ナノギャップを用いた単一分子の伝導特性計測とセンサ応用

• Project/Area Number: 15073208
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: The University of Tokyo
• Principal Investigator: 染谷 隆夫 The University of Tokyo, 大学院・工学系研究科, 准教授 (90292755)
• Project Period (FY): 2003 – 2007
• Project Status: Completed (Fiscal Year 2007)
• Budget Amount: ¥30,200,000 (Direct Cost: ¥30,200,000); Fiscal Year 2007: ¥5,100,000 (Direct Cost: ¥5,100,000); Fiscal Year 2006: ¥5,100,000 (Direct Cost: ¥5,100,000); Fiscal Year 2005: ¥6,400,000 (Direct Cost: ¥6,400,000); Fiscal Year 2004: ¥7,200,000 (Direct Cost: ¥7,200,000); Fiscal Year 2003: ¥6,400,000 (Direct Cost: ¥6,400,000)
• Keywords: 有機トランジスタ / ナノテクノロジー / 有機半導体 / 大面積トランジスタ / 有機デバイス / フレキシブルデバイス / 科学センサ / ナノデバイス / 分子エレクトロニクス

Research Abstract

本研究は、有機トランジスタをナノ寸法まで微細化して高性能化し、大面積センサに応用する研究を推進することを目的している。これまでに、「有機半導体分子を用いたトランジスタをナノ寸法にまで微細化して、大面積センサに応用する」ため、ナノ印刷技術や張り合わせ法によって有機トランジスタを製造する方法に取り組んだ。特に、有機トランジスタの製造に当たっては、ソース・ドレインの微細化を低コストプロセスで実現するだけでなく、そのほかのゲート電極層、ゲート絶縁膜、有機半導体層などを低コストプロセスで成膜することが大切である。これまでに、筆者らはポリイミドの前駆体をポリエチレンナフタレートの上にスピンコートで塗布して、有機トランジスタのゲート絶縁膜とすることに成功している。また、ポリイミドの前駆体をインクジェットで塗布し、ゲート絶縁膜のパターニングに取り組んだ。インクジェット塗布時の周波数や印加電圧を最適化することによって、ポリイミド薄膜の平坦性や均一性を向上させた。また、電極層については、銀ナノ粒子をインクジェットで塗布して、ゲート電極に応用してきたが、同様の手法をソース・ドレイン電極に応用した。特に、インクジェット描画によるミクロン寸法の電極を利用することによって、チャネル長が1ミクロンかつ高移動度のペンタセン電界効果トランジスタの試作に成功した。

Research Products

• [Journal Article] Organic transistor integrated circuits for large-area sensors (2006)
  • Author(s): Someya T, Sekitani T, Iba s, Kato Y, Sakurai T, Kawaguchi H
  • Journal Title: MOLECULAR CRYSTALS AND LIQUID CRYSTALS 2006 444 : 13-22 Pages: 14-22
• [Journal Article] Organic transistor integrated circuits for large-area sensors (2006)
  • Author(s): Someya T, Sekitani T, Iba S, Kato Y, Sakurai T, Kawaguchi H
  • Journal Title: MOLECULAR CRYSTALS AND LIQUID CRYSTALS 2006 444: 13-22 Pages: 14-22
• [Journal Article] Integration of organic field-effect transistors with organic photo diodes for alarge-area, fiexible, and lightweight sheet image scanner (2005)
  • Author(s): Takao Someya, Yusaku Kato, Shingo Iba, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: IEEE Transactions on Electron Devices, (NOV 2005) Volume 52, Issue 11 Pages: 2502-2511
  • Peer Reviewed
• [Journal Article] Conformable, fiexible, large-area networks of pressure and thermal sensors with organic transistor active matrixes (2005)
  • Author(s): Takao Someya, Yusaku Kato, Tsuyoshi Sekitani, Shingo Iba, Yoshiaki Noguchi, Yousuke Murase, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: Proceedings of the National Academy of Sciences of the United States of America, (August 30, 2005) Volume 102, Issue 35 Pages: 12321-12325
  • Peer Reviewed
• [Journal Article] Integration of organic field-effect transistors with organic photodiodes for a large-area, flexible, and lightweight sheet image scanner (2005)
  • Author(s): Takao Someya, Yusaku Kato, Shingo Iba, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: IEEE Transactions on Electron Devices, (NOV 2005). Volume 52, Issue 11 Pages: 2502-2511
