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充填スクッテルダイト構造に由来する新奇量子現象の解明

Research Project

Project/Area Number 15072203
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

榊原 俊郎  The University of Tokyo, 物性研究所, 教授 (70162287)

Co-Investigator(Kenkyū-buntansha) 上田 和夫  東京大学, 物性研究所, 教授 (70114395)
瀧川 仁  東京大学, 物性研究所, 教授 (10179575)
辛 埴  東京大学, 物性研究所, 教授 (00162785)
上床 美也  東京大学, 物性研究所, 准教授 (40213524)
松田 裕司 (松田 祐司)  京都大学, 大学院・理学研究科, 教授 (50199816)
武田 直也  新潟大学, 大学院工学研究科, 教授 (80242171)
石川 征靖  東京大学, 物性研究所, 教授 (70159705)
Project Period (FY) 2003 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥117,500,000 (Direct Cost: ¥117,500,000)
Fiscal Year 2007: ¥17,900,000 (Direct Cost: ¥17,900,000)
Fiscal Year 2006: ¥21,400,000 (Direct Cost: ¥21,400,000)
Fiscal Year 2005: ¥21,700,000 (Direct Cost: ¥21,700,000)
Fiscal Year 2004: ¥29,800,000 (Direct Cost: ¥29,800,000)
Fiscal Year 2003: ¥26,700,000 (Direct Cost: ¥26,700,000)
Keywords多極子秩序 / スカラー秩序 / 異方的超伝導 / 非フェルミ液体 / 核磁気緩和率 / スクッテルダイト / ベータパイロクロア / ラットリング / 超伝導転移 / 圧力効果 / スカラー型秩序変数 / 核磁気共鳴 / 磁化測定 / ダイヤモンドアンビルセル / ホール効果 / 磁場誘起転移 / 緩和時間 / オフセンター振動 / 光電子分光 / 量子臨界現象 / 異方的超伝導体 / ギャップ対称性 / 比熱測定 / 反強四重極転移 / NMR / 超伝導転移温度圧力依存性 / 四重極秩序 / 中性子散乱 / 磁気相図 / 金属非金属転移
Research Abstract

PrFe_4P_<12>の熱膨張測定から、スカラー秩序相において立方対称性が破れていないことを高い精度で示した。またPrをLaでわずかに置換することで強磁性が誘起されることから、ネスティングを伴うスカラー秩序と強磁性とが競合していることを明らかにした。
SmFe_4P_<12>、Ce_2Pd_3Si_5、Ce_2RhSi_3の圧力下電気抵抗測定を行い、それぞれの圧力相図を得た。SmFe_4P_<12>は8GPaの圧力下においても強磁性秩序が1.5K以下で出現し、ほとんど圧力依存しないことを明らかにした。
CeFe_4P_<12>において、硬X線励起Ce3d内殻光電子スペクトル、及び軟X線励起Ce3d-4f共鳴光電子分光の結果から、Ceの4f電子と伝導電子との間に働く強い混成効果とエネルギーギャップの起源を明らかにした。
超伝導体LaOs_4P_<12>の純良単結晶を用いて磁揚中比熱の研究を行い、新しい相転移を発見した。この相転移は磁場の影響を受けず、超伝導転移の影響も受けていない点でベータパイロクロアにおける奇妙な相転移と類似している。
PrRu_4P_<12>におけるRu核のNQR測定を行い、極低温においても磁気揺らぎが残っていること、更に1K以下で核磁気緩和率の異常な増大を見出した。
準2次元重い電子系化合物CeMIn_5(M=Co,Rh.Jr)の超伝導転移温度以上の正常状態における輸送現象を測定し、非フェルミ流体的な振る舞いを系統的に調べ高温超伝導体との比較を行った。
重い電子系超伝導体URu_2Si_2の超純良単結晶を用いて磁場中での比熱・熱伝導度の測定を行い超伝導対称性の決定を行うと同時に、準粒子状態の異常性も明らかにした。
ベータパイロクロア超伝導体でみられる、上に凸の温度依存性を持った電気抵抗や低温でピークを持ち高温で定数となる核磁気緩和率などこれまでにない現象について、ラットリングが電子系と結合したモデルを用いて説明できることを自己無撞着な調和近似を用いて明らかにした。

Report

(5 results)
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (65 results)

All 2008 2007 2006 2005 2004 Other

All Journal Article (50 results) (of which Peer Reviewed: 11 results) Publications (15 results)

  • [Journal Article] Field-Angle-Dependent Specific Heat Measurements and Gap Deter mination of a Heavy Fermion Superconductor URu_2Si_22008

    • Author(s)
      K. Yano
    • Journal Title

      Phys. Rev. Lett. 100

      Pages: 170041-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of semiconducting CeFe_4P_<12>: Strong hybridization and relevance of single-impurity Anderson model2008

