, T.Mchedlidze, W.M.Chen, A.Utsumi, Y.Furukawa, A.Wakahara, H.Yonezu
    • Journal Title

      Applied Physics Letters Vol. 88, No. 10

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Electrical Properties of n-type GaPN Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      Y.Furukawa, H.Yonezu, A.Wakahara Y.Yoshizumi, Y.Morita, A.Sato
    • Journal Title

      Applied Physics Letters (to be published)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Analog Integrated Circuit for Edge Detection with Wide Dynamic Range Based on Vertebrate Outer Retina2006

    • Author(s)
      S.Sawa, K.Nishio, Y.Furukawa, H.Yonezu, J.-K.Shin
    • Journal Title

      Intelligent Automation and Soft Computing Vol.11(to be published)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Growth of Low-Dislocation-Density AlN under Ga Irradiation2006

    • Author(s)
      A.Nakajima, Y.Furukawa, H.Yokoya, S.Yamaguchi, H.Yonezu
    • Journal Title

      Japanese Journal of Applied Physics Vol.45,No.4A(to be published)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of Nitrogen Ion Bombardment on Defect Formation and Luminescence Efficiency of GaNP Epilayers Grown by Molecular-Beam Epitaxy2006

    • Author(s)
      U.Dagnelund, I.A.Buyanova, T.Mchedlidze, W.M.Chen, A.Utsumi, Y.Furukawa, A.Wakahara, H.Yonezu
    • Journal Title

      Applied Physics Letters Vol.88,No.10

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Analog Integrated Circuit for Detection of an Approaching Object with Simple-Shape Recognition Based on Lower Animal Vision2006

    • Author(s)
      K.Nishio, H.Yonezu, Y.Furukawa
    • Journal Title

      IEICE Transactions on Fundamentals of Electronics, Communications and Computer Sciences Vol.E89-A, No.2

      Pages: 416-427

    • NAID

      110004656487

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Point Defects in Dilute Nitride III-N-As and III-N-P2006

    • Author(s)
      W.M.Chen, I.A.Buyanova, C.W.Tu, H.Yonezu
    • Journal Title

      Physica B Vol.376-377

      Pages: 545-551

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of Indium on Photoluminescence Properties of InGaPN Layers Grown by Solid Source Molecular Beam Epitaxy2005

    • Author(s)
      S.M.Kim, Y.Furukawa, H.Yonezu, K.Umeno, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol. 44,No. 12

      Pages: 8309-8313

    • NAID

      10016958323

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dislocation-Free In_xGa_<1-x>P_<1-y>N_y/GaP_<1-z>N_z Double-Heterostructure Light Emitting Diode on Si Substrate2005

    • Author(s)
      S.Y.Moon, H.Yonezu, Y.Furukawa, S.M.Kim, Y.Morita, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol. 44,No. 4A

      Pages: 1752-1755

    • NAID

      10015470221

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Elemental Devices, Circuits and Processes for a Monolithic Si/III-V-N Alloy OEIC2005

    • Author(s)
      H.Yonezu, Y.Furukawa, H.Abe, Y.Yoshikawa, S.-Y.Moon, A.Utsumi, Y.Yoshizumi, A.Wakahara, M.Ohtani
    • Journal Title

      Optical Materials Vol. 27

      Pages: 799-803

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Indium on Photoluminescence Properties of InGaPN Layers Grown by Solid Source Molecular Beam Epitaxy2005

    • Author(s)
      S.M.Kim, Y.Furukawa, H.Yonezu, K.Umeno, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol. 44, No. 12

      Pages: 8309-8313

    • NAID

      10016958323

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Dislocation-Free InxGa1-xP1-yNy/GaP1-zNz Double-Heterostructure Light Emitting Diode on Si Substrate2005

    • Author(s)
      S.Y.Moon, H.Yonezu, Y.Furukawa, S.M.Kim, Y.Morita, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol. 44, No. 4A

      Pages: 1752-1755

    • NAID

      130004533576

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Indium on Photoluminescence Properties of InGaPN Layers Grown by Solid Source Molecular Beam Epitaxy2005