• [Journal Article] Conformable, flexible, large-area networks of pressure and thermal sensors with organic transistor active matrixes (2005)
  • Author(s): Takao Someya, Yusaku Kato, Tsuyoshi Sekitani, Shingo Iba, Yoshiaki Noguchi, Yousuke Murase, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: Proceedings of the National Academy of Sciences of the United States of America, (August 30, 2005). Volume 102, Issue 35 Pages: 12321-12325
• [Journal Article] High-Temperature Operation of Pentacene Field-Effect Transistors with Polyimide Gate Insulators (2005)
  • Author(s): Tsuyoshi Sekitani, Yusaku Kato, Shingo Iba, Takayasu Sakurai, Takao Someya
  • Journal Title: Material Research Society Spring Meeting, Symposium I, "Organic Thin-Film Electronics" I1.9(印刷中)
• [Journal Article] Pentacene field-effect transistors on plastic films operating at high temperature above 100 [degree]C (2004)
  • Author(s): Tsuyoshi Sekitani, Shingo Iba, Yusaku Kato, Takao Someya
  • Journal Title: Applied Physics Letters Vol. 85, Issue 17 Pages: 3902-3904
  • Peer Reviewed
• [Journal Article] High mobility of pentacene field-effect transistors with polyimide gate dielectric layers (2004)
  • Author(s): Yusaku Kato, Shingo Iba, Ryohei Teramoto, Tsuyoshi Sekitani, Takao Someya, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: Applied Physics Letters Vol. 84, No. 19 Pages: 3789-3791
  • Peer Reviewed
• [Journal Article] Elastomeric transistor stamps : Reversible probing of charge transport in organic crystals (2004)
  • Author(s): V. C. Sundar, J. Zaumseil, V. Podzorov, E. Menard, R. L. Willett, T. Someya, M. E. Gershenson, J. A. Rogers
  • Journal Title: SCIENCE 303 (5664) Pages: 1644-1646
  • Peer Reviewed
• [Journal Article] 有機トランジスタの化学センサー応用 (2004)
  • Author(s): 染谷,隆夫
  • Journal Title: 機能材料 3月号 Pages: 42-42
• [Journal Article] Pentacene field-effect transistors on plastic films operating at high temperature above 100 [degree]C (2004)
  • Author(s): Tsuyoshi Sekitani, Shingo Iba, Yusaku Kato, Takao Someya
  • Journal Title: Applied Physics Letters Vol.85,Issue 17 Pages: 3902-3904
• [Journal Article] High mobility of pentacene field-effect transistors with polyimide gate dielectric layers (2004)
  • Author(s): Yusaku Kato, Shingo Iba, Ryohei Teramoto, Tsuyoshi Sekitani, Takao Someya, Hiroshi Kawaguchi, Takayasu Sakurai
  • Journal Title: Applied Physics Letters Vol.84,No.19 Pages: 3789-3791
• [Journal Article] Elastomeric transistor stamps : Reversible probing of charge transport in organic crystals (2004)
  • Author(s): V.C.Sunder, J.Zaumseil, V.Podzorov, S.Menard, R.L.Willett, T.Someya, M.E.Gershenson, J.A.Rogers
  • Journal Title: SCIENCE 303(5664) Pages: 1644-1646
• [Journal Article] Manufacturing Process and Characterization of Organic Diode-based Sheet Thermal Sensors (2004)
  • Author(s): Y.Kato
  • Journal Title: Third International Conference on Molecular Electronics and Bioelectronics (M&BE3), National Center of Sciences (National Institute of Informatics) 40-A09(印刷中)
• [Journal Article] A Large-Area, Flexible, and Lightweight Sheet Image Scanner (2004)
  • Author(s): T.Someya, S.Iba, Y.Kato, T.Sekitani, Y.Noguchi, Y.Murase, H.Kawaguchi, T.Sakurai