    • Author(s)
      M. Matsunami
    • Journal Title

      Phys. Rev. B 77

      Pages: 1651261-5

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bulk Electronic Structure of the Antiferromagnetic Superconducting Phase in ErNi_2B_2C2008

    • Author(s)
      T. Baba
    • Journal Title

      Phys. Rev. Lett. 100

      Pages: 170031-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Flux Line Lattice Melting and the Formation of a Coherent Quasiparticle Bloch State in Ultraclean URu_2Si_2 Superconductor2008

    • Author(s)
      R. Okazaki
    • Journal Title

      Phys. Rev. Lett. 100

      Pages: 370041-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of NMR relaxation due to rattling phonons2008

    • Author(s)
      T. Dahm
    • Journal Title

      J. Phys. Chem. Solids (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of La Impurities on the Phase Transitions in PrFe_4P_<12>2007

    • Author(s)
      T. Tayama
    • Journal Title

      J. Phys. Soc. Jpn. 76

      Pages: 837021-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of SmFe4P12 at Pressures to 8 GPa2007

    • Author(s)
      N. Kurita
    • Journal Title

      J. Phys. Soc. Jpn. 76,Suppl.A

      Pages: 64-65

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Hydrostatic Pressure on the Electrical Resistivity of PrOs_4Sb_<12> up to 10 GPa2007

    • Author(s)
      N. Kurita
    • Journal Title

      J. Phys. Soc. Jpn. 76,Suppl.A

      Pages: 150-151

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Symmetry Lowering Associated with the, Metal-Insulator Transition in SmRu_4P_<12> by 101Ru-NQR2007

    • Author(s)
      S. Masaki
    • Journal Title

      J. Phys. Soc. Jpn. 74

      Pages: 437141-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exotic Superconducting Properties in the Electron-Hole Compensated Heavy Fermion Semimetal URu_2Si_22007

    • Author(s)
      Y. Kasahara
    • Journal Title

      Phys. Rev. Lett. 99

      Pages: 1164021-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NMR relaxation and resistivity from rattling phonons in pyrochlore superconductors2007

    • Author(s)
      T. Dahm
    • Journal Title

      Phys. Rev. Lett. 99

      Pages: 1870031-4

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-Fermi liquid behavior in the magnetotransport of CeMIn_5 (M : Co and Rh) : Striking similarity between quasi two-dimensional heavy fermion and high-T_c cuprates2007

    • Author(s)
      Y.Nakajima et al.
    • Journal Title

      J. Phys. Soc. Jpn 76

      Pages: 24703-24703

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Observation of two spin gap energies in the filled skutterudite compound CeOs_4Sb_<12>2007

    • Author(s)
      D.A.Adroja et al.
    • Journal Title

      Phys. Rev. B 75

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Raman scattering study of the skutterudite compounds2007

    • Author(s)
      N.Ogita et al.
    • Journal Title

      J. Magn. Magn. Mat. 310

      Pages: 948-950

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Relation between superconductivity and superstructure in Ce_2RhIn_82007

    • Author(s)
      M.Koeda et al.
    • Journal Title

      J. Magn. Magn. Mat. 310

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Superconductivity of PrOs_4Sb_<12> at pressures to 10 GPa2007

    • Author(s)
      N.Kurita et al.
    • Journal Title

      J. Magn. Magn. Mat. 310

      Pages: 611-613

    • Related Report
      2006 Annual Research Report
  • [Journal Article] On the Symmetry of Low-Field Ordered Phase of PrFe_4P_<12> : ^<31>P NMR2007

    • Author(s)
      J.Kikuchi et al.
    • Journal Title

      J. Phys. Soc. Jpn 76

    • Related Report
      2006 Annual Research Report
  • [Journal Article] The superconducting gap structure of PrOs_4Sb_<12> and CeRu_2 probed by C(H,ψ)2007

    • Author(s)
      J.Custers et al.
    • Journal Title

      J. Mag. Mag. Mater. 310

      Pages: 700-702

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nodal Structures of Heavy Fermion Superconductors Probed by the Specific-Heat Measurements in Magnetic Fields2007

    • Author(s)
      T.Sakakibara et al.
    • Journal Title

      J. Phys. Soc. Jpn. 76(印刷中)

    • NAID

      110006273160

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Angle-Resolved Magnetization Study of the Multipole Ordering in PrFe_4P_<12>2007

    • Author(s)
      H.Sato et al.
    • Journal Title

      J. Phys. Soc. Jpn. 76(印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thermal Conductivity of the Pyrochlore Superconductor KOs_2O_6 : Strong Electron Correlations and Fully Gapped Superconductivity.2006