    • Author(s)
      S.M.Kim, Y.Furukawa, H.Yonezu, K.Umeno, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol.44,No.12

      Pages: 8309-8313

    • NAID

      10016958323

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Analog Integrated Circuit for Edge Detection with Massively Parallel Processing Based on Vertebrate Outer Retina2005

    • Author(s)
      Y.Furukawa, H.Yonezu, S.Sawa, K.Nishio, J.-K.Shin
    • Journal Title

      Sensors and Materials Vol.17,No.5

      Pages: 299-306

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Step Control of Vicinal 6H-SiC(0001) Surface by H_2 Etching2005

    • Author(s)
      A.Nakajima, H.Yokoya, Y.Furukawa, H.Yonezu
    • Journal Title

      Journal of Applied Physics Vol.97

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Growth of B_xAl_<1-x>N Layers Using Decaborane on SiC Substrates2005

    • Author(s)
      A.Nakajima, Y.Furukawa, H.Yokoya, H.Yonezu
    • Journal Title

      Journal of Crystal Growth Vol.278

      Pages: 437-442

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dislocation- Free In_xGa_<1-x>P_<1-y>N_y/GaP_<1-z>N_z Double -Heterostructure Light Emitting Diode on Si Substrate2005

    • Author(s)
      S.Y.Moon, H.Yonezu, Y.Furukawa, S.M.Kim, Y.Morita, A.Wakahara
    • Journal Title

      Japanese Journal of Applied Physics Vol.44,No.4A

      Pages: 1752-1755

    • NAID

      10015470221

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Properties of Ga-Interstitial Defects in Al_xGa_<1-x>N_yP_<1-y>2005

    • Author(s)
      N.Q.Thinh, I.P.Vorona, I.A.Buyanova, W.M.Chen, Sukit Limpijumnong, S.B.Zhang, Y.G.Hong, H.P.Xin, C.W.Tu, A.Utsumi, Y.Furukawa, S.Moon, A.Wakahara, H.Yonezu
    • Journal Title

      Physical Review B Vol.71,No.12

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effects of Rapid Thermal Annealing on Optical Properties of GaN_xP_<1-x> Alloys Grown by Solid Source Molecular Beam Epitaxy2005

    • Author(s)
      M.Izadifard, I.A.Buyanova, J.P.Bergman, W.M.Chen, A.Utsumi, Y.Furukawa, A.Wakahara, H.Yonezu
    • Journal Title

      Semiconductor Science and Technology Vol.20

      Pages: 353-356

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Defects in Dilute Nitrides2005

    • Author(s)
      W.M.Chen, I.A.Buyanova, C.W.Tu, H.Yonezu
    • Journal Title

      Acta Physica Polonica A Vol.108,No.4

      Pages: 571-579

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Improvement of Crystalline Quality of GaPN Layers Grown by RF-MBE with Ion Collector2005

    • Author(s)
      A.Utsumi, Y.Furukawa, H.Yonezu, Y.Yoshizumi, Y.Morita, A.Wakahara
    • Journal Title

      Phys.Stat.Sol.(a) Vol.202, No.5

      Pages: 758-762

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Optical Properties of Lattice Matched InxGa1-xP1-yNy Heteroepitaxial Layers on GaP2005

    • Author(s)
      T.Imanishi, A.Wakahara, S.-M.Kim, H.Yonezu, Y.Furukawa
    • Journal Title

      Phys.Stat.Sol.(a) Vol.202, No.5

      Pages: 854-858

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Elemental Devices, Circuits and Processes for a Monolithic Si/III-V-N Alloy OEIC2005

    • Author(s)
      H.Yonezu, Y.Furukawa, H.Abe, Y.Yoshikawa, S.-Y.Moon, A.Utsumi, Y.Yoshizumi, A.Wakahara, M.Ohtani
    • Journal Title

      Optical Materials Vol.27

      Pages: 799-803

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Growth of High-Quality A1N with Low Pit Density on SiC Substrates2004