  • Journal Title: 2004 IEEE International Electron Devices Meeting (IEDM) 15.1(印刷中)
• [Journal Article] Nanoscale organic transistors that use source/drain electrodes supported by high resolution rubber stamps (2003)
  • Author(s): J. Zaumseil, T. Someya, Z. Bao, Y. L. Loo, R. Cirelli, J. A. Rogers
  • Journal Title: Applied Physics Letters 82(5) Pages: 793-795
  • Peer Reviewed
• [Journal Article] Magnetoresistance oscillations induced by intersubband scattering of two-dimensional electron gas in Al0.22Ga0.78N/GaN heterostructures (2003)
  • Author(s): N. Tang, B. Shen, Z. W. Zheng, J. Liu, D. J. Chen, J. Lu, R. Zhang, Y. Shi, Y. D. Zheng, Y. S. Gui, C. P. Jiang. Z. J. Qiu, S. L. Guo, J. H. Chu, K. Hoshio, T. Someya, Y. Arakawa
  • Journal Title: Applied Physics Letters 94 (8) Pages: 5420-5422
  • Peer Reviewed
• [Journal Article] Time-resolved gain dynamics in InGaN MQWs using a Kerr gate (2003)
  • Author(s): R. A. Taylor, J. D. Smith, J. H. Rice, J. F. Ryan, T. Someya, Y. Arakawa
  • Journal Title: PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES 17(1-4) Pages: 255-257
  • Peer Reviewed
• [Journal Article] Transport properties of two-dimensional electron gas in different subbands in triangular quantum wells at AlxGalxN/GaN heterointerfaces (2003)
  • Author(s): Z. W. Zheng, B. Shen, Y. S. Gui, C. P. Jiang, N. Tang, R. Zhang, Y. Shi, Y. D. Zheng, S. L. Guo, G. Z. Zheng, J. H. Chu, T. Someya, Y. Arakawa
  • Journal Title: Applied Physics Letters 82(12). Pages: 1872-1874
  • Peer Reviewed
• [Journal Article] Multisubband transport of the two-dimensional electron gas in AlxGalxN/GaN heterostructures (2003)
  • Author(s): Z. W. Zheng, B. Shen, C. P. Jiang, Y. S. Gui, T. Someya, R. Zhang, Y. Shi, Y. D. Zheng, S. L. Guo, J. H. Chu, Y. Arakawa
  • Journal Title: Journal of Applied Physics 93(3) Pages: 1651-1655
  • Peer Reviewed
• [Presentation] Printed organic transistors for skin-like sensors (2007)
  • Author(s): T. Someya
  • Organizer: OEC-07, Sheraton- Conference Centre
  • Place of Presentation: Frankfurt, Germany
• [Presentation] Printed organic transistors for large-area electronics (2007)
  • Author(s): T. Someya
  • Organizer: International Symposium on Strongly-Correlated Applied Physics
  • Place of Presentation: Takeda Hall, University of Tokyo
• [Presentation] Contactless position sensing using printed organic transistors for power transmission sheets (2007)
  • Author(s): Takao Someya
  • Organizer: Paper 6658-4, Session 1 : Circuits and Displays
  • Place of Presentation: Optics West, San Diego
• [Presentation] Printed Organic Transistors for Skin-like Sensors (2007)
  • Author(s): Takao Someya
  • Organizer: 2007 International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
  • Place of Presentation: Mielparque Nagano, Nagano, Japan
• [Presentation] Printed organic transistors for large-area skin-like sensors and actuators (2007)
  • Author(s): Takao Someya
  • Organizer: International Conference on Organic Electronics
  • Place of Presentation: Philips High Tech Campus, Eindhoven
• [Presentation] Organic transistors for ambient electronics (2007)