    • Author(s)
      Y.Kasahara et al.
    • Journal Title

      Phys. Rev. Lett. 96

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fulde-Ferrell-Larkin-Ovchinnikov state in a perpendicular field of quasi two-dimensional CeCoIn_52006

    • Author(s)
      K.Kumagai et al.
    • Journal Title

      Phys. Rev. Lett. 97

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nodal structure of unconventional superconductors probed by angle resolved thermal transport measurements2006

    • Author(s)
      Y.Matsuda et al.
    • Journal Title

      J. Phys : Condens. Matter 18

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Low energy excitations of the one-dimensional attractive SU(4) Hubbard Model2006

    • Author(s)
      J.Zhao et al.
    • Journal Title

      Phys. Rev. B 74

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Evolution of Hall Coefficient in Two-Dimensional Heavy Fermion CeCoIn_52006

    • Author(s)
      Y.Nakajima et al.
    • Journal Title

      J.Phys.Soc.Jpn. 75

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Specific Heat Measurements on a Modulated Quadrupolar Ordering Compound PrPb_3 at Very Low Temperatures2006

    • Author(s)
      T.Morie et al.
    • Journal Title

      J.Phys.Soc.Jpn.Suppl. (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Photoemission Spectroscopy of Ce-filed Skutterudites2006

    • Author(s)
      M.Matsunami et al.
    • Journal Title

      Physica B (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Physical Properties and Phase Diagram of Geometrically Quadrupolar-Frustrated System DyB_42006

    • Author(s)
      R.Watanuki et al.
    • Journal Title

      Physica B (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Field-Orientation Dependence of the Specific Heat of PrOs_4Sb_<12>2006

    • Author(s)
      J.Custers et al.
    • Journal Title

      Physica B (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure Effect on Superconductivity and Antiferroquadrupolar Order in PrOs_4Sb_<12>2006

    • Author(s)
      T.Tayama et al.
    • Journal Title

      J.Phys.Soc.Jpn. 75, No.4(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The development of a high pressure micro-cell for magnetization and specific heat measurements : the effect of pressure on the magnetism in CeAg2005

    • Author(s)
      Y.Uwatoko et al.
    • Journal Title

      J.Phys.Condens.Matter 17

    • Related Report
      2005 Annual Research Report
  • [Journal Article] NMR Study of the new filled skutterudite superconductor YFe_4P_<12>2005

    • Author(s)
      K.Magishi et al.
    • Journal Title

      PhysicaB 359-361

      Pages: 883-885

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Influence of the crystal field potential on the superconducting properties of PrRu_4Sb_<12>2005

    • Author(s)
      D.A.Adroja et al.
    • Journal Title

      PhysicaB 359-361

      Pages: 983-985

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Probing the vortex state of PrSu_4Sb_<12> through muon spin rotation and relaxation2005

    • Author(s)
      D.A.Adroja et al.
    • Journal Title

      Phys.Rev.B 72

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Quadrupolar order and field-induced heavy-fermion state in the filled skutterudite PrFe_4P_<12> via ^<31>P NMR2005

    • Author(s)
      J.Kikuchi et al.
    • Journal Title

      Physica B 359-361

      Pages: 877-879

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Evolution of 4f-Electron States in the Metal-Insulator Transition of PrRu4P_<12>2005

    • Author(s)
      K.Iwasa et al.
    • Journal Title

      Phys.Rev.B 72

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Observation of modulated quadrupole structures in PrPb_32005

    • Author(s)
      T.Onimaru et al.
    • Journal Title

      Phys.Rev.Lett. 94

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phase Diagrams and Ground State Magnetic Properties of Pr-based Filled Skutterudites2005

    • Author(s)
      T.Sakakibara et al.
    • Journal Title

      Physica B 359-361

      Pages: 836-843

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phase Diagrams and Ground State Magnetic Properties of Pr-based Filled Skutterudites2005

    • Author(s)
      T.Sakakibara et al.
    • Journal Title

      Physica B (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Quadrupolar order and field-induced heavy-fermion state in the filled skutterudite PrFe_4P_<12> via ^<31>P NMR2005

    • Author(s)
      J.Kikuchi et al.
    • Journal Title

      Physica B (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Photoemission Spectroscopic Evidence of Gap Anisotropy in an f-Electron Superconductor2005

    • Author(s)
      T.Kiss et al.
    • Journal Title

      Phys.Rev.Lett. 94

      Pages: 57001-57001

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Texture in the Superconducting Order Parameter of CeCoIn_52005

    • Author(s)
      K.Kakuyanagi et al.
    • Journal Title

      Phys.Rev.Lett. 94

      Pages: 47602-47602

    • Related Report
      2004 Annual Research Report
  • [Journal Article] New High-Field Ordered State in PrFe_4P_<12>2004