    • Author(s)
      A.Nakajima, Y.Furukawa, S.Koga, H.Yonezu
    • Journal Title

      Journal of Crystal Growth Vol. 265

      Pages: 351-356

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] GaPN-GaP Double Heterostructure Light Emitting Diode Grown on GaP Substrate by Solid-Source Molecular Beam Epitaxy2004

    • Author(s)
      S.Y.Moon, A.Utsumi, H.Yonezu, Y.Furukawa, T.Ikeda, A.Wakahara
    • Journal Title

      Phys.Stat.Sol.(a) Vol.201, No.12

      Pages: 2695-2698

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Growth of High-Quality AIN with Low Pit Density on SiC Substrates2004

    • Author(s)
      A.Nakajima, Y.Furukawa, S.Koga, H.Yonezu
    • Journal Title

      J.Cryst.Growth Vol.265

      Pages: 351-356

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Analog Integrated Circuit for Motion Detection of Approaching Object Based on the Insect Visual System2004

    • Author(s)
      K.Nishio, H.Yonezu, M.Ohtani, H.Yamada, Y.Furukawa
    • Journal Title

      Opt.Rev. Vol.11, No.1

      Pages: 38-47

    • NAID

      10012050685

    • Related Report
      2004 Annual Research Report
  • [Book] ニューロインフォマティクス : 第6章6.1 初期視覚情報処理を行うアナログ・ビジョンチップ2006

    • Author(s)
      米津宏雄
    • Publisher
      オーム社(出版予定)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Book] ニューロインフォマティクス:第6章6.1 初期視覚情報処理を行うアナログ・ビジョンチップ2006

    • Author(s)
      米津宏雄
    • Publisher
      オーム社(出版予定)
    • Related Report
      2005 Annual Research Report
  • [Book] Dilute Nitride Semiconductors : Chapter 14. Dislocation-free III-V-N Alloy Layers on Si Substrates and Their Device Applications2005

    • Author(s)
      H.Yonezu
    • Publisher
      Elsevier Ltd.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体装置及びその製造方法2001

    • Inventor(s)
      米津宏雄
    • Industrial Property Rights Holder
      (独)科学技術振興機構
    • Industrial Property Number
      2001-263610
    • Filing Date
      2001-08-31
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Publications] A.Utsumi, H.Yonezu, Y.Furukawa, K.Momose, K.Kuroki: "Increase in luminescence efficiency of GaPN layers by thermal annealing"Phys.Stat.Sol.(c). Vol.0,No.7. 2741-2744 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Momose, H.Yonezu, Y.Furukawa, A.Utsumi, Y.Yoshizumi, S.Shinohara: "Improvement of Crystalline Quality of GaAsyP1-x-yNx Layers with High Nitrogen Compositions at Low-Temperature Growth by Atomic Hydrogen Irradiation"J.Cryst.Growth. Vol.251. 443-448 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Nishio, H.Yonezu, M.Ohtani, H.Yamada, Y.Furukawa: "Analog Metal-Oxide-Semiconductor Integrated Circuit Implementation of Approach Detection with Simple-Shape Recognition Based on Visual Systems of Lower Animals"Opt.Rev.. Vol.10,No.2. 96-105 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Nishio, H.Yonezu, A.B.Kariyawasam, Y.Yoshikawa, S.Sawa, Y.Furukawa: "Analog Integrated Circuit for Motion Detection against Moving Background Based on the Insect Visual System"Opt.Rev.. Vol.11,No.1. 24-33 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Y.Moon, A.Utsumi, H.Yonezu, Y.Furukawa, T.Ikeda, A.Wakahara: "GaPN-GaP Double Heterostructure Light Emitting Diode Grown on GaP Substrate by Solid-Source Molecular Beam Epitaxy"The 5th International Symposium on Blue Laser and Light Emitting Diodes-2004 (ISBLLED-2004). 262 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Furukawa, H.Yonezu, A.Utsumi, K.Momose, S.Shinohara, Y.Yoshizumi: "Effect of Thermal Annealing on Optical Property of GaPN Alloy"The 15th American Conference on Crystal Growth and Epitaxy (ACCGE-15) 724. 91 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2018-03-28  

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