Project/Area Number |
15069205
|
Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
|
Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
|
Research Institution | Kyoto Institute of Technology |
Principal Investigator |
YAMADA Etsu Kyoto Institute of Technology, Center for Environmental Science, Professor, 環境科学センター, 教授 (30159214)
|
Co-Investigator(Kenkyū-buntansha) |
TANAKA Nobuo Kyoto Institute of Technology, Department of Polymer Science and Engineering, Professor, 繊維学部, 教授 (60127165)
MIKI Sadao Kyoto Institute of Technology, Department of Chemistry and Materials Technology, Professor, 工芸学部, 教授 (30135537)
CHIBA Kouichi National Institute of Advanced Industrial Science and Technology (AIST), Metrology Institute of Japan, Deputy Director, 計測標準研究部門無機分析科, 副部門長 (20281066)
NAKAMURA Masaaki Nagoya University, Graduate School of Engineering, Professor, 大学院工学研究科, 教授 (30023279)
|
Project Period (FY) |
2003 – 2005
|
Project Status |
Completed (Fiscal Year 2005)
|
Budget Amount *help |
¥9,200,000 (Direct Cost: ¥9,200,000)
Fiscal Year 2005: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 2004: ¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 2003: ¥2,800,000 (Direct Cost: ¥2,800,000)
|
Keywords | scientific research / chemical management / volatile organic compounds (VOCs) / portable VOCs instrument / passive sampler / environmental management system / 環境負荷低減 / 化学物質管理データベース |
Research Abstract |
A small, rapid, and sensitive instrument for the continuous analysis of very volatile organic compounds (VOCs) with a lower boiling point than 100℃ in addition to the analysis of VOCs with a boiling point of 100-150℃ was developed and applied to the measurement of VOCs in the course of university research and environmental monitoring. VOCs, such as n-hexane, acetone, ethyl acetate, alcohols, benzene, toluene, and xylene, can be continuously measured once every 30 min. The detection limits of hexane, ethyl acetate, benzene, and toluene at a pre-concentration time of 10 min were 0.41 μg/m^3 (0.12 ppb), 0.67 μg/m^3 (0.19 ppb), 0.22 μg/m^3 (0.07 ppb), and 0.22 μg/m^3 (0.06 ppb), respectively. The relative standard deviations of VOCs were less than 5%. The sensitivities of VOCs obtained by the present method were higher than those obtained by the conventional method. The temporal changes in the VOC concentrations in several laboratories and at a plant for the disposal of organic liquid wastes were measured, and the behavior of VOCs was analyzed. The VOC concentrations, except for those of ethyl acetate, obtained with the portable instrument were slightly lower than those obtained with a passive sampler. The portable instrument developed in the course of this study may be used for the risk assessment and management of chemicals.
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