  • Author(s): Takao Someya
  • Organizer: 2007 NEC Technology Forum on "Technology Paradigm Shift in Computing & Communication"
  • Place of Presentation: Aoyama Diamond Hall
• [Presentation] "Printed organic transistors for skin-like sensors" (2007)
  • Author(s): T. Someya
  • Organizer: OEC-07, Sheraton- Conference Centre
  • Place of Presentation: Frankfurt-Airport, Germany
• [Presentation] "Printed organic transistors for large-area electronics" (2007)
  • Author(s): T. Someya
  • Organizer: International Symposium on Strongly-Correlated Applied Physics
  • Place of Presentation: Takeda Hall, University of Tokyo
• [Presentation] "Contactless position sensing using printed organic transistors for power transmission sheets" (2007)
  • Author(s): Takao Someya
  • Organizer: Paper 6658-4, Session 1: Circuits and Displays
  • Place of Presentation: Optics West, San Diego
• [Presentation] "Printed Organic Transistors for Skin-like Sensors" (2007)
  • Author(s): Takao Someya
  • Organizer: 2007 International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
  • Place of Presentation: Mielparque Nagano, Nagano, Japan
• [Presentation] "Printed Organic transistors for large-area skin-like sensors and actuators" (2007)
  • Author(s): Takao Someya
  • Organizer: International Conference on Organic Electronics
  • Place of Presentation: Philips High Tech Campus, Eindhoven
• [Presentation] "Organic transistors for ambient electronics" (2007)
  • Author(s): Takao Someya
  • Organizer: 2007 NEC Technology Forum on "Technology Paradigm Shift in Computing & Communication"
  • Place of Presentation: Aoyama Diamond Hall
• [Presentation] High-Temperature Operation of Pentacene Field-Effect Transistors with Polyimide Gate Insulators (2005)
  • Author(s): Tsuyoshi Sekitani, Yusaku Kato, Shingo Iba. Takayasu Sakurai, Takao Someya
  • Organizer: Material Research Society Spring Meeting, Symposium I, "Organic Thin-Film Electronics"
  • Place of Presentation: Moscone West Convention Center, San Francisco
  • Year and Date: 2005-03-29
• [Presentation] Manufacturing Process and Characterization of Organic Diode-based Sheet Thermal Sensors (2005)
  • Author(s): Y. Kato, T. Sekitani, S. Iba, T. Sakurai, T. Someya
  • Organizer: Third International Conference on Molecular Electronics and Bioelectronics (M&BE3), National Center of Sciences (National Institute of Informatics)
  • Place of Presentation: National Center of Sciences (National Institute of Informatics), Tokyo
• [Presentation] A Large-Area, Flexible, and Lightweight Sheet Image Scanner (2004)
  • Author(s): T. Someya, S. Iba, Y. Kato, T. Sekitani, Y. Noguchi, Y. Murase, H. Kawaguchi, T. Sakurai
  • Organizer: 2004 IEEE International Electron Devices Meeting(IEDM)
  • Place of Presentation: Hilton San Francisco and Towers, San Francisco
• [Book] フレキシブルセンサー、「有機基板上の電子デバイス」 (2006)
  • Author(s): 染谷隆夫, 関谷毅, 桜井貴康
  • Publisher: シーエムシー出版(発行20065年4月24日).
• [Book] "Large area detectors and sensors", Organic Electronics, ISBN Wiley-VCH, 3-527-31264-1 (2006)
  • Author(s): Takao Someya, Takayasu Sakurai
  • Publisher: - Weinheim.