    • Author(s)
      T.Tayama et al.
    • Journal Title

      J.Phys.Soc.Jpn. 73

      Pages: 3258-3261

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Competition between Kondo effect and ferromagnetic interaction in skutterudite La_<1-x>Sm_xFe_4P_<12>2004

    • Author(s)
      N.Takeda et al.
    • Journal Title

      J.Magn.Magn.Mat. 272-276

      Pages: 64-65

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Study of the hybridization gap formation in a heavy fermion compound : CeRu_4Sb_<12>2004

    • Author(s)
      D.A.Adroja et al.
    • Journal Title

      J.Magn.Magn.Mat. 272-276

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Magnetization study of the heavy fermion superconductor PrOs_4Sb_<12>2004

    • Author(s)
      T.Tayama et al.
    • Journal Title

      J.Magn.Magn.Mat. 272-276

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Pressure effects on the Kondo-lattice compound Ce_2Pd_3Si_52004

    • Author(s)
      M.Abliz et al.
    • Journal Title

      Physical Review B 69

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Superconducting Gap Function in Antiferromagnetic Heavy-Fermion Upd_2Al_3 Probed by Angle Resolved Magnetothermal Transport Measurements2004

    • Author(s)
      T.Watanabe et al.
    • Journal Title

      Physical Review B 70

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Angle-resolved magnetization measurements on antiferroquadrupolar ordering system PrPb_3:evidence for anisotropic quadrupolar interaction2004

    • Author(s)
      T.Onimaru et al.
    • Journal Title

      J.Phys.Soc.Jpn. 73

      Pages: 2377-2380

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Low temperature magnetization study on the phase IV ordering in Ce_xLa_<1-x>B_6 under [111] uniaxial pressure2004

    • Author(s)
      T.Morie et al.
    • Journal Title

      J.Phys.Soc.Jpn. 73

      Pages: 2381-2384

    • Related Report
      2004 Annual Research Report
  • [Publications] K.Izawa et al.: "Multiple Superconducting Phases in New Heavy Fermion Superconductor PrOs_4Sb_<12>"Phys.Rev.Lett.. 90. 117001 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Kakuyanagi et al.: "Antiferromagnetic vortex core in Tl_2Ba_2CuO_<6+δ> studied by nuclear magnetic resonance"Phys.Rev.Lett.. 90. 197003 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Shibata et al.: "Anomalous Flux Flow Resistivity in Two Gap Superconductor MgB_2"Phys.Rev.B. 68. 060501 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Nakajima et al.: "Normal-state Hall Angle and Magnetoresistance in quasi-2D Heavy Fermion CeCoIn_5 near a Quantum Critical Point."J.Phys.Soc.Jpn. 73. 5-8 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Tayama et al.: "Magnetic phase diagram of the heavy fermion superconductor PrOs_4Sb_<12>"J.Phys.Soc.Jpn. 72. 1516-1522 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] D.T.Adroja et al.: "Investigation of the spin gap formation in a heavy fermion skutterudite compound CeRu_4Sb_<12>"Phys.Rev.B. 68. 094425 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] I.Shirotani et al.: "Superconductivity of new filled skutterudite YFe_4P_<12> prepared at high pressure"J.Phys.Condens.Matter. 15. S2201 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Takeda et al.: "Ferromagnetic Kondo-lattice compound SmFe_4P_<12>"J.Phys.:Condens.Matter. 15. L229 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Harima et al.: "Origin of the Metal-Insulator Transition in PrRu_4P_<12>"Acta Physica Polonica B. 34. 1189-1192 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.H.Curnoe et al.: "Quadrupolar ordering in half-integral spin systems"Physica B. 329-323. 474-475 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Maehira et al.: "Electronic Structure and Fermi Surface of PuCoGa_5 and NpCoGa_5"Phys.Rev.Lett.. 90. 207007-1-207007-4 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Aoki et al.: "Field-angle dependence of the zero-energy density of states in the unconventional heavy-fermion superconductor CeCoIn_5"J.Phys.Condens.Matter. 16. L13-L19 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Sakakibara et al.: "Liquid-gas transition in the spin-ice dysprosium titanate"J.Mag.Mag.Mater. (印刷中).

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Takeda et al.: "Competition between Kondo effect and ferromagnetic interaction in skutterudite La_<1-x>Sm_xFe_4P_12"J.Magn.Magn.Mater. (印刷中).

    • Related Report
      2003 Annual Research Report
  • [Publications] D.T.Adroja et al.: "Study of the hybridization gap in a heavy fermion compound : CeRu_4Sb_<12>"J.Magn.Magn.Mater. (印刷中).

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2018-03-28  

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