• [Book] フレキシブルセンサー、「フレキシブルエレクトロニクス」 (2006)
  • Author(s): 染谷隆夫, 関谷毅, 桜井貴康
  • Total Pages: 6
  • Publisher: シーエムシー出版
• [Book] "Large area detectors and sensors", Organic Electronics (2006)
  • Author(s): Takao Someya, Takayasu Sakurai
  • Total Pages: 8
  • Publisher: Wiley-VCH
• [Book] 「エレクトロニクス高品質スクリーン印刷技術」巻頭言 (2006)
  • Author(s): 染谷隆夫
  • Total Pages: 2
  • Publisher: シーエムシー出版
• [Book] フレキシブルセンサー、「有機基板上の電子デバイス」 (2006)
  • Author(s): 染谷隆夫, 関谷毅, 桜井貴康
  • Publisher: シーエムシー出版(発行20065年4月24日)
• [Book] "Large area detectors and sensors", Organic Electronics, ISBN Wiley-VCH,3-527-31264-1 (2006)
  • Author(s): Takao Someya, Takayasu Sakurai
  • Publisher: Weinheim
• [Book] "Large area detectors and sensors", Organic Electronics (2006)
  • Author(s): Takao Someya, Takayasu Sakurai
  • Publisher: Wiley-VCH(印刷中)
• [Book] エレクトロニクス高品質スクリーン印刷技術 (2005)
  • Author(s): 染谷隆夫
  • Publisher: シーエムシー出版
• [Book] 「第三編 応用第1章大面積センサー」、「有機トランジスタ材料の評価と応用」 (2005)
  • Author(s): 染谷隆夫
  • Total Pages: 11
  • Publisher: シーエムシー出版(ISBN4-88231-510-6)、2005年7月.
• [Book] 「第三編 応用 第1章 大面積センサー」、「有機トランジスタ材料の評価と応用」 (2005)
  • Author(s): 染谷隆夫
  • Total Pages: 190
  • Publisher: シーエムシー出版(ISBN4-88231-510-6)、2005年7月.
• [Patent(Industrial Property Rights)] 触覚ディスプレイ及びその製造方法 (2005)
  • Inventor(s): 染谷隆夫, 桜井貴康, 川口博, 関谷毅, 加藤祐作
  • Industrial Property Number: 2005-267582
  • Filing Date: 2005-09-14
• [Publications] 染谷隆夫: "有機トランジスタの化学センサー応用"機能材料. 3月号. 42 (2004)
• [Publications] J.Zaumseil, T.Someya, Z.Bao, Y.L.Loo, R.Cirelli, J.A.Rogers: "Nanoscale.organic transistors that use source/drain electrodes supported by high resolution rubber stamps"Applied Physics Letters. 82(5). 793-795 (2003)
• [Publications] N.Tang, B.Shen, Z.W.Zheng, J.Liu, D.J.Chen, J.Lu, R.Zhang, Y.Shi, Y.D.Zheng, Y.S.Gui, C.P.Jiang, Z.J.Qiu, S.L.Guo, J.H.Chu, K.Hoshino, T.Someya, Y.Arakawa: "Magnetoresistance oscillations induced by intersubband scattering of two-dimensional electron gas in A10.22Ga0.78N/GaN heterostructures"Journal of Applied Physics. 94(8). 5420-5422 (2003)
• [Publications] R.A.Taylor J.D.Smith, J.R.Rice, J.F.Ryan, T.Someya, Y.Arakawa: "Time-resolved gain dynamics in InGaN MQWs using a Kerr gate"PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES. 17(1-4). 255-257 (2003)
• [Publications] Z.W.Zheng, B.Shen, Y.S.Gui, C.P.Jiang, N.Tang, R.Zhang, Y.Shi, Y.D.Zheng, S.L.Guo, G.Z.Zheng, J.H.Chu, T.Someya, Y.Arakawa: "Transport properties of two-dimensional electron gas in different subbands in triangular quantum wells at AlxGa1xN/GaN heterointerfaces"Applied Physics Letters. 82(12). 1872-1874 (2003)
• [Publications] Z.W.Zheng, B.Shen, C.P.Jiang, Y.S.Gui, T.Someya, R.Zheng, Y.Shi, Y.D.Zheng, S.L.Guo, J.H.Chu, Y.Arakawa: "Multisubband transport of the two-dimensional electron gas in AlxGa1xN/GaN heterostructures"Journal of Applied Physics. 93(3). 1651-1655 (2